Experiments and modeling to develop a Pistia stratiotes based Floating Vegetated System (FVS) for the removal of heavy metals (Pb, Zn, Cr, Cu, Ni).

Floating Vegetated System (FVS) emerged as a green and sustainable technology, presenting a viable solution for treating heavy metals (HMs) contaminated water without disrupting the food web. Pistia stratiotes has been used in the design of FVS due to its abundance of aerenchyma tissues, which contribute to its ability to remain buoyant. FVS exhibited significant HMs removal efficiencies, with Pb top at average 84.4 %, followed by Zn (81.1 %), Cr (78.5 %), Cu (76.5 %) and Ni (73 %). Bio-concentration Factor (BCF) and Translocation Factor (TF) values evaluated the plant's adeptness in metal uptake. For plants treated with Cu, the highest post-treatment chlorophyll content of 9 ± 1 mg.ml-1 was observed while Zn induced plant shows the lowest content of 7.1 ± 0.4 mg.ml-1. Using Box-Behnken Design (BBD), the system achieved 81.48 % Pb removal under optimized conditions such as initial Pb conc. of 9.25 mg. l-1, HRT of 24.49 days and a water depth of 26.52 cm. ANOVA analysis highlighted the significant impact of all the factors such as initial HM conc., HRT and wastewater depth on FVS performance. Kinetic analysis estimated a closer observance to the zero-order model, supported by high determination coefficient (R2) values. In conclusion, the FVS, as one of the most eco-friendly technologies, demonstrates higher potential for treating polluted water bodies, offering a sustainable remedy to global metal pollution challenges. Research on FVS for HMs removal is an area of ongoing interest and there are several potential future studies that could be pursued to further understand and optimize their effectiveness such as optimization of plant species, enhancement of plant-metal interactions, effects of environmental factors, economic feasibility studies, disposal of heavy metals accumulated plant, scale-up and application in real-world settings, etc.

Waste Stabilization Pond (WSP) for wastewater treatment: A review on factors, modelling and cost analysis.

Waste stabilization pond (WSP) is natural technology which can be installed in centralized or semi-centralized sewerage systems for treatment of domestic and industrial wastewater, septage and sludge, etc. WSPs are highly efficient, simple to construct, low cost and easy to operate. It can be used as secondary or tertiary treatment unit in a treatment plant either individually or in a coupling manner. The algal-bacterial symbiosis in WSP makes it completely natural treatment process for which it becomes economic as compared to other treatment technologies in terms of its maintenance cost and energy requirement. Effluent from WSP can also be used for agricultural purpose, gardening, watering road, vehicle wash, etc. Advance technologies are being integrated for better design and efficiency of WSP, but the main challenges are the separation and removal of algal species which lead to deterioration of the water if stays long. Research is necessary to maximize algal growth yield, selection of beneficial strain and optimizing harvesting methods. This review focuses on the treatment mechanism in the pond, affecting factors, types of ponds, design equation, cost analysis.

Ecological floating bed (EFB) for decontamination of polluted water bodies: Design, mechanism and performance.

Worldwide water quality is degrading and most of the water bodies are now being contaminated by heavy load of pollutants from various industries. Aquatic ecosystems are also disrupted affecting various flora and fauna adversely. Water bodies dominated with aquatic plants have high yielding capacity. These plants are capable of high nutrient accumulation and creating favorable condition in rhizosphere for microbial organic degradation, which can be applied in the restoration process of polluted lakes, natural streams and wetlands, etc. Ecological Floating Bed (EFB) is designed by using aquatic plants, floating like mat on the surface of water. The plant roots hang beneath the floating mat and provide a large surface area for biofilm growth. This paper reviewed the EFB concept, structure, mechanisms and functions. Screening of suitable macrophyte species, involvement of biofilm in organic removal process and necessity of growth media have been discussed briefly. Apart from this, effect of depth, buoyancy, vegetation coverage ratio are also represented. Detail mechanisms of oxygen transfer from top to bottom of water biomass have been well analyzed. Various pollutants present in wastewater like organics, solids, nitrogen, phosphorous, heavy metals etc. and their removal mechanism have also mentioned. Again biomass needs to be harvested in regular interval, else the absorbed nutrients may re-enter to the water body. Overall, EFB is an efficient and effective wastewater treatment technology and further research is necessary for its better utilization. Finally, based on reviews, recommendations have been made for future research.

Vermifiltration as a sustainable natural treatment technology for the treatment and reuse of wastewater: A review.

With increasing urbanization and industrialization, the scarcity of freshwater is becoming rampant. To counteract this, authorities all over the world are forced to consider the treatment and reuse of the wastewater produced by either industries or domestic units. After an extensive literature survey, vermifiltration coupled with/without macrophyte has been identified as one of the best sustainable, natural and eco-friendly technology for the treatment and reuse of wastewater. Till date, it has been successfully applied for treating domestic wastewater. However, the results from very limited industrial applications are also encouraging and proving its worth for industrial wastewater remediation. The present review on vermifiltration deals with the mechanisms involved and its current status for the remediation and reutilisation of the effluents generated from domestic and industrial premises. The review successfully identifies and explicitly discusses the mechanisms involved in the vermifiltration. The review exhaustively discusses the performance of vermifiltration and identifies the factors contributing to the performance of vermifiltration, which could be of help in designing of the field scale vermifilter based treatment plant. The review identifies the limitations associated with the vermifiltration and suggests possible alternatives, aimed to improve its performance and applicability. The aim of this review is to bring the attention of prospective researchers to study each and every aspect related to the vermifiltration so that it may be adopted as a reliable and dependable technology for the remediation of several industrial effluents meeting the concept of "Zero discharge".

Design and development of a hybrid macrophyte assisted vermifilter for the treatment of dairy wastewater: A statistical and kinetic modelling approach.

Global urbanization, exponential increase in population and sophisticated life style of the present generation are the major causes leading to a rapid increase in water demand in recent years. In order to nullify this rising water demand, it's high time to reuse domestic as well as industrial effluent after providing suitable chemical/biological treatment. Macrophyte filter incorporated with earthworm is identified as one of the most economic system for the treatment purpose in developing countries. However, very few literatures and technical information are available to scale up the design and its easy operation. This paper aims to develop a hybrid system and assess its performance for the purification of dairy wastewater. In the present study, two stage macrophyte assisted vermifilters (MAVFs) have been designed. The 1st stage encompassed a vertical flow (VF) unit, and the 2nd stage contained a horizontal flow (HF) unit. Both the units were inoculated with earthworm Eisenia fetida and were planted with Canna indica. Box-Behnken model was applied to design the system and study the effect of various parameters. It was observed that hybrid MAVF system removed a maximum of 83.2% COD and 57.3% TN at HLR 0.6 m/d and an active layer depth of 30 cm. Ammonification and nitrification typically occurred in the active layer (earthworm inoculated zone) of VF unit due to high activity of earthworms and its associated gut microbes, whereas HF unit facilitate denitrification process. Earthworm growth characteristics in the system were monitored, which is an imperative factor for the design of MAVF reactor. Kinetic modelling of 1st order, grau 2nd order and Stover-Kincannon model were performed and the Stover-Kincannon model showed high regression coefficient (COD, R2 0.9961 and TN, R2 0.9353) supporting its applicability as compared to the other models.