RESUMO
In this present study, an abundant, available lignocellulosic biomass, sunflower seed shells, SSS, was used as a precursor to prepare an effective eco-adsorbent by treatment with H2SO4. A study of the surface characteristics of raw and acid-treated SSS (ACS) has shown that the addition of H2SO4 greatly affected the physicochemical properties of the obtained eco-adsorbent, improving the BET surface area from 6.106 to 27.145 m2 g-1 and surface oxygen-rich functional groups. Batch experiments were performed to assess the removal efficiency of a phenolic compound, bisphenol A (BPA), on the adsorbents. Several parameters were evaluated and are discussed (contact time, pollutant concentration, adsorbent dosage, and pH), determining that the adsorption efficiency of BPA onto SSS was notably improved, from 20.56% to 87.81% when a sulfuric acid solution was used. Different canonical and stochastic isotherm models were evaluated to predict the experimental behaviour. A dynamic study was performed based on the models of reaction kinetics and those of mass transfer. The results showed that the adsorption kinetics of BPA obey the fractal like-kinetic model of Hill for all experimental conditions. The equilibrium data are well suited to the Hill-Sips isotherm model with a determination coefficient >0.999. The kinetic modelling also indicates that the adsorption processes of BPA onto ACS are exothermic and proceed through a physical mechanism. A mass transfer study, using simplified models, proved that the process is controlled by intraparticle and film resistances to mass transfer of the BPA.
RESUMO
A Pseudomonas stutzeri strain acclimated to the presence of neoteric contaminants has been proposed for simultaneously remediating an effluent polluted with Polycyclic Aromatic Hydrocarbons and a diazo dye. The pollutants chemical nature imposed a strict control of both the medium composition and the operating conditions. pH, temperature and agitation rates of 7.0, 37.5 and 146 rpm, respectively, led to optimum levels of contaminant removal (higher than 60%) after RSM optimization. The validity of these conditions was checked at flask and bioreactor scale and the kinetics of the biotreatment was elucidated. The simulation of this one-step process applied at larger scale for the remediation of a 200,000 m(3)/year-effluent from a leather factory was compared with a conventional two-steps option. Great reductions in treatment times and in investment and manufacturing costs were concluded, proving the promising potential of the proposed process.
