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1.
Acta Crystallogr B Struct Sci Cryst Eng Mater ; 79(Pt 1): 73-77, 2023 Feb 01.
Artigo em Inglês | MEDLINE | ID: mdl-36748900

RESUMO

Carbon doping is studied in MgB2 pellets during one-step synthesis by solid-state reaction, employing both undoped and carbon-doped boron with and without the addition of nano-SiC. The phase formation during the synthesis as a function of time was followed using powder X-ray diffraction and Rietveld refinement. The superconducting properties were characterized with a magnetometer to investigate doping-induced changes. Mg(B1-xCx)2 is obtained with nano-precipitates and different compositions depending on the synthesis temperature. It is found that the addition of nano-SiC prevents the phase formation at low temperature (700°C). Nevertheless, the best superconducting properties are obtained for the sample treated at 900°C using simultaneously C and SiC, with a critical current density of 105 A cm-2 at 3 T and 20 K, named the 900-20-C-nanoSiC sample.

2.
Nat Mater ; 3(7): 439-43, 2004 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-15170180

RESUMO

There are numerous potential applications for superconducting tapes based on YBa(2)Cu(3)O(7-x) (YBCO) films coated onto metallic substrates. A long-established goal of more than 15 years has been to understand the magnetic-flux pinning mechanisms that allow films to maintain high current densities out to high magnetic fields. In fact, films carry one to two orders of magnitude higher current densities than any other form of the material. For this reason, the idea of further improving pinning has received little attention. Now that commercialization of YBCO-tape conductors is much closer, an important goal for both better performance and lower fabrication costs is to achieve enhanced pinning in a practical way. In this work, we demonstrate a simple and industrially scaleable route that yields a 1.5-5-fold improvement in the in-magnetic-field current densities of conductors that are already of high quality.

3.
J Nanosci Nanotechnol ; 4(1-2): 189-91, 2004.
Artigo em Inglês | MEDLINE | ID: mdl-15112565

RESUMO

We report the formation of pile networks by long carbon nanotubes grown at 700 degrees C from a Co-Mo film on a quartz plate. Carbon monoxide (CO) was used as the carbon source. The networks were formed because the density of catalyst particles on the substrate was low, which resulted in low carbon nanotube density that did not support vertical growth. At the same time, the low carbon nanotube density makes it possible for CO to reach the catalysts on the substrate for continuous growth. No obvious amorphous carbon chunks were observed, suggesting that the pile networks consisted of fairly high-quality, long carbon nanotubes.


Assuntos
Monóxido de Carbono/química , Cristalização/métodos , Teste de Materiais , Molibdênio/química , Nanotecnologia/métodos , Nanotubos de Carbono/química , Nanotubos de Carbono/ultraestrutura , Adsorção , Temperatura Alta , Substâncias Macromoleculares , Membranas Artificiais , Conformação Molecular , Propriedades de Superfície
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