RESUMO
We present aspects of emerging optical activity in thin racemic 1,1'-Bi-2-naphthol films upon irradiation with circularly polarized light and subsequent resonant two-photon absorption in the sample. Thorough analysis of the sample morphology is conducted by means of (polarization-resolved) optical microscopy and scanning electron microscopy (SEM). The influence of crystallization on the nonlinear probing technique (second harmonic generation circular dichroism [SHG-CD]) is investigated. Optical activity and crystallization are brought together by a systematic investigation in different crystallization regimes. We find crystallization to be responsible for two counter-acting effects, which arise for different states of crystallization. Measuring crystallized samples offers the best signal-to-noise ratio, but it limits generation of optical activity due to self-assembly effects. For suppression of crystallization on the other hand, there is a clear indication that enantiomeric selective desorption is responsible for the generation of optical activity in the sample. We reach the current resolution limit of probing with SHG-CD, as we suppress the crystallization in the racemic sample during desorption. In addition, intensity-dependent measurements on the induced optical activity reveal an onset threshold (≈0.7 TW cm-2), above which higher order nonlinear processes impair the generation of optical activity by desorption with CPL.
