Industrial impact on groundwater quality with special reference to Cr2+ and Pb2+ in coastal aquifers.

The present investigation has been carried out in the Ottapidaram taluk to evaluate the suitability of groundwater for drinking purposes and to assess the non-carcinogenic health risks. Twenty groundwater samples were collected, and the major physicochemical parameters were measured along with the heavy metals lead (Pb2+) and chromium (Cr2+). The analyzed anions and cations follow the average dominance order, Cl- > PO43- > SO42- > NO3- > F-, and Mg2+ > Ca2+ > Na+ > K+, respectively. From the water quality index to know the 45% of the water samples are unsuitable for drinking purposes. The statistical analysis of the data infers that major geochemical process of the region is leaching of salts by contaminated water, followed by industrial pollution and geogenic sources. The spatial representation of the different parameters reveals that the western part of the study area is predominated by geogenic sources and the eastern part is contaminated by industrial effluents. The non-carcinogenic risks of F-, NO3-, Cr2+, and Pb2+ were assessed. The findings show 40% of the samples exceeds the chromium hazard quotient, and 50% exceed the lead hazard quotient value of 1 recommended by the US Environmental Protection Agency (USEPA). The present investigation shows that Cr2+ and Pb2+ highly pollute the groundwater due to the industrial impacts. The present study suggests that the groundwater from this taluk is worse, and people from this taluk have health risks due to groundwater drinking.

Health Risk Assessment of Heavy Metals in Groundwater of Industrial Township Virudhunagar, Tamil Nadu, India.

The present investigation deals with the health risk assessment due to the heavy metals (Cd, Cr, Cu, Co, Mn, Pb, Ni, and Zn) in groundwater in the industrial township of Virudhunagar district. Twenty groundwater samples were collected, and the measured concentration of the heavy metals follows the order Pb > Ni > Zn > Co > Cr > Cd > Cu > Mn. The metal pollution indices (heavy metal evaluation index, Heavy metal pollution index, degree of contamination) were calculated using the measured heavy metal concentrations. The samples collected nearer to the industrial zone have elevated concentrations of Pb, Cd, and Ni. The carcinogenic and noncarcinogenic risks were calculated based on the measured heavy metals concentration and average daily intake of water. The calculated carcinogenic risk values (5.66 × 10-3-1.56 × 10-2) (Pb, Cd, and Ni) exceed the acceptable limit of 10-6-10-4. The noncarcinogenic risk exceeds the acceptable limit of one for the heavy metals Pb and Cr. The higher carcinogenic and noncarcinogenic risk values reveal that the study area has health risks due to Pb, Cd, Ni, and Cr metals. Furthermore, factor analysis and cluster analysis showed that the industrial impact and wastage dumpsites are the prime sources for heavy metal contamination in groundwater of the study area.