Chemical nature of superhydrophobic aluminum alloy surfaces produced via a one-step process using fluoroalkyl-silane in a base medium.

Various surface characterization techniques were used to study the modified surface chemistry of superhydrophobic aluminum alloy surfaces prepared by immersing the substrates in an aqueous solution containing sodium hydroxide and fluoroalkyl-silane (FAS-17) molecules. The creation of a rough micronanostructure on the treated surfaces was revealed by scanning electron microscopy (SEM). X-ray photoelectron spectroscopy (XPS) and infrared reflection absorption spectroscopy (IRRAS) confirmed the presence of low surface energy functional groups of fluorinated carbon on the superhydrophobic surfaces. IRRAS also revealed the presence of a large number of OH groups on the hydrophilic surfaces. A possible bonding mechanism of the FAS-17 molecules with the aluminum alloy surfaces has been suggested based on the IRRAS and XPS studies. The resulting surfaces demonstrated water contact angles as high as ~166° and contact angle hystereses as low as ~4.5°. A correlation between the contact angle, rms roughnesses, and the chemical nature of the surface has been elucidated.

Superhydrophobic aluminum alloy surfaces by a novel one-step process.

A simple one-step process has been developed to render aluminum alloy surfaces superhydrophobic by immersing the aluminum alloy substrates in a solution containing NaOH and fluoroalkyl-silane (FAS-17) molecules. Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and water contact angle measurements have been performed to characterize the morphological features, chemical composition and superhydrophobicity of the surfaces. The resulting surfaces provided a water contact angle as high as ∼162° and a contact angle hysteresis as low as ∼4°. The study indicates that it is possible to fabricate superhydrophobic aluminum surfaces easily and effectively without involving the traditional two-step processes.