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The physicochemical properties of clathrate hydrates are influenced by the chemical nature and three-dimensional (3D) geometry of the added molecules. This study investigates the effects of five oxirane compounds: cis-2,3-epoxybutane (c23EB), trans-2,3-epoxybutane (t23EB), 1,2-epoxybutane (12EB), 1,2,3,4-diepoxybutane (DEB), and 3,3-dimethylepoxybutane (33DMEB) on CH4 hydrate formation. Despite having a four-carbon backbone, these compounds differ in their 3D geometries. The structures and stabilities of CH4 hydrates containing each compound were analyzed using high-resolution powder diffraction, solid-state 13C NMR, and phase equilibrium measurements. The experimental results revealed that c23EB, 12EB, and 33DMEB act as sII/sH hydrate formers and thermodynamic promoters, whereas t23EB and DEB have opposite roles. These results were analyzed in relation to the 3D geometries and relative stabilities of various rotational isomers using DFT calculations. Hydrate structure was influenced by both the length and thickness of the added compounds. Moreover, an appropriate level of (not excessive) hydrophilicity induced by an oxirane group appeared to enhance the thermodynamic stability of the hydrates. This study provides insights into how the chemical nature of additives influences the structure and stability of clathrate hydrates.
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In this study, we investigate three oxabicyclic compounds, 3,6-dioxabicyclo[3. 1.0]hexane (C4H6O2, ETHF), 7-oxabicyclo[2.2.1]heptane (C6H10O, 14ECH), and 7-oxabicyclo[4.1.0]heptane (C6H10O, 12ECH) as novel promoters for gas hydrates. According to the outcomes of powder X-ray diffraction (PXRD) and synchrotron high-resolution powder diffraction (HRPD), all CH4 hydrates formed with ETHF, 14ECH, and 12ECH were identified to be sII (Fd-3m) hydrates with corresponding lattice parameters of 17.195, 17.330, and 17.382 Å, respectively. It was also clearly demonstrated that CH4 molecules are accommodated in the sII-S cages through solid-state 13C NMR and Raman spectra. Consequently, we clarified that the three compounds observed are large guest molecules (LGMs) that occupy the sII-L cages. Moreover, the thermodynamic stability of each LGM + CH4 (and N2) hydrate system was remarkably improved compared to that of the simple CH4 (and N2) hydrate. In particular, 14ECH manifested several unique features compared to the other two promoters. First, the 14ECH + CH4 hydrate did not dissociate up to room temperature (298 K), even at a moderate pressure of approximately 60 bar. At a given pressure, 14ECH increased the dissociation temperature of the CH4 hydrate by ~18 K, indicating that its promotion capability is as strong as that of tetrahydrofuran (THF), currently considered to be the most powerful promoter. Second, more interestingly, it was revealed by further PXRD, NMR, and Raman analyses that 14ECH forms a simple sII hydrate in the absence of help gases. According to differential scanning calorimetry (DSC) outcomes, we revealed that the simple 14ECH hydrate dissociates at 270~278 K under ambient pressure. In addition to the thermodynamic stability, we also note that the 14ECH + CH4 hydrate presented a sufficiently high temperature of formation, requiring little additional cooling. Given these promising features, we expect that the 14ECH hydrate system can be adopted to realize hydrate-based technologies. We also believe that the LGMs introduced here have considerable potential to serve as alternates to conventional promoters and that they can be widely utilized in both engineering and scientific research fields.
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We suggest epoxycyclopentane (ECP) as a novel guest compound for hydrate-based energy storage. All of the key properties of the ECP hydrate, including the thermodynamic stability, storage capacity, and formation condition, are notably superior to those of hydrates containing tetrahydrofuran (THF) and cyclopentane (CP), currently considered to be the most powerful promoters.
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This study focuses on the cage occupancy of guest molecules in the infinitely dilute state. At the extreme conditions of highly diluted guest concentrations the direct measurements of the cage occupancy ratio representing the competitive inclusion of multiguest species appear to be so difficult because of spectroscopic intensity limitation, but its thermodynamic significance might be considerable due to the fact that the infinite-dilution value of the cage occupancy ratio can provide the valuable thermodynamic information as a very unique and guest-specific parameter. To experimentally identify gaseous guest populations in structure I (sI) and structure II (sII) cages, we used the solid-state nuclear magnetic resonance (NMR), gas chromatography, and direct gas measurements. Furthermore, we derived the simple and generalized thermodynamic equation related to cage occupancies at infinite dilution from the van der Waals-Platteeuw model. Both experimental and predicted values agree well within the experimental error range.
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Magnetic molecules physisorbed into low-dimensional nanostructures of microporous materials such as graphite and metal-organic frameworks have been verified to exhibit an unusual magnetic behavior. We demonstrate that the selective injection of both magnetic and nonmagnetic guest molecules into the water-ice cages of clathrate hydrates to form a 3D superstructure with tetrahedral and diamond-like sublattices can modify the inherent magnetism.
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Natural methane hydrates occurring in marine clay sediments exhibit heterogeneous phase behavior with high complexity, particularly in the negatively charged interlayer region. To date, the real clay interlayer effect on natural methane hydrate formation and stability remains still much unanswered, even though a few computer simulation and model studies are reported. We first examined the chemical shift difference of 27Al, 29Si, and 23Na between dry clay and clay containing intercalated methane hydrates (MH) in the interlayer. We also measured the solid-state 13C MAS NMR spectra of MH in Na-montmorillonite (MMT) and Ca-montmorillonite (MMT) to reveal abnormal methane popularity established in the course of intercalation and further performed cryo-TEM and XRD analyses to identify the morphology and layered structure of the intercalated methane hydrate. The present findings strongly suggest that the real methane amount contained in natural MH deposits should be reevaluated under consideration of the compositional, structural, and physical characteristics of clay-rich sediments. Furthermore, the intercalated methane hydrate structure should be seriously considered for developing the in situ production technologies of the deep-ocean methane hydrate.
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A hydrogen molecule entrapped in the cages of icy hydrogen hydrate is confined in host water framework and thus behaves unlike pure solid or liquid hydrogen. The gamma-irradiated hydrogen radicals are for the first time observed from ESR and solid-state MAS 1H NMR spectra to stably exist in the icy hydrate channels without any collapse of the host framework, confirming the chemical shift consistency of ionized hydrogen derivatives. We discuss the confined icy hydrate channels, which can act as potential storage sites for simultaneously imprisoning both molecular and ionized hydrogen and further as icy nanoreactors.
Assuntos
Hidrogênio/química , Água/química , Espectroscopia de Ressonância de Spin Eletrônica , Radicais Livres/química , Gelo , Espectroscopia de Ressonância Magnética , Modelos MolecularesRESUMO
We first report here that under strong surrounding gas of external CH4 guest molecules the sII and sH methane hydrates are structurally transformed to the crystalline framework of sI, leading to a favorable change of the lattice dimension of the host-guest networks. The high power decoupling 13C NMR and Raman spectroscopies were used to identify structure transitions of the mixed CH4 + C2H6 hydrates (sII) and hydrocarbons (methylcyclohexane, isopentane) + CH4 hydrates (sH). The present findings might be expected to provide rational evidences regarding the preponderant occurrence of naturally occurring sI methane hydrates in marine sediments. More importantly, we note that the unique and cage-specific swapping pattern of multiguests is expected to provide a new insight for better understanding the inclusion phenomena of clathrate materials.