Parameterization of nutrients and sediment build-up/wash-off processes for simulating stormwater quality from specific land uses.

Urbanization changes land cover through the expansion of impermeable surfaces, leading to a significant rise in runoff, sediment, and nutrient loading. The quality of stormwater is related to land use and is highly variable. Currently, stormwater is predominantly described through watershed models that rely minimally, if at all, on field monitoring data. The simple event mean concentration (EMC) wash-off approach by land use is a common method for estimating urban runoff loads. However, a major drawback of the EMC approach is it assumes concentration remains constant across events for a specific land use. Build-up/wash-off equations have been formulated to consider variations in concentration between events. However, several equation parameters are challenging to estimate, making them difficult to use. We conducted a monitoring and modeling study and investigated the impact of land use on stormwater quantity and quality and optimized and investigated the build-up/wash-off parameters for three homogenous urban land uses to estimate nutrients (nitrogen and phosphorus) and sediment loads. Stormwater from commercial, medium-density residential, and transportation land uses was sampled using automatic samplers during storm events, and water quality was characterized for a variety of them for 14 months. Analysis of stormwater samples included assessments for total nitrogen, total phosphorus, and total suspended solids. Results showed that medium-density residential land use had the highest median total nitrogen and total phosphorus event mean concentrations and commercial had the highest median total suspended solids EMCs. Water quality parameters (or build-up/wash-off parameters) exhibited significant variation between land uses, confirming that land use is a key determinant of stormwater quality. The median particle size for each land use was less than 150 µm, indicating that the most common particle size in stormwater was a very fine sand or smaller. This small size should be considered by stakeholders in the design of stormwater treatment systems.

The effect of piping stream channels on dissolved oxygen concentration and ecological health.

Sunlight plays a key role in the nutrient cycle within streams. Streams are often piped to accommodate urban residential or commercial development for buildings, roads, and parking. This results in altered exposure to sunlight, air, and soil, subsequently affecting the growth of aquatic vegetation, reducing reaeration, and thus impairing the water quality and ecological health of streams. While the effects of urbanization on urban streams, including changing flow regimes, stream bank and bed erosion, and degraded water quality, are well understood, the effects of piping streams on dissolved oxygen (DO) concentrations, fish habitats, reaeration, photosynthesis, and respiration rates are not. We addressed this research gap by assessing the effects of stream piping on DO concentrations before and after a 565-m piped section of Stroubles Creek in Blacksburg, VA, for several days during the summer of 2021. Results indicate that the DO level decreased by approximately 18.5% during daylight hours as water flowed through the piped section of the creek. Given the optimum DO level (9.0 mg·L-1) for brook trout (Salvelinus sp.), which are native and present in a portion of Stroubles Creek, the resulting DO deficits were - 0.49 and - 1.24 mg·L-1, for the inlet and outlet, respectively, indicating a possible adverse impact from piping the stream on trout habitat. Photosynthesis and respiration rates were reduced through the piped section, primarily due to the reduced solar radiation and the resultant reduction in oxygen production from aquatic vegetation; however, the reaeration rate increased. This study can inform watershed restoration efforts, particularly decisions regarding stream daylighting with respect to potential water quality and aquatic habitat benefits.

Using Random Forest, a machine learning approach to predict nitrogen, phosphorus, and sediment event mean concentrations in urban runoff.

Estimating pollutant loads from developed watersheds is vitally important to reduce nonpoint source pollution from urban areas, as a key tool in meeting water quality goals is the implementation of Stormwater Control Measures (SCMs). SCMs are selected and sized based on influent pollutant loads. A common method used to estimate pollutant loads in urban runoff is the Event Mean Concentration (EMC) method. In this study, we develop and apply data-driven models using Random Forest (RF), a machine learning approach, to predict Total Nitrogen (TN), Total Phosphorus (TP), Total Suspended Solids (TSS), and Ortho-Phosphorus (Ortho-P) EMCs in urban runoff. The parameters considered in this study were climatological characteristics (i.e., Antecedent Dry Period or ADP, Precipitation Depth or P, Duration or D, and Intensity or I) and catchment characteristics including land use-related parameters including Imperviousness or Imp, Saturated Hydraulic Conductivity or Ksat, and Available Water Capacity or AWC), and site-specific parameters including Slope (S), and Catchment Size (A). Stormwater quality data for this study were obtained from the National Stormwater Quality Database (NSQD), which is the largest repository of stormwater quality data in the U.S. Results demonstrate that land use-related characteristics (i.e., Imp, Ksat, and AWC) were the most effective variables for predicting all EMCs. For TP, TSS, and Ortho-P, site-specific characteristics (S and A) had a greater effect than climatological characteristics (i.e., ADP, P, D, and I). However, for TN, climatological characteristics had a greater effect than site-specific characteristics (S and A). In addition, for TN, TP, and TSS, precipitation characteristics (P, D, and I) were found to be more effective parameters for estimating EMCs than ADP. This study highlights the most influential parameters affecting EMCs which can be used by stakeholders and SCMs designers to improve estimates of nutrients and sediment EMCs. The selection and design of the highest performing SCMs is essential in achieving effective treatment of stormwater, attaining water quality goals, and protecting downstream waterbodies.

What are the relevant sources and factors affecting event mean concentrations (EMCs) of nutrients and sediment in stormwater?

Urbanization increases runoff, sediment, and nutrient loadings downstream, causing flooding, eutrophication, and harmful algal blooms. Stormwater control measures (SCMs) are used to address these concerns and are designed based on inflow loads. Thus, estimating nutrient and sediment loads is important for meeting restoration objectives. Pollutants accumulate on surfaces during dry periods, making Event Mean Concentration (EMC) a function of antecedent dry period (ADP). An EMC results from wash-off of accumulated pollutants from catchment surface during runoff events. However, several studies found little to no correlation between constituent concentrations in stormwater and ADP. The objective of this study is to verify this finding and discover which climatological or catchment characteristics most significantly affect stormwater quality. Stormwater quality data were obtained from the National Stormwater Quality Database (NSQD), which is the largest data repository of stormwater quality data in the U.S. Bayesian Network Structure Learner (BNSL) was used to assess the relationships between catchment characteristics, climatological information, and stormwater quality for selected land uses. Given the optimal BN structure, it was determined which parameters most affect stormwater quality EMCs. The results demonstrate that both catchment and rain characteristics affected stormwater quality EMCs. Among catchment characteristics, land use (LU) was the most important factor and catchment size was the least. Precipitation depth (P) and duration (D) affected Total Phosphorus (TP), Total Nitrogen (TN), and Total Suspended Solids (TSS). This indicated that it is likely that P and D had a greater influence on stormwater quality more than ADP. P, D, and ADP affected the dissolved constituents of TN (i.e. NO2-N/NO3-N) and TP (i.e. Ortho-P). Compared to other factors (i.e. P and D), the effect of ADP on TSS was negligible. Stormwater quality EMCs related to nitrogen were not affected by catchment slope (S). However, TSS and Ortho-P were influenced by S.

The effects of land use characteristics on urban stormwater quality and watershed pollutant loads.

Urban developments can result in higher runoff and nutrient loadings transported to downstream receiving waterbodies. While much effort has been made recently in watershed restoration in the U.S., a lack of recent runoff quality data limits the prediction capability of urban watershed models. The objectives of this study was to fill an existing information gap on how rainfall and land uses interact and affect such loadings. This study instrumented six coastal urban catchments, each dominated by a single land use. We measured total nitrogen (TN), total phosphorus (TP), total suspended solids (TSS), total Kjeldahl Nitrogen (TKN), ortho-P, and nitrate concentrations in runoff from 30 storm events over one year from six urban land uses, namely commercial, industrial, transportation, open space, low density residential, and high density residential. Results indicated that the median event mean concentrations (EMCs) for TSS, TP, and TN were 30 (19-34), 0.31 (0.26-0.31), and 0.94 (0.73-1.25) mg L-1, respectively. TSS EMCs from the open space and industrial land uses were significantly greater than other land uses; there were positive correlations between TN concentrations and imperviousness and between TP concentrations and turf coverage. Both the amount and intensity of rainfall positively influenced TSS concentrations in runoff regardless of land use. Using the collected data, this study developed a generic equation for predicting the loading of a pollutant as a function of rainfall depth. This equation was verified by comparing its predictions with the simulations of a sufficiently-calibrated water quality model in terms of TSS, TP, and TN loadings from various land uses in another coastal catchment for a period of ten years. Average TSS, TN, and TP loadings from the catchment were estimated to be 0.86, 0.03, and 0.01 kg ha-1 cm-1, respectively.

Response of non-point source pollution to landscape pattern: case study in mountain-rural region, China.

Landscape patterns have a substantial effect on non-point source (NPS) pollution in watersheds. Facilitating sustainable development of mountain-rural areas is a major priority for China. Knowledge of the impacts of various landscapes on water quality in these areas is critical to meeting environmental goals. This study applied the Soil and Water Assessment Tool (SWAT) to create a hydrologic and water quality model of the study watershed; then, the relationship between water quality and landscape patterns was investigated using multiple linear regression and redundancy analysis. The results show that the western sub-basins had higher nitrogen pollution loads, and the total nitrogen concentration reached a maximum value of 3.91 mg/L; the eastern sub-basins had a higher pollution load of phosphorous featured by maximum total phosphorous concentration of 2.15 mg/L. The water quality of the entire watershed in all scenarios tended to deteriorate over time. Landscape metrics accounted for 81.7% of the total variation in pollutant indicators. The percentage of forest landscape was negatively correlated with NPS pollution, while other types of landscape showed a positive correlation. The patch density, landscape shape index, and largest patch index of urban and agricultural lands were negatively correlated with pollutant concentrations. Upland landscapes contributed more pollutants than paddy fields. Some measures, e.g., returning grassland and farmland to forest in steep regions and replacing upland crops with paddy fields, were recommended for mitigating NPS pollution in the study watershed.

Effect of intermittent aeration mode on nitrogen concentration in the water column and sediment pore water of aquaculture ponds.

Nitrogen in pond sediments is a major water quality concern and can impact the productivity of aquaculture. Dissolved oxygen is an important factor for improving water quality and boosting fish growth in aquaculture ponds, and plays an important role in the conversion of ammonium-nitrogen (NH4+-N) to nitrite-nitrogen (NO2--N) and eventually nitrate-nitrogen (NO3--N). A central goal of the study was to identify the best aeration method and strategy for improving water quality in aquaculture ponds. We conducted an experiment with six tanks, each with a different aeration mode to simulate the behavior of aquaculture ponds. The results show that a 36 hr aeration interval (Tc = 36 hr: 36 hr) and no aeration resulted in high concentrations of NH4+-N in the water column. Using a 12 hr interval time (Tc = 12 hr: 12 hr) resulted in higher NO2--N and NO3--N concentrations than any other aeration mode. Results from an 8 hr interval time (Tc = 8 hr: 8 hr) and 24 hr interval time (Tc = 24 hr: 24 hr) were comparable with those of continuous aeration, and had the benefit of being in use for only half of the time, consequently reducing energy consumption.

The effect of temperature on sulfate release from Pearl River sediments in South China.

Sulfate (SO42-) has received attention as means of monitoring water quality and pollution. However, the SO42- content of rivers, lakes, and reservoirs varies significantly by season, so environmental factors such as temperature can affect it. An experiment was conducted with a series of aerobic and anaerobic tanks containing Pearl River sediments and distilled water to assess the release of SO42- from sediments under controlled conditions. "Black-odor river" refers to near anoxic conditions in the water column and foul odors emanating from affected rivers in southeastern China. These river systems typical have sediments containing ammonia (NH3), hydrogen sulfide (H2S), and organic sulfide compounds in excess, and precipitates of sulfide (S2-), with ferrous (Fe2+) or manganese (Mn2+). SO42- concentration was measured at various depths in pore water and in the water column while controlling temperature and dissolved oxygen (DO) concentrations. Interpolation of study results revealed that SO42- content was highest between temperatures of 20 °C and 25 °C. The relationship between SO42- concentration, which varied with temperature and time, was fit using a linearized Michaelis-Menten function (R2 = 0.69). The release of SO42- to the water column was accelerated during the experiment (for temperatures higher than 20 °C), and led to higher SO42- content in the water column than in pore water. The maximum concentration of SO42- within the sediment occurred at a temperature of 20 °C. Comparing aerated and non-aerated tanks at 20 °C, we found that O2 restricted SO42- content in the water column; DO could, in turn, also be controlled by temperature. Fe2+ and Mn2+ had a negative correlation with SO42-.

Simulation of watershed-scale practices for mitigating stream thermal pollution due to urbanization.

Thermally enriched runoff from urban impervious surfaces can be harmful to aquatic life; however, only limited information is available on how to mitigate these impacts at the watershed-scale. This study evaluates the effects of retrofitting an urban watershed with thermal mitigation practices (TMPs) relative to thermal toxicity thresholds for aquatic species. The Minnesota Urban Heat Export Tool (MINUHET) and Storm Water Management Model (SWMM) models were used to evaluate TMPs that help reduce temperature and total heat loads (THL) from the Stroubles Creek watershed in Blacksburg, Virginia. We used the aquatic health criteria for brook trout (Salvelinus fontinalis), the most sensitive species present downstream of the watershed, as a performance measure. TMPs included bioretention systems, methods for reducing the albedo of surfaces (cool surfaces), and increasing forest canopy. Performance metrics included Event Mean Temperature (EMT), and the Percentage of Time Temperature Exceeded the 21 °C Acute Toxicity Threshold [Percentage of Time above the Threshold (PTAT)] for brook trout; these metrics were used to quantify reductions in heat loads and temperatures. TMPs were evaluated during continuous simulation and selected storm events. Increased forest canopy alone produced the greatest reduction of stream temperature, as quantified by EMT and PTAT metrics during continuous and event-based simulations. In contrast, cool surfaces reduced THL more than any other individual TMP for the continuous simulation. A comprehensive mitigation plan (CMP) integrating all three TMPs reduced THL by 62.3%, and PTAT by approximately 12%, for the entire summer of 2015. The CMP was also applied to select storm events, during which streamflow EMT was reduced up to 9%, and PTAT was reduced nearly to zero. This study, which is the first to simulate watershed-scale TMPs for a large, complex urban area, demonstrates the application of appropriate strategies for restoring aquatic habitats in the thermally impacted Stroubles Creek.

Water quality characterization of storm and irrigation runoff from a container nursery.

Commercial nurseries grow specialty crops for resale using a variety of methods, including containerized production, utilizing soilless substrates, on a semipervious production surface. These "container" nurseries require daily water application and continuous availability of mineral nutrients. These factors can generate significant nutrients [total nitrogen (TN), and total phosphorus (TP)] and sediment [total suspended solids (TSS)] in runoff, potentially contributing to eutrophication of downstream water bodies. Runoff is collected in large ponds known as tailwater recovery basins for treatment and reuse or discharge to receiving streams. We characterized TSS, TN, and TP, electrical conductivity (EC), and pH in runoff from a 5.2 ha production portion of a 200-ha commercial container nursery during storm and irrigation events. Results showed a direct correlation between TN and TP, runoff and TSS, TN and EC, and between flow and pH. The Storm Water Management Model (SWMM) was used to characterize runoff quantity and quality of the site. We found during irrigation events that simulated event mean concentrations (EMCs) of TSS, TN, and TP were 30, 3.1 and 0.35 mg·L-1, respectively. During storm events, TSS, TN and TP EMCs were 880, 3.7, and 0.46 mg·L-1, respectively. EMCs of TN and TP were similar to that of urban runoff; however, the TSS EMC from nursery runoff was 2-4 times greater. The average loading of TSS, TN and TP during storm events was approximately 900, 35 and 50 times higher than those of irrigation events, respectively. Based on a 10-year SWMM simulation (2008-2018) of runoff from the same nursery, annual TSS, TN and TP load per ha during storm events ranged from 9230 to 13,300, 65.8 to 94.0 and 9.00 to 12.9 kg·ha-1·yr-1, respectively. SWMM was able to characterize runoff quality and quantity reasonably well. Thus, it is suitable for characterizing runoff loadings from container nurseries.

Assessing nitrogen and phosphorus removal potential of five plant species in floating treatment wetlands receiving simulated nursery runoff.

The feasibility of using floating treatment wetlands (FTWs) to treat runoff typical of commercial nurseries was investigated using two 8-week trials with replicated mesocosms. Plants were supported by Beemat rafts. Five monoculture treatments of Agrostis alba (red top), Canna × generalis 'Firebird' (canna lily), Carex stricta (tussock sedge), Iris ensata 'Rising Sun' (Japanese water iris), Panicum virgatum (switchgrass), two mixed species treatments, and an unplanted control were assessed. These plant species are used for ornamental, wetland, and biofuel purposes. Nitrogen (N) and phosphorus (P) removals were evaluated after a 7-day hydraulic retention time (HRT). N removal (sum of ammonium-N, nitrate-N, and nitrite-N) from FTW treatments ranged from 0.255 to 0.738 g·m-2·d-1 (38.9 to 82.4% removal) and 0.147 to 0.656 g·m-2·d-1 (12.9 to 59.6% removal) for trials 1 and 2, respectively. P removal (phosphate-P) ranged from 0.052 to 0.128 g·m-2·d-1 (26.1 to 64.7% removal) for trial 1, and 0.074 to 0.194 g·m-2·d-1 (26.8 to 63.2% removal) for trial 2. Panicum virgatum removed more N and P than any other FTW treatment and the control in both trials. Results show that species selection and timing of FTW harvest impact the rate and mass of nutrient remediation. FTWs can effectively remove N and P from runoff from commercial nurseries.

Data on floating treatment wetland aided nutrient removal from agricultural runoff using two wetland species.

The data presented in this article are related to the research article entitled "Floating treatment wetland aided nutrient removal from agricultural runoff using two wetland species" (Spangler et al., 2018). This Data in Brief article provides data on concentrations of common ions, macro- and micro-nutrients and metals every other week during a floating treatment wetland (FTW) mesocosm experiment, and macro- and micro-nutrient contents in cumulative plant tissues, data on continuously monitored water temperature, and nitrogen and phosphorus removal curves assessed every other week. The full data set is made available to enable critical or extended analysis of the research.

Thermal evaluation of urbanization using a hybrid approach.

Urban development increases runoff temperatures from buildings and pavement, which can be harmful to aquatic life. However, our ability to predict runoff temperature as a function of land use is limited. This paper explores available tools for simulating runoff temperature with respect to brook trout (Salvelinus sp.), a sensitive species. The Minnesota Urban Heat Export Tool (MINUHET) and the Storm Water Management Model (SWMM) were applied to a 14.1 km2 portion of the Stroubles Creek watershed near Blacksburg, Virginia for two summers. Streamflow, water temperature, and weather data were acquired from the Virginia Tech StREAM Lab (Stream Research, Education, and Management) monitoring stations. SWMM and MINUHET were calibrated and validated for streamflow, and stream temperature, respectively. The models were sensitive to imperviousness (SWMM-predicted streamflow) and dew point temperature (MINUHET-predicted water temperature). While the models output time-step was 15 min, the model performance in simulating streamflow was evaluated using Nash-Sutcliffe Efficiency (NSE) on hourly time-steps. NSE values were 0.67 and 0.65 for SWMM and 0.62 and 0.57 for MINUHET during the calibration and validation periods, respectively, indicating that SWMM performed better than MINUHET in streamflow simulation. Stream temperatures were simulated using MINUHET with NSE value of 0.58 for the validation period, demonstrating a satisfactory simulation of water temperature. Since SWMM is not capable of stream temperature simulation beyond simple mixing. Hydrologic and thermal outputs from SWMM and MINUHET were combined in a hybrid approach that emphasized the strength of each respective model, i.e. SWMM for runoff and streamflow and MINUHET for water temperature. Heat loads were simulated using the MINUHET and the Hybrid models; the Hybrid model (0.56) had a greater NSE than MINUHET (0.45) alone. MINUHET predictions indicated water temperatures would exceed the trout toxicity threshold of 21 °C during 39% and 38% of calibration and validation periods, respectively. Since the observed temperature exceeded the toxicity threshold 59% and 53% of the time for the calibration and validation periods, respectively, MINUHET was not a conservative predictor of the duration of temperatures exceeding the toxicity threshold value.

Water supply and runoff capture reliability curves for hypothetical rainwater harvesting systems for locations across the U.S. for historical and projected climate conditions.

The data presented in this article are related to the research article entitled "Assessing climate change impacts on the reliability of rainwater harvesting systems" (Alamdari et al., 2018) [1]. This article evaluated the water supply and runoff capture reliability of rainwater harvesting (RWH) systems for locations across the U.S. for historical and projected climate conditions. Hypothetical RWH systems with varying storage volumes, rooftop catchment areas, irrigated areas, and indoor wSater demand based upon population from selected locations were simulated for historical (1971-1998) and projected (2041-2068) periods, the latter dataset was developed using dynamic downscaling of North American Regional Climate Change (CC) Assessment Program (NARCCAP). A computational model, the Rainwater Analysis and Simulation Program (RASP), was used to compute RWH performance with respect to the reliability of water supply and runoff capture. The reliability of water supply was defined as the proportion of demands that are met; and the reliability of runoff capture was defined as the amount stored and reused, but not spilled. A series of contour plots using the four design variables and the reliability metrics were developed for historical and projected conditions. Frequency analysis was also used to characterize the long-term behavior of rainfall and dry duration at each location. The full data set is made publicly available to enable critical or extended analysis of this work.

Evaluating the performance of a retrofitted stormwater wet pond for treatment of urban runoff.

This paper describes the performance of a retrofitted stormwater retention pond (Ashby Pond) in Northern Virginia, USA. Retrofitting is a common practice which involves modifying existing structures and/or urban landscapes to improve water quality treatment, often compromising standards to meet budgetary and site constraints. Ashby Pond is located in a highly developed headwater watershed of the Potomac River and the Chesapeake Bay. A total maximum daily load (TMDL) was imposed on the Bay watershed by the US Environmental Protection Agency in 2010 due to excessive sediment and nutrient loadings leading to eutrophication of the estuary. As a result of the TMDL, reducing nutrient and sediment discharged loads has become the key objective of many stormwater programs in the Bay watershed. The Ashby Pond retrofit project included dredging of accumulated sediment to increase storage, construction of an outlet structure to control flows, and repairs to the dam. Due to space limitations, pond volume was less than ideal. Despite this shortcoming, Ashby Pond provided statistically significant reductions of phosphorus, nitrogen, and suspended sediments. Compared to the treatment credited to retention ponds built to current state standards, the retrofitted pond provided less phosphorus but more nitrogen reduction. Retrofitting the existing stock of ponds in a watershed to at least partially meet current design standards could be a straightforward way for communities to attain downstream water quality goals, as these improvements represent reductions in baseline loads, whereas new ponds in new urban developments simply limit future load increases or maintain the status quo.

Vegetation effects on floating treatment wetland nutrient removal and harvesting strategies in urban stormwater ponds.

Floating treatment wetlands (FTWs) consist of emergent macrophytes that are placed on a floating mat in a pond for water treatment and aesthetic purposes. FTWs may have unique advantages with respect to treating urban runoff within existing retention ponds for excess nutrients. However, research is lacking in providing guidance on performance of specific species for treating urban runoff, and on timing of harvest. Harvesting is needed to remove nutrients permanently from the retention pond. We investigated vegetation effects on FTWs on nitrogen (N) and phosphorus (P) removal performance and storage in above-ground FTW macrophyte tissues. The study evaluated pickerelweed (PW, Pontederia cordata L.) and softstem bulrush (SB, Schoenoplectus tabernaemontani) over time in microcosms flushed with water obtained from a nearby urban retention pond in northern Virginia near Washington, DC. While the literature exhibits a wide range of experimental sizes, using the term mesocosm, we have chosen the term microcosm to reflect the small size of our vessel; and do not include effects of sediment. The experiment demonstrated PW outperformed SB for P and N removal. Based upon analysis of the accumulated nutrient removal over time, a harvest of the whole PW and SB plants in September or October is recommended. However, when harvesting only the aerial parts, we recommend harvesting above-ground PW tissues in July or August to maximize nutrient removal. This is because PW translocates most of its nutrients to below-ground storage organs in the fall, resulting in less nutrient mass in the above-ground tissue compared to the case in the summer (vegetative stage). Further research is suggested to investigate whether vegetation can be overly damaged from multiple harvests on an annual basis in temperate regions.

Assessment of the nutrient removal effectiveness of floating treatment wetlands applied to urban retention ponds.

The application of floating treatment wetlands (FTWs) in point and non-point source pollution control has received much attention recently. Although the potential of this emerging technology is supported by various studies, quantifying FTW performance in urban retention ponds remains elusive due to significant research gaps. Actual urban retention pond water was utilized in this mesocosm study to evaluate phosphorus and nitrogen removal efficiency of FTWs. Multiple treatments were used to investigate the contribution of each component in the FTW system with a seven-day retention time. The four treatments included a control, floating mat, pickerelweed (Pontederia cordata L.), and softstem bulrush (Schoenoplectus tabernaemontani). The water samples collected on Day 0 (initial) and 7 were analyzed for total phosphorus (TP), total particulate phosphorus, orthophosphate, total nitrogen (TN), organic nitrogen, ammonia nitrogen, nitrate-nitrite nitrogen, and chlorophyll-a. Statistical tests were used to evaluate the differences between the four treatments. The effects of temperature on TP and TN removal rates of the FTWs were described by the modified Arrhenius equation. Our results indicated that all three FTW designs, planted and unplanted floating mats, could significantly improve phosphorus and nitrogen removal efficiency (%, E-TP and E-TN) compared to the control treatment during the growing season, i.e., May through August. The E-TP and E-TN was enhanced by 8.2% and 18.2% in the FTW treatments planted with the pickerelweed and softstem bulrush, respectively. Organic matter decomposition was likely to be the primary contributor of nutrient removal by FTWs in urban retention ponds. Such a mechanism is fostered by microbes within the attached biofilms on the floating mats and plant root surfaces. Among the results of the four treatments, the FTWs planted with pickerelweed had the highest E-TP, and behaved similarly with the other two FTW treatments for nitrogen removal during the growth period. The temperature effects described by the modified Arrhenius equation revealed that pickerelweed is sensitive to temperature and provides considerable phosphorus removal when water temperature is greater than 25 °C. However, the nutrient removal effectiveness of this plant species may be negligible for water temperatures below 15 °C. The study also assessed potential effects of shading from the FTW mats on water temperature, DO, pH, and attached-to-substrate periphyton/vegetation.

Assessment of selected bioretention blends for nutrient retention using mesocosm experiments.

This study compares the performance of three bioretention media blends for N and P removal from simulated urban runoff in experimental mesocosms. TerraSolve, Biofilter, and "VT Mix" (Virginia Tech) were compared with and without vegetation at varying hydraulic residence times (HRTs). Adsorption isotherm experiments were also conducted. TerraSolve and VT Mix included water treatment residuals (WTRs), Biofilter and VT Mix included yard-waste compost (YWC), and TerraSolve included a mix of coir and peat. TerraSolve removed the highest amount of total P (>95%), which is attributed to the high quantity of WTRs. Results were similar for VT Mix, likely due to WTR content. Adsorption isotherms indicate a substantial difference due to this factor. Vegetative mesocosms were found to be less effective at P removal at an HRT of 6 to 12 h but not at an HRT of 24 h. VT Mix had the highest removal of total Kjeldahl nitrogen (TKN), significantly different than the other blends. Interactive effects with vegetation were observed, generally improving TKN removal at all HRTs, with the highest at 24 h. Substantial export of nutrients when using compost was not observed. The addition of YWC appeared to increase N removal, possibly by denitrification. It is recommended that bioretention media contain <10% fines, a source of amorphous Al for P adsorption, at least 3 to 5% total organic C in the form of a low P, relatively stable compost, and a minimum concentration of plant-available nutrients for establishment of vegetation. For systems that use HRT, optimum residence time is influenced by media composition.

Assessing performance of manufactured treatment devices for the removal of phosphorus from urban stormwater.

Nutrients such as nitrogen and phosphorus in urban runoff can be controlled through a variety of nonstructural and structural controls commonly known as best management practices (BMPs). Manufactured treatment devices (MTDs) are structural BMPs that may be used in portions of a site, often when space is limited. MTDs use a variety of technologies to achieve potentially greater treatment efficiency while reducing spatial requirements. However, verifying the performance of MTDs is difficult because of the variability of runoff water quality, the variability in treatment technologies, and the lack of standardized protocols for field testing. Performance testing of MTDs has focused almost exclusively upon removal of sediment; however MTDs are now being applied to the task of removing other constituents of concern, including nutrients such as phosphorus. This paper reviews current methods of assessing treatment performance of MTDs and introduces the Virginia Technology Assessment Protocol (VTAP), a program developed to evaluate the removal of phosphorus by MTDs. The competing goals of various stakeholders were considered when developing the VTAP. A conceptual framework of the tradeoffs considered is presented; these tradeoffs require compromise among the competing interests in order that innovation proceeds and benefits accrue. The key strengths of VTAP are also presented and compared with other existing programs.