Microporous poly- and monocrystalline diamond films produced from chemical vapor deposited diamond-germanium composites.

We report on a novel method for porous diamond fabrication, which is based on the synthesis of diamond-germanium composite films followed by etching of the Ge component. The composites were grown by microwave plasma assisted CVD in CH4-H2-GeH4 mixtures on (100) silicon, and microcrystalline- and single-crystal diamond substrates. The structure and the phase composition of the films before and after etching were analyzed with scanning electron microscopy and Raman spectroscopy. The films revealed a bright emission of GeV color centers due to diamond doping with Ge, as evidenced by photoluminescence spectroscopy. The possible applications of the porous diamond films include thermal management, surfaces with superhydrophobic properties, chromatography, supercapacitors, etc.

Laser Ablated Nanocrystalline Diamond Membrane for Infrared Applications.

We are reporting on laser microstructuring of thin nanocrystalline diamond membranes, for the first time. To demonstrate the possibility of microstructuring, we fabricated a diamond membrane, of 9 µm thickness, with a two-dimensional periodic array of closely located chiral elements. We describe the fabrication technique and present the results of the measurements of the infrared transmission spectra of the fabricated membrane. We theoretically studied the reflection, transmission, and absorption spectra of a model structure that approximates the fabricated chiral metamembrane. We show that the metamembrane supports quasiguided modes, which appear in the optical spectra due to grating-assisted diffraction of the guided modes to the far field. Due to the C4 symmetry, the structure demonstrates circular dichroism in transmission. The developed technique can find applications in infrared photonics since diamond is transparent at wavelengths >6 µm and has record values of hardness. It paves the way for creation of new-generation infrared filters for circular polarization.

A new approach to precise mapping of local temperature fields in submicrometer aqueous volumes.

Nanodiamonds hosting temperature-sensing centers constitute a closed thermodynamic system. Such a system prevents direct contact of the temperature sensors with the environment making it an ideal environmental insensitive nanosized thermometer. A new design of a nanodiamond thermometer, based on a 500-nm luminescent nanodiamond embedded into the inner channel of a glass submicron pipette is reported. All-optical detection of temperature, based on spectral changes of the emission of "silicon-vacancy" centers with temperature, is used. We demonstrate the applicability of the thermometric tool to the study of temperature distribution near a local heater, placed in an aqueous medium. The calculated and experimental values of temperatures are shown to coincide within measurement error at gradients up to 20 °C/µm. Until now, temperature measurements on the submicron scale at such high gradients have not been performed. The new thermometric tool opens up unique opportunities to answer the urgent paradigm-shifting questions of cell physiology thermodynamics.

Fabry-Perot Pressure Sensors Based on Polycrystalline Diamond Membranes.

Pressure sensors based on diamond membranes were designed and tested for gas pressure measurement up to 6.8 MPa. The diamond film (2" diameter, 6 µm thickness)-grown by microwave plasma chemical vapor deposition on a silicon substrate-was a starting material to produce an array of membranes with different diameters in the 130-400 µm range, in order to optimize the sensor performance. Each 5 mm × 5 mm sensing element was obtained by subsequent silicon slicing. The fixed film thickness, full-scale pressure range, and sensor sensitivity were established by a proper design of the diameter of diamond membrane which represents the sensing element for differential pressure measurement. The pressure-induced deflection of the membrane was optically measured using a Fabry-Pérot interferometer formed by a single mode optical fiber front surface and the deflecting diamond film surface. The optical response of the system was numerically simulated using geometry and the elastic properties of the diamond diaphragm, and was compared with the experiments. Depending on the diamond membrane's diameter, the fabricated sensors displayed a good modulation depth of response over different full-scale ranges, from 3 to 300 bar. In view of the excellent mechanical, thermal, and chemical properties of diamond, such pressure sensors could be useful for performance in a harsh environment.

Thin Diamond Film on Silicon Substrates for Pressure Sensor Fabrication.

Thin polycrystalline diamond films chemically vapor deposited on thinned silicon substrates were used as membranes for pressure sensor fabrication by means of selective chemical etching of silicon. The sensing element is based on a simple low-finesse Fabry-Pérot (FP) interferometer. The FP cavity is defined by the end-face of a single mode fiber and the diamond diaphragm surface. Hence, pressure is evaluated by measuring the cavity length by an optoelectronic system coupled to the single mode fiber. Exploiting the excellent properties of Chemical Vapor Deposition (CVD) diamond, in terms of high hardness, low thermal expansion, and ultra-high thermal conductivity, the realized sensors have been characterized up to 16.5 MPa at room temperature. Preliminary characterizations demonstrate the feasibility of such diamond-on-Si membrane structure for pressure transduction. The proposed sensing system represents a valid alternative to conventional solutions, overcoming the drawback related to electromagnetic interference on the acquired weak signals generated by standard piezoelectric sensors.