Bis{N-benzyl-N-[2-(thio-phen-2-yl)eth-yl]di-thio-carbamato-κ(2) S,S'}lead(II).

The mol-ecule of the title compound, [Pb(C14H14NS3)2], is located on a twofold rotation axis. The di-thio-carbamate anion S,S'-chelates to the Pb(II) atom, which shows a Ψ-trigonal-bipyramidal coordination. The thio-phene ring is disordered over two positions, the major component having 71.3 (7)% occupancy. The mol-ecular conformation is stabilized by intra-molecular C-H⋯S inter-actions.

Bis[N-benzyl-N-(2-phenyl-eth-yl)dithio-carbamato-κ(2)S,S']lead(II).

The mol-ecule of the title compound, [Pb(C(16)H(16)NS(2))(2)], is located on a twofold rotation axis, which runs through the Pb(II) atom. The two dithio-carbamate ligands coordinate the metal in a pyramidal configuration through the S atoms. The two phenyl rings of each dithocarbamate ligand are aligned at a dihedral angle of 78.4 (1)°. The mol-ecular conformation is stabilized by intra-molecular C-H⋯S inter-actions.