A seed-like structured Mo@ZrS2 catalyst on graphene nanosheets for boosting the performance of rechargeable Zn-air batteries.

Novel composite materials are being studied by researchers for energy storage and renewable energy applications. Here, a seed-like Mo-doped ZrS2 catalyst was developed on a reduced graphene oxide (rGO) surface by an annealing and hydrothermal method. Using photoelectron spectroscopy, scanning microscopy, and X-ray diffraction analyses, the structure of Mo@ZrS2/rGO and the impact of heteroatoms are demonstrated, providing insight into the catalyst. Furthermore, it is demonstrated that Mo@ZrS2/rGO has been utilized as an efficient energy storage electrocatalyst by offering a very low half-wave potential of 0.80 V for the oxygen reduction reaction in an alkaline solution. Furthermore, Zn-air batteries with a high-power density of 128.6 mW cm-2 and exceptional cycling stability are demonstrated by the developed array electrocatalyst. Ultimately, the research findings suggest novel perspectives on the structure of ZrS2 nanoseeds created by Mo surface doping, promote the usage of Zn-air batteries in practical scenarios, and offer a fascinating idea for creating a redox electrocatalyst.

Strong intramolecular charge-transfer effect strengthening naphthoquinone-based chemosensor: Experimental and theoretical evaluation.

An aminophenol-linked naphthoquinone-based fluorometric and colorimetric chemosensor 2-chloro-3-((3-hydroxyphenyl) amino) naphthalene-1,4-dione (2CAN-Dione) was synthesized for selective detection of Sn2+ ion in aqueous solution. The amine and conversion of carbonyl into carboxyl groups play a vital role in the sensing mechanism when Sn2+ is added to 2CAN-Dione. Comprehensive characterization of the sensor was carried out using standard spectral and analytical approaches. Because of the intramolecular charge transfer (ICT) effect and the turn-on sensing mode, the strong fluorometric emission towards Sn2+ was observed at about 435 nm. The chemosensor exhibited good selectivity for Sn2+ in the presence of coexisting metal ions. An improved linear connection was established with a low limit of detection (0.167 µM). FT-IR, 1H NMR, 13C NMR, and quantum chemistry methods were performed to verify the binding coordination mechanism. The chemosensing probe 2CAN-Dione was successfully employed in bioimaging investigations, demonstrating that it is a reliable fluorescent marker for Sn2+ in human cancer cells.