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1.
Adv Mater ; 28(46): 10149-10154, 2016 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-27714926

RESUMO

A highly conductive, air stable and scalable poly(3,4-ethylenedioxythiophene) (PEDOT): poly(4-styrenesulfonate) (PEDOT:PSS) are prepared by using mass production ultrafiltration. By effectively removing excess PSS and various reaction impurities using repeated 100 nm pore membrane filtration, purified PEDOT:PSS exhibit conductivity as high as 2000 S cm-1 .

2.
J Nanosci Nanotechnol ; 16(5): 4565-9, 2016 May.
Artigo em Inglês | MEDLINE | ID: mdl-27483791

RESUMO

Aromatic hydrocarbons were produced from lignin, a complex natural amorphous polymer commonly regarded as by-product of the pulping process and from biofuel production. The catalytic decomposition of lignin using supported Pt catalysts was performed to produce small molecule hydrocarbons. Aromatic small-molecule hydrocarbon products were identified and quantified using GC/MS and GC-FID, which demonstrated that 27.6% of aromatic hydrocarbons were obtained from the activated carbon-supported Pt (Pt/AC) catalyst which had the highest Pt surface area.


Assuntos
Álcalis/química , Biocombustíveis , Hidrocarbonetos Aromáticos/síntese química , Lignina/química , Nanopartículas Metálicas/química , Platina/química , Catálise , Coloides/química , Conservação de Recursos Energéticos/métodos , Teste de Materiais , Tamanho da Partícula
3.
J Nanosci Nanotechnol ; 16(5): 4570-5, 2016 May.
Artigo em Inglês | MEDLINE | ID: mdl-27483792

RESUMO

Alkali lignin, a byproduct of the pulping process, was depolymerized using Pt nanoparticle catalysts. A depolymerized lignin with a lower molecular weight was obtained and characterized with GPC and NMR. 31P-NMR using OH-sensitive probing molecules showed the formation of guaiacyl OHs during the reaction, indicating the cleavage of guaiacyl ether bonds.


Assuntos
Álcalis/química , Lignina/química , Nanopartículas Metálicas/química , Platina/química , Polímeros/química , Catálise , Teste de Materiais , Nanopartículas Metálicas/ultraestrutura , Peso Molecular , Tamanho da Partícula , Viscosidade
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