Natural surfactant mediated bioremediation approaches for contaminated soil.

The treatment of environmental pollution by employing microorganisms is a promising technology, termed bioremediation, which has several advantages over the other established conventional remediation techniques. Consequently, there is an urgent inevitability to develop pragmatic techniques for bioremediation, accompanied by the potency of detoxifying soil environments completely. The bioremediation of contaminated soils has been shown to be an alternative that could be an economically viable way to restore polluted soil. The soil environments have long been extremely polluted by a number of contaminants, like agrochemicals, polyaromatic hydrocarbons, heavy metals, emerging pollutants, etc. In order to achieve a quick remediation overcoming several difficulties the utility of biosurfactants became an excellent advancement and that is why, nowadays, the biosurfactant mediated recovery of soil is a focus of interest to the researcher of the environmental science field specifically. This review provides an outline of the present scenario of soil bioremediation by employing a microbial biosurfactant. In addition to this, a brief account of the pollutants is highlighted along with how they contaminate the soil. Finally, we address the future outlook for bioremediation technologies that can be executed with a superior efficiency to restore a polluted area, even though its practical applicability has been cultivated tremendously over the few decades.

Potential application of Micellar nanoreactor for electron transfer reactions mediated by a variety of oxidants: A review.

Surfactant, either natural or synthetic, forms a different type of aggregates among which 'Micelle' is truly an important dynamic surfactant aggregate, having a different region to interact with several organic, inorganic, and biomolecules; therefore the practical use of micelle is rapidly growing day-to-day. Surfactant-micelle, looks like a reactor of nano-dimension, govern a variety of reactions in aqueous media extensively. Oxidation is one of the vital reaction, take a part in the course of several organic transformations which are not very easy to execute in water media alone due to the solubility problem. Moreover, in order to achieve a quick transformation overcoming several difficulties the utility of micellar media became an excellent innovation, that's why nowadays, the surfactant and its aggregates are a focus of interest to the researcher of synthetic field and thus its practical applicability has been tremendously cultivated over the few decades. It is, therefore, useful to introduce some basic concepts regarding the aggregation of surfactants. Subsequently, we emphasize the importance of micellar media on the kinetics of oxidation reactions mediated by several metal ions with a special emphasis on their catalytic role.

Best combination of promoter and micellar catalyst for the rapid conversion of sorbitol to glucose.

Kinetic data for oxidation of D-sorbitol to glucose by hexavalent chromium in aqueous medium and aqueous surfactant medium (SDS, TX-100) have been reported. Effect of promoter such as PA, bipy and phenanthroline on the reaction has been investigated. The reaction is performed under pseudo first order condition with an excess of substrate over the oxidant. The reaction is first order with respect to substrate and oxidant. The micelles have a catalytic effect on the reaction. Combination of phen and TX-100 produces almost twelve times increase in rate of oxidation.

Combination of best promoter and micellar catalyst for more than kilo-fold rate acceleration in favor of chromic acid oxidation of D-galactose to D-galactonic acid in aqueous media at room temperature.

Picolinic acid, 2,2'-bipyridine and 1,10-phenanthroline promoted Cr(VI) oxidation of D-galactose to D-galactonic acid in three representative aqueous micellar media has been studied. The anionic surfactant (SDS) accelerated the rate of reaction while the cationic surfactant (CPC) and neutral surfactant (TX-100) retarded the reaction rate. Combination of bipy and SDS is the best choice for chromic acid oxidation of D-galactose to D-galactonic acid in aqueous media although 1,10-phenanthroline is best promoter in absence of micellar catalyst.