Bio-efficacy of imidazolinones in weed control in a tropical paddy soil amended with optimized agrowaste-derived biochars.

Biochar is a black carbon sorbent that has the ability to stabilize organic substances in soil and, therefore, the potential to reduce their bio-availability. This sustainable material can be produced from locally-available agro wastes. The present study, for the first time, investigated the effects of biochars produced from oil palm empty fruit bunches (EFB) and rice husk (RH) on the efficiency of imazapic and imazapyr (two polar members of imidazolinone herbicides) as well as Onduty®, a mixture of them. It was executed in a Malaysian paddy field soil during a 30-day greenhouse experiment. The presence of optimized EFB and RH biochars in the heavy soil generally increases weed seeds germination and plants growth due to stabilization of the herbicides. The effect of EFB biochar was found higher than RH biochar having a higher affinity to the herbicides. An increase in the biochars application rates enhanced their effects as a soil modifier. Differences were more significant in the higher herbicides doses. Efficacies of all the herbicides were generally decreased in the biochar-amended soils. In the presence of 0.5% biochar in soil, the GR50 values for all herbicides were almost similar to biochar-free soil. In a 1.0% biochar-soil mixture, GR50 values of the herbicides increased by about 1.5 times. Bio-efficacies of the herbicides decreased by around 2.0 times as the biochar application rate enhanced to 2.0%. The greatest GR50 values were obtained in the presence of 4.0% biochar in the soils and were about 7.0-8.5 folds, indicating the high capability of amended soil in the stabilization of the herbicides. The findings of this study can help to reduce imidazolinones' pollution and, in this way, prevent the threats of their residues to the environment.

Enhancing the hydrophobicity of mangrove bark by esterification for oil adsorption.

Oil spills generally cause worldwide concern due to their detrimental effects on the environment and the economy. An assortment of commercial systems has been developed to control these spills, including the use of agricultural wastes as sorbents. This work deals with raw and modified mangrove barks (Rhizophora apiculata), an industrial lignocellulosic waste, as a low cost adsorbent for oil-product-spill cleanup in the aquatic environment. Mangrove bark was modified using fatty acids (oleic acid and palmitic acid) to improve its adsorption capacity. The oil sorption capacity of the modified bark was studied and compared with that of the raw bark. Kinetic tests were conducted with a series of contact times. The influence of particle size, oil dosage, pH and temperature on oil sorption capacity was investigated. The results showed that oleic acid treated bark has a higher sorption capacity (2,860.00 ± 2.00 mg/g) than untreated bark for Tapis crude oil. A correlation between surface functional groups, morphology and surface area of the adsorbent was studied by Fourier transform infrared spectrum, field emission scanning electron microscopy images and Brunauer-Emmett-Teller analysis. Isotherm study was conducted using the Langmuir and Freundlich isotherm models. The result showed that adsorption of crude oil on treated mangrove bark could be best described by the Langmuir model.