RESUMO
The title compound, C21H14O3, crystallizes with eight independent mol-ecules (A-H) in the asymmetric unit which are arranged in four groups of two mol-ecules each (AB, CD, EF and GH). In each mol-ecule, the pyran-2-one ring is planar (r.m.s. deviations vary from 0.001 to 0.017â Å), while the pyran ring has a screw-boat conformation. In the crystal, mol-ecules stack in two columns, along the [10-1] direction, composed of mol-ecules C, B, E and G, and D, A, F and H. Mol-ecules A and F are linked via C-Hâ¯O hydrogen bonds. In addition, there are a number of C-Hâ¯π contacts present involving all of the mol-ecules. These inter-actions result in the formation of a three-dimensional network.
RESUMO
In the racemic title compound, C(22)H(21)NO(3), the nitro-gen-containing ring of the pyran-oquinoline moiety adopts a slightly distorted half-chair conformation and the oxygen-containing ring adopts a slightly distorted chair conformation. The benzene rings make a dihedral angle of 84.97â (8)°. In the crystal, weak C-Hâ¯O inter-actions link the mol-ecules into chains extending along the a-axis direction.
RESUMO
A three-component one-pot condensation of 2-naphthol, ureas/amides and aldehydes catalyzed by sulfamic acid, under ultrasound irradiation and ambient conditions gives 1-amidoalkyl-2-naphthols in excellent yield and in short time.