Multi-mode waveguides from ultra-long self-assembled hexagonal faceted microtubules of a benzothiadiazole molecule.

Length controlled (µm-mm-cm) self-assembly of hexagonal faceted microtubules has been achieved using a phase-transfer solution processing approach from . The self-assembled structures exhibit both polarized light emission and multi-mode waveguide properties over large length scales. The multi-mode waveguide characteristics are analyzed using a combination of experiment and finite-difference-time-domain calculations.

Synthesis of iron nanoparticles from hemoglobin and myoglobin.

Stable iron nanoparticles have been synthesized from naturally occurring and abundant Fe-containing bio-precursors, namely hemoglobin and myoglobin. The formation of stable iron nanoparticles was achieved through a one-pot, single-phase chemical reduction approach. The reduction of iron ions present in the bio-precursors was carried out at room temperature and avoids the use of harsh chemical reagents. The size distribution of the product falls into the narrow 2-5 nm range and the particles were found to be crystalline. This method can be a valuable synthetic approach for producing bio-conjugated nanoparticle systems for biological applications.

Chemical reaction mediated self-assembly of PTCDA into nanofibers.

Uniform and crystalline nanofibers of perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA), an insoluble organic semiconducting molecule, have been achieved by self-assembling the molecules using chemical reaction mediated conversion of an appropriately designed soluble precursor, perylene tetracarboxylic acid (PTCA) using carbodiimide chemistry.

Patterned color liquid crystal polymer polarizers.

We demonstrate patterned polarizers for visible wavelengths using dichroic dye in a liquid crystal polymer (LCP) host. Contact lithography is used to pattern a thin alignment layer, which subsequently transfers the pattern to the LCP. A gray dichroic dye mixture for the visible spectrum is optimized and implemented along with LCP to fabricate this polarizer. A peak extinction ratio of 41 was measured at a 633 nm wavelength, while simultaneously showing patterns as small as 3 µm. Finally, multi layer films are demonstrated by fabricating a two layer patterned circular polarizer consisting of a quarter-wave retarder and a color polarizer. Our process has applications in three-dimensional displays, interferometry, optical storage, and polarimeters.

Amphiphilicity-driven organization of nanoparticles into discrete assemblies.

We present a method for organizing metallic nanoparticles in solution that is based on the hydrophobic effect and does not require either hydrogen bonding or molecular recognition. When amphiphilic V-shaped molecules are attached to a gold cluster, an aggregation process ensues in aqueous solution and leads to the formation of well-defined cylindrical and vesicular nanoarrays of particles. The metallic clusters densely pack at the boundary separating the hydrophobic core from the hydrophilic corona of the hybrid micelle-like aggregates. This design allows one to assemble and disassemble the nanoparticles in a reversible manner and control the size and the morphology of the arrays by changing the conditions of the solution preparation. The versatility of this method is demonstrated by its applicability to different metals with covalently attached amphiphilic arms with various chemical compositions (PS-PEO and PB-PEO) and molecular weights.

Amphiphilic gold nanoparticles with V-shaped arms.

Here we describe a very efficient method to produce well-defined amphiphilic gold nanoparticles (Au NPs) with an equal number of hydrophobic and hydrophilic arms which are distributed along the surface of a 2-nm gold core in an alternating fashion. The strategy involves direct coupling of V-shaped block copolymer amphiphile 2 with a carboxylic group at its junction point to mercaptophenol-terminated Au NPs. The reaction proceeds under mild esterification conditions and yields the product with a molecular weight of 40 kDa, high grafting density (2.9 chains/nm2), and extremely low polydispersity (1.07). The big advantage of this approach is the opportunity to avoid the use of expensive and often inaccessible polymeric thiols. The method described here is applicable to any carboxyl-terminated molecules and can be used for the preparation of complex, yet well-defined, macromolecular hybrid structures such as 1 (Au(PB-PEG)n). The new product, which was characterized by a combination of SEC, NMR, UV-vis, DLS, and TEM, represents a unique example of gold nanoparticles soluble in any conventional solvent.

From small building blocks to complex molecular architecture.

[reaction: see text] We describe a synthesis of a dendrimer-like amphiphile containing a flat rigid core and 12 hydrophobic and hydrophilic arms. We employ a modular approach based on stepwise protection chemistry starting from simple building blocks. The key feature of this approach is the absence of a polymerization step, which makes it applicable for linear monofunctionalized precursors of any kind. This strategy also allows for precise control of the number of arms and ensures their alternating arrangement.