Silica aerogel cavity enhancement of spectral reflection from distributed Bragg reflectors with patterned surfaces.

Distributed Bragg reflectors (DBRs) can experience thermomechanical issues under an intense incident beam. A remedy for this issue is to pattern the DBR structure to facilitate thermal expansion in the structure. However, finite-size patterns reduce the design's electromagnetic performance, including the reflectivity amplitude and the operational bandwidth. Here, we introduce a silica aerogel cavity medium between the DBR layer and the substrate to increase the reflection by stimulating the cavity modes. By altering the cavity layer's thickness and the pattern width, the interference of reflected lights can be controlled and enhance the reflectivity at desired wavelengths. The results show a significant enhancement in the reflection by introducing the cavity in the design. For a comprehensive investigation of the mechanisms, the interaction of the DBR layers with the substrate, the effect of patterns, and the propagation of electric fields, especially in the cavity layer, are examined.

Broadband-Tunable Vanadium Dioxide (VO2)-Based Linear Optical Cavity Sensor.

Sensors fabricated by using a silicon-on-insulator (SOI) platform provide promising solutions to issues such as size, power consumption, wavelength-specific nature of end reflectors and difficulty to detect ternary mixture. To address these limitations, we proposed and investigated a broadband-thermally tunable vanadium dioxide (VO2)-based linear optical cavity sensor model using a finite element method. The proposed structure consists of a silicon wire waveguide on a silicon-on-insulator (SOI) platform terminated with phase-change vanadium oxide (VO2) on each side to provide light confinement. A smooth transmission modulation range of 0.8 (VO2 in the insulator state) and 0.03 (VO2 in the conductive phase state) in the 125 to 230 THz spectral region was obtained due to the of Fabry-Pérot (FP) effect. For the 3.84 µm cavity length, the presented sensor resulted in a sensitivity of 20.2 THz/RIU or 179.56 nm/RIU, which is approximately two orders of magnitude higher than its counterparts in the literature. The sensitivity of the 2D model showed direct relation with the length of the optical cavity. Moreover, the change in the resonating mode line width Δν of approximately 6.94 THz/RIU or 59.96 nm/RIU was also observed when the sensor was subjected to the change of the imaginary part k of complex refractive index (RI). This property of the sensor equips it for the sensing of aternary mixture without using any chemical surface modification. The proposed sensor haspotential applications in the areas of chemical industries, environmental monitoring and biomedical sensing.

Tungsten Based Spectrally Selective Absorbers with Anisotropic Rough Surface Texture.

Spectrally selective absorbers have received considerable interest due to their applications in thermophotovoltaic devices and as solar absorbers. Due to extreme operating conditions in these applications, such as high temperatures, thermo-mechanically stable and broadband spectrally selective absorbers are of interest. This paper demonstrates anisotropic random rough surfaces that provide broadband spectrally selective absorption for the thermo-mechanically stable Tungsten surfaces. Anisotropic random rough surface has different correlation lengths in the x- and y-directions, which means their topography parameters have directional dependence. In particular, we demonstrate that spectral absorptance of Tungsten random rough surfaces at visible (VIS) and near-infrared (NIR) spectral regions are sensitive to correlation length and RMS height variations. Our results indicate that by optimizing random rough surface parameters, absorption values exceeding 95% can be obtained. Moreover, our results indicate that anisotropic random rough surfaces broaden the bandwidth of the high absorption region. It is shown that in VIS and NIR regions, the absorption enhancements of up to 47% and 52% are achieved for the isotropic and anisotropic rough surfaces, respectively.

Synthesis and Morphological Control of VO2 Nanostructures via a One-Step Hydrothermal Method.

The morphology of nanostructures is a vital parameter to consider in components comprised of materials exhibiting specific functionalities. The number of process steps and the need for high temperatures can often be a limiting factor when targeting a specific morphology. Here, we demonstrate a repeatable synthesis of different morphologies of a highly crystalline monoclinic phase of vanadium dioxide (VO2(M)) using a one-step hydrothermal method. By adjusting the synthesis parameters, such as pH, temperature, and reducing agent concentration in the precursor, VO2 nanostructures with high uniformity and crystallinity are achieved. Some of these morphologies were obtained via the choice of the reducing agent that allowed us to skip the annealing step. Our results indicate that the morphologies of the nanostructures are very sensitive to the hydrazine hydrate (N2H4.H2O) concentration. Another reducing agent, dodecylamine, was used to achieve well-organized and high-quality VO2(M) nanotubes. Differential scanning calorimetry (DSC) experiments revealed that all samples display the monoclinic-to-tetragonal structural transition (MTST) regardless of the morphology, albeit at different temperatures that can be interpreted as the variations in overheating and undercooling limits. VO2(M) structures with a higher surface to volume ratio exhibit a higher overheating limit than those with low ratios.

Enhancing Spectral Reflection through Controlled Phase Distribution Using Doped Polar-Dielectric Metasurfaces.

Controlling the phase distribution of wavefronts using optical metasurfaces has led to interesting optical properties and applications. Here, we explore the control of phase distribution through polar-dielectric metasurfaces composed of doped SiC nanosphere arrays. We investigate the impact of doping concentration on the optical properties of SiC nano-spheres. Our results indicate that increasing the doping of SiC nanoparticles influenced electric dipolar resonances, whereas it did not change the dipolar resonances. Using this concept, we numerically studied the extension of this idea to form metasurface arrays of single, dimer and linear trimers of the doped SiC nano-spheres. Using different doping schemes, we studied the improvement of the reflectivity at frequencies greater than the longitudinal optical phonon frequency.

Surface Roughness Effects on the Broadband Reflection for Refractory Metals and Polar Dielectrics.

Random surface roughness and surface distortions occur inevitably because of various material processing and fabrication techniques. Tailoring and smoothing the surface roughness can be especially challenging for thermomechanically stable materials, including refractory metals, such as tungsten (W), and polar dielectrics, such as silicon carbide (SiC). The spectral reflectivity and emissivity of surfaces are significantly impacted by surface roughness effects. In this paper, we numerically investigated the surface roughness effects on the spectral reflectivity and emissivity of thermomechanically stable materials. Based on our results, we determined that surface roughness effects are strongly impacted by the correlation length of the Gaussian surface. In addition, our results indicate that surface roughness effects are stronger for the materials at the epsilon-near-zero region. Surface roughness effects are stronger between the visible and infrared spectral region for W and around the wavelength of 12 µ m for SiC, where plasma frequency and polar resonance frequency are located.

A Theoretical Treatment of THz Resonances in Semiconductor GaAs p-n Junctions.

Semiconductor heterostructures are suitable for the design and fabrication of terahertz (THz) plasmonic devices, due to their matching carrier densities. The classical dispersion relations in the current literature are derived for metal plasmonic materials, such as gold and silver, for which a homogeneous dielectric function is valid. Penetration of the electric fields into semiconductors induces locally varying charge densities and a spatially varying dielectric function is expected. While such an occurrence renders tunable THz plasmonics a possibility, it is crucial to understand the conditions under which propagating resonant conditions for the carriers occur, upon incidence of an electromagnetic radiation. In this manuscript, we derive a dispersion relation for a p-n heterojunction and apply the methodology to a GaAs p-n junction, a material of interest for optoelectronic devices. Considering symmetrically doped p- and n-type regions with equal width, the effect of certain parameters (such as doping and voltage bias) on the dispersion curve of the p-n heterojunction were investigated. Keeping in sight the different effective masses and mobilities of the carriers, we were able to obtain the conditions that yield identical dielectric functions for the p- and n-regions. Our results indicated that the p-n GaAs system can sustain propagating resonances and can be used as a layered plasmonic waveguide. The conditions under which this is feasible fall in the frequency region between the transverse optical phonon resonance of GaAs and the traditional cut-off frequency of the diode waveguide. In addition, our results indicated when the excitation was slightly above the phonon resonance frequency, the plasmon propagation attained low-loss characteristics. We also showed that the existence or nonexistence of the depletion zone between the p- and n- interfaces allowed certain plasmon modes to propagate, while others decayed rapidly, pointing out the possibility for a design of selective filters.

Focusing short-wavelength surface plasmons by a plasmonic mirror.

Emerging applications in nanotechnology, such as superresolution imaging, ultra-sensitive biomedical detection, and heat-assisted magnetic recording, require plasmonic devices that can generate intense optical spots beyond the diffraction limit. One of the important drawbacks of surface plasmon focusing structures is their complex design, which is significant for ease of integration with other nanostructures and fabrication at low cost. In this study, a planar plasmonic mirror without any nanoscale features is investigated that can focus surface plasmons to produce intense optical spots having lateral and vertical dimensions of λ/9.7 and λ/80, respectively. Intense optical spots beyond the diffraction limit were produced from the plasmonic parabolic mirror by exciting short-wavelength surface plasmons. The refractive index and numerical aperture of the plasmonic parabolic mirror were varied to excite short-wavelength surface plasmons. Finite-element method simulations of the plasmonic mirror and scanning near-field optical microscopy experiments have shown very good agreement.

Entropy Generation Analysis of Laminar Flows of Water-Based Nanofluids in Horizontal Minitubes under Constant Heat Flux Conditions.

During the last decade, second law analysis via entropy generation has become important in terms of entropy generation minimization (EGM), thermal engineering system design, irreversibility, and energy saving. In this study, heat transfer and entropy generation characteristics of flows of multi-walled carbon nanotube-based nanofluids were investigated in horizontal minitubes with outer and inner diameters of ~1067 and ~889 µm, respectively. Carbon nanotubes (CNTs) with outer diameter of 10-20 nm and length of 1-2 µm were used for nanofluid preparation, and water was considered as the base fluid. The entropy generation based on the experimental data, a significant parameter in thermal design system, was examined for CNTs/water nanofluids. The change in the entropy generation was only seen at low mass fractions (0.25 wt.% and 0.5 wt.%). Moreover, to have more insight on the entropy generation of nanofluids based on the experimental data, a further analysis was performed on Al2O3 and TiO2 nanoparticles/water nanofluids from the experimental database of the previous study of the authors. The corresponding results disclosed a remarkable increase in the entropy generation rate when Al2O3 and TiO2 nanoparticles were added to the base fluid.

Tunable Surface Plasmon and Phonon Polariton Interactions for Moderately Doped Semiconductor Surfaces.

Spatial charge distribution for biased semiconductors fundamentally differs from metals since they can allow inhomogeneous charge distributions due to penetration of the electric field, as observed in the classical Schottky junctions. Similarly, the electrostatics of the dielectric/semiconductor interface can lead to a carrier depletion or accumulation in the semiconductor side when under applied bias. In this study, we demonstrate that the inhomogeneous carrier accumulation in a moderately p-doped GaAs-dielectric interface can be tailored for tunable plasmonics by an external voltage. Solving Maxwell's equations in the doped GaAs-dielectric stack, we investigate the tunability of the surface plasmon and phonon polaritons' interaction via an external bias. The plasmonic mode analysis of such an interface reveals interesting dispersion curves for surface plasmon and phonon polariton interactions that are not possible in metals. We show that the plasmon dispersion curve can be engineered through an external bias using the inherent properties of the p-doped GaAs- dielectric interface.

Plasmonic spiderweb nanoantenna surface for broadband hotspot generation.

In this study, we demonstrate a general framework for obtaining a plasmonic nanoantenna surface with a broadband polarization-independent response. The plasmonic spiderweb nanoantenna surface is composed of unit cells, which form multiple resonance paths due to patterning of the metallic conductor such that electrons can find multiple ways to oscillate between the poles of the conductor. The tailoring of the conductor paths and shapes of the unit cells' patterns results in a broadband spectral response. At various resonance frequencies, the electrons oscillate along different paths between the poles of the antenna, generating broadband hot spots around those poles.

Absorption efficiency enhancement in inorganic and organic thin film solar cells via plasmonic honeycomb nanoantenna arrays.

We demonstrate theoretically that by embedding plasmonic honeycomb nanoantenna arrays into the active layers of inorganic (c-Si) and organic (P3HT:PCBM/PEDOT:PSS) thin film solar cells, absorption efficiency can be improved. To obtain the solar cell absorption spectrum that conforms to the solar radiation, spectral broadening is achieved by breaking the symmetry within the Wigner-Seitz unit cell on a uniform hexagonal grid. For optimized honeycomb designs, absorption efficiency enhancements of 106.2% and 20.8% are achieved for c-Si and P3HT:PCBM/PEDOT:PSS thin film solar cells, respectively. We have demonstrated that the transverse modes are responsible for the enhancement in c-Si solar cells, whereas both the longitudinal and transverse modes, albeit weaker, are the main enhancement mechanisms for P3HT:PCBM/PEDOT:PSS solar cells. For both inorganic and organic solar cells, the absorption enhancement is independent of polarization.

Unidirectional broadband radiation of honeycomb plasmonic antenna array with broken symmetry.

Emerging plasmonic and photovoltaic applications benefit from effective interaction between optical antennas and unidirectional incident light over a wide spectrum. Here, we propose a honeycomb array of plasmonic nanoantennas with broken symmetry to obtain a unidirectional radiation pattern over a wide spectrum. The honeycomb nanoantenna array is based on a hexagonal grid with periodically arranged nanostructure building blocks. To analyze the far-field optical distribution and spectral behavior of the plasmonic antenna honeycomb, a two-dimensional Wigner-Seitz unit cell is used together with periodic boundary conditions. As a result of the vectoral superposition of the fields produced by the Wigner-Seitz unit cells, far-zone optical fields interfere constructively or destructively in different directions. The constructive interference along the array's normal direction engenders unidirectional radiation. Due to the broken symmetry of the Wigner-Seitz cell, multiple resonances are supported by the plasmonic antenna honeycomb array over a broad spectrum.

Broadband plasmonic nanoantenna with an adjustable spectral response.

Six-particle and eight-particle common-gap plasmonic nanoantennas are utilized to obtain a broadband spectral response when illuminated with circular and elliptical polarization. Due to the insensitivity of dipole antennas to circular polarization, the resonant structures are brought together around the common-gap to expand the spectrum of the whole system. Their ability to focus light at different frequencies is demonstrated. The spectral response is manipulated by geometrical parameters and the strength of the spectral peaks is tailored through the ellipticity of the elliptically polarized light.

Perpendicular oriented single-pole nano-optical transducer.

Nano-optical transducers have been utilized in existing and emerging applications due to their ability to obtain small optical spots, large transmission efficiency, and narrow and adjustable spectral response. In emerging nano-optical applications, such as heat assisted magnetic recording (HAMR), these features are not sufficient. For example, in HAMR a transducer should also satisfy additional requirements, such as massproduction and integrability with other device components. In this study, the basic principles of Maxwell's equations and image theory for good metals are utilized to design a perpendicular oriented single-pole nano-optical transducer, which can be integrated into the manufacturing technologies of current hard disk drive heads. The perpendicular oriented single-pole nano-optical transducer is investigated using 3-D finite element method. Gold transducers are investigated for both longitudinal and perpendicular orientations. The optical intensity profiles and spot sizes of longitudinal and perpendicular oriented transducers are compared for various fly heights. It is shown that a perpendicular ridge waveguide provides localized optical spots with intensities comparable to longitudinal transducers.

Interaction of radially polarized focused light with a prolate spheroidal nanoparticle.

The interaction of a nanoparticle with light is affected by nanoparticle geometry and composition, as well as by focused beam parameters, such as the polarization and numerical aperture of the beam. The interaction of a radially focused beam with a prolate spheroidal nanoparticle is particularly important because it has the potential to produce strong near-field electromagnetic radiation. Strong and tightly localized longitudinal components of a radially polarized focused beam can excite strong plasmon modes on elongated nanoparticles such as prolate spheroids. In this study, near field radiation from a prolate spheriodal nanoparticle is investigated when it is illuminated with a radially polarized focused beam of light. Near-field radiation from the nanoparticle is investigated in the absence and presence of metallic layers. It is shown that the interaction of a radially polarized focused beam with a prolate spheroidal nanoparticle can be enhanced by creating images of monopole charges using metallic layers. In addition, it is also observed that the presence of a metallic layer shifts the resonance of the prolate spheroid toward longer wavelengths. Dipole, quadruple, and off resonance field distributions for particles with different sizes and aspect ratios are presented when they are illuminated with a radially focused beam of light.

An integral equation based numerical solution for nanoparticles illuminated with collimated and focused light.

To address the large number of parameters involved in nano-optical problems, a more efficient computational method is necessary. An integral equation based numerical solution is developed when the particles are illuminated with collimated and focused incident beams. The solution procedure uses the method of weighted residuals, in which the integral equation is reduced to a matrix equation and then solved for the unknown electric field distribution. In the solution procedure, the effects of the surrounding medium and boundaries are taken into account using a Green's function formulation. Therefore, there is no additional error due to artificial boundary conditions unlike differential equation based techniques, such as finite difference time domain and finite element method. In this formulation, only the scattering nano-particle is discretized. Such an approach results in a lesser number of unknowns in the resulting matrix equation. The results are compared to the analytical Mie series solution for spherical particles, as well as to the finite element method for rectangular metallic particles. The Richards-Wolf vector field equations are combined with the integral equation based formulation to model the interaction of nanoparticles with linearly and radially polarized incident focused beams.

Interaction of spherical nanoparticles with a highly focused beam of light.

The interaction of a highly focused beam of light with spherical nanoparticles is investigated for linear and radial polarizations. An analytical solution is obtained to calculate this interaction. The Richards-Wolf theory is used to express the incident electric field near the focus of an aplanatic lens. The incident beam is expressed as an integral where the integrand is separated into transverse-electric (TE) and transverse-magnetic (TM) waves. The interaction of each TE and TM wave with a spherical nanoparticle is calculated using the Mie theory. The resulting analytical solution is then obtained by integrating the scattered waves over the entire angular spectrum. A finite element method solution is also obtained for comparison.

Near-field radiation from a ridge waveguide transducer in the vicinity of a solid immersion lens.

A near-field optical system is investigated to improve the transmission efficiency of near-field transducers. A ridge waveguide is placed adjacent to a solid immersion lens (SIL) but separated by a low-index dielectric layer. The incident electric field near the focus of the SIL is determined by the Richards-Wolf vector field equations. The finite element method is used to solve Maxwell's equations. A spot size of 31 nm is obtained. The maximum value of the absorbed optical power density in the recording medium is 7.51 x 10(-4) mW/nm3 for a 100 mW input power.