Effective role of tannic acid in the fabrication of hydrophobic, oleophilic, antibacterial, boron nitride/chlorobutyl rubber nanocomposite for reusable protective clothing and oil-water separation.

Boron Nitride (h-BN) possesses unique qualities like increased thermal conductivity, non-toxic nature, and environmental friendliness; hence, it is a good reinforcing agent for chlorobutyl rubber (CIIR). Tannic acid (TA) holds excellent bio-functional properties and is considered as an exceptional bio-exfoliating agent. Hence, in this study, we have utilized the bio-exfoliating ability of TA to exfoliate h-BN and evaluate its efficiency in reinforcing the CIIR matrix. Results demonstrate the exceptional role of tannic acid in imparting multifunctionality to chlorobutyl rubber. CIIR matrix introduced with h-BN:TA (h-BN:TA/CIIR) display excellent mechanical performance due to the reinforcing effect shown by excess TA in addition to the exfoliating effect. In addition, h-BN:TA/CIIR composite exhibited superior antimicrobial activity against S. aureus. The retention of thermal decontamination efficiency of the composites with increase in the number of cycles ensures their promising application in the field of reusable gloves and chemical protective clothing. The exfoliated filler created a tortuous path inside the matrix which prevents the permeation of solvent. Hence the work intends to synergize the hydrophobic nature of h-BN, exfoliating capacity of TA and the barrier abilities of CIIR for the adsorption of oil from oil-water mixture and portrays the future of the trio in water purification.

Multifunctional role of tannic acid in improving the mechanical, thermal and antimicrobial properties of natural rubber-molybdenum disulfide nanocomposites.

Natural rubber is the only biosynthesized rubber and the most prominent of all the elastomers. Insertion of nanofillers into natural rubber matrix has received much research interest because of the enhanced mechanical, thermal, electrical, antibacterial, etc. properties of the final natural rubber nanocomposite. Molybdenum disulfide (MoS2), an important member in transition metal dichalcogenides (TMD) is having excellent optical, thermal, mechanical, electronic and antibacterial properties. The inherent properties of this novel filler was exploited through the preparation of natural rubber-MoS2 nanocomposites via latex dipping method in which tannic acid (TA), naturally occurring macromolecule was used as an exfoliating agent for MoS2. MoS2:TA dispersions were prepared in 1:2, 1:4 and 1:6 ratios by mechanical stirring followed by sonication method for analyzing the optimum amount of exfoliating agent for the preparation of NR-MoS2 nanocomposite. MoS2:TA in 1:4 ratio was found to be the optimum loading for the NR nanocomposite preparation with improved mechanical, thermal and antibacterial properties. The enhanced properties of the NR composites could be attributed to the synergistic effect of both MoS2 and TA. The current study shows the role of TA in tuning the properties of NR/MoS2 nanocomposites that enable their potential utilization in various biomedical applications.

MoS2 based nanomaterials: Advanced antibacterial agents for future.

Bacterial infections are yet another serious threat to human health. Misuse or overuse of conventional antibiotics has led to the arrival of various super resistant bacteria along with many serious side effects to human body. In this exigent circumstance, the use of nanomaterial based antibacterial agents is one of the most appropriate solutions to fight against bacteria thereby causing an inhibition to bacterial proliferation. Recent studies show that, due to the large surface area, high biocompatibility, strong near-infrared (NIR) absorption and low cytotoxicity, molybdenum disulphide (MoS2), an extraordinary member in the transition metal dichalcogenides (TMDs) is extensively explored in the obliteration of many drug resistant bacteria, photothermal therapy and drug delivery. MoS2 based nanomaterials can effectively prevent bacterial growth through many mechanisms. Through this review, we have tried to provide an inclusive knowledge on the recent progress of antibacterial studies in MoS2 based nanomaterials including MoS2 nanosheets, nanoflowers, quantum dot (QD), hybrid nanocomposites and polymer nanocomposites. Moreover, toxicity of MoS2 based nanomaterials is described at the end of the review.

A comprehensive review on the recent advancements in natural rubber nanocomposites.

Natural rubber (NR) is an eminent sustainable material and is the only agricultural product among various rubbers. Use of nanofillers in NR matrix as a reinforcing agent has gained huge attention because they offer excellent matrix-filler interaction upon forming a good dispersion in the NR matrix. Nanoscale dispersion of fillers lead to greater interfacial interactions between NR and fillers compared to microfillers, which in turn lead to a conspicuous reinforcing effect. Addition of various nanofillers into NR matrix improves not only the mechanical properties but also the electrical, thermal and antimicrobial properties to an extreme level. The current review describes the reinforcing ability of various nanofillers such as clay, graphene, carbon nanotube (CNT), titanium dioxide (TiO2), chitin, cellulose, barium titanate (BaTiO3) and lignin in NR matrix. Moreover, reinforcement of various hybrid nanofillers in NR is also discussed in a comprehensive manner. The review also includes the historical trajectory of rubber nanocomposites and a comprehensive account on the factors affecting the properties of the NR nanocomposites.