RESUMO
Poly-l-lactic acid (PLLA) nanocomposites containing graphene oxide (GO), modified with different chain lengths of poly(ethylene glycol) (PEG) (400, 2000, and 10â¯000 g/mol), were prepared by solution casting. The effect of the PEG chain length and nanoparticle content (0.5, 1, and 1.5 wt %) on the nucleation, crystal growth rate, and overall crystallization rate, under isothermal conditions, was then evaluated. The results showed that, in samples containing GO modified with 400 g/mol of PEG, the nucleation density increased as a function of a modified nanoparticle concentration. In the case of the samples containing GO modified with PEG of a molar mass of either 2000 or 10â¯000 g/mol, the nucleation density exhibited a maximum at a concentration of 1 wt %. Furthermore, the addition of graphene oxide modified with poly(ethylene glycol) of a molar mass of 2000 g/mol resulted in the largest nucleation, fastest crystal growth, and highest overall crystallization rate, for all concentrations. The results were explained in light of the steric hindrance between the modified nanoparticles.
RESUMO
Electrospinning has gained much attention in recent years due to its ability to easily produce high-quality polymeric nanofibers. However, electrospinning suffers from limited production capacity and a method to readily scale up this process is needed. One obvious approach includes the use of multiple electrospinning needles operating in parallel. Nonetheless, such an implementation has remained elusive, partly due to the uneven electric field distribution resulting from the Coulombic repulsion between the charged jets and needles. In this work, the uniformization of the electric field was performed for a linear array of twenty electrospinning needles using lateral charged plates as auxiliary electrodes. The effect of the auxiliary electrodes was characterized by investigating the semi-vertical angle of the spun jets, the deposition area and diameter of the fibers, as well as the thickness of the produced membranes. Finite element simulation was also used to analyze the impact of the auxiliary electrodes on the electric field intensity below each needle. Implementing parallel lateral plates as auxiliary electrodes was shown to help achieve uniformization of the electric field, the semi-vertical angle of the spun jet, and the deposition area of the fibers for the multi-needle electrospinning process. The high-quality morphology of the polymer nanofibers obtained by this improved process was confirmed by scanning electron microscopy (SEM). These findings help resolve one of the primary challenges that have plagued the large-scale industrial adoption of this exciting polymer processing technique.
RESUMO
The objective of this study is to demonstrate the practical use of polluted river sediments after treatment into brick production. Consequently, a full-scale industrial experiment was conducted at a brick factory in the north of France. Polluted sediment was stabilized by the Novosol process and then was introduced in the mix-design with a substitution ratio of 15% as a partial replacement of quartz sand. Approximately 15,000 perforated sediment-amended bricks were produced. The produced bricks were then subjected to several qualification tests (compressive strength, freeze and thaw resistance, water absorption). The results obtained showed that the substitution of quartz sand by treated sediment resulted in a significant increase in brick compressive strength and firing shrinkage, and in a decrease in porosity and water absorption. Moreover, leaching tests performed according to different standards on substituted brick samples showed that the quantities of heavy metals leached from crushed bricks were within the regulatory limits. Thus substituted bricks can be regarded as non-hazardous material.