Effectiveness of the tropical plants Rhynchospora corymbosa and Coix lacryma-jobi in vertical flow constructed wetlands for municipal primary sewage effluent treatment.

The performance of two tropical plants, Rhynchospora corymbosa L. (RC) and Coix lacryma-jobi, L (CL) in treatment of primary sewage effluent in lab-scale vertical-flow constructed wetlands (VFCW) along with no plant control wetland was investigated. A batch-flow VFCWs were operated under batch fill and drain hydraulic loading system with hydraulic retention times (HRT) of 0.5, 1, and 2 days and fill rate of 8 L/day. Removal of solids, organics, nutrients, and pathogens were monitored. The volumetric contaminant removal rates were best described by 1st order kinetics except for ammonia and phosphate, which was best described by Stover-Kincannon kinetics. Influent TSS, PO43-, COD, BOD5, and total coliform concentration were low but high in NH4+ concentration. CL was better in nutrient removal as HRT increases compared to RC. RC was more efficient at TSS, turbidity, and organics removal. Pathogen removal was independent of plant type but HRT. Solids and organic removal were lower in CL planted CWs due to preferential flow paths created by their bulky root. CL planted CWs removed more nutrients followed by RC planted CWs and then no-plant control CWs. The results of these tests demonstrate that both CL and RC are suitable for the treatment of municipal wastewater in VFCW system.

Assessment of Ordinary Kriging and Inverse Distance Weighting Methods for Modeling Chromium and Cadmium Soil Pollution in E-Waste Sites in Douala, Cameroon.

BACKGROUND: Several studies have demonstrated that chromium (Cr) and cadmium (Cd) have adverse impacts on the environment and human health. These elements are present in electronic waste (e-waste) recycling sites. Several interpolation methods have been used to evaluate geographical impacts on humans and the environment. OBJECTIVES: The aim of the present paper is to compare the accuracy of inverse distance weighting (IDW) and ordinary kriging (OK) in topsoil analysis of e-waste recycling sites in Douala, Cameroon. METHODS: Selecting the proper spatial interpolation method is crucial for carrying out surface analysis. Ordinary kriging and IDW are interpolation methods used for spatial analysis and surface mapping. Two sets of samples were used and compared. The performances of interpolation methods were evaluated and compared using cross-validation. RESULTS: The results showed that the OK method performed better than IDW prediction for the spatial distribution of Cr, but the two interpolation methods had the same result for Cd (in the first set of samples). Results from Kolmogorov-Smirnov and Shapiro-Wilk tests showed that the data were normally distributed in the study area. The p value (0.302 and 0.773) was greater than 0.05 for Cr and for Cd (0.267 and 0.712). In the second set of samples, the OK method results (for Cd and Cr) were greatly diminished and the concentrations dropped, looking more like an average on the maps. However, the IDW interpolation gave a better representation of the concentration of Cd and Cr on the maps of the study area. For the second set of samples, OK and IDW for Cd and Cr had more similar results, especially in terms of root mean square error (RMSE). CONCLUSIONS: Many parameters were better identified from the RMSE statistic obtained from cross-validation after exhaustive testing. Inverse distance weighting appeared more adequate in limited urban areas. COMPETING INTERESTS: The authors declare no competing financial interests.

Ecological Risk and Human Health Implications of Heavy Metals Contamination of Surface Soil in E-Waste Recycling Sites in Douala, Cameroun.

BACKGROUND: Recycling of electronic waste (e-waste) in developing nations poses a risk to the environment and human health through the release of heavy metals. OBJECTIVES: The aim of the present study was to evaluate the levels of heavy metals in Douala, Cameroun, the site of e-waste recycling activities. METHODS: Soil samples were collected from Makea, Ngodi and New Bell e-waste recycling sites, as well as from a control site. Samples were digested and levels of heavy metals were determined. RESULTS: The concentrations of the heavy metals in Makea occurred in the order of lead (Pb) (290±40) > zinc (Zn) (160±30) > chromium (Cr) (130±40) > copper (Cu) (130±20) > nickel (Ni) (56±5.7) > cadmium (Cd) (20±3.0); Pb (310±30) >Zn (150±20) >Cu (80±30) >Cr (70±40) >Ni (50±1.0) >Cd (30±5.0) in Ngodi; and Pb (280±40) >Zn (155±35) >Cu (80±50) >Cr (70±40) >Ni (53±2.0) >Cd (20±10) in New Bell. The levels of metals in all of the samples were higher compared to the control site, which was composed of vegetation and far from the e-waste sites, and in some cases, higher than permissible limits or guidelines. The ecological risk index of heavy metals for soil samples in all the e-waste sites indicated a very high risk. CONCLUSIONS: Heavy metals concentrations in soil around e-waste recycling sites present serious health risks and further investigations are needed. COMPETING INTERESTS: The authors declare no competing financial interests.