Utilization of rice production residues as a reinforcing agent in bioadhesives based on polyphenols extracted from the bark of trees from the Brazilian Cerrado biome.

The scarcity of nonrenewable resources and the increase in environmental pollution have intensified the search for materials that exhibit specific characteristics and are nontoxic, renewable, and sustainable. Thus, the objective of this work was to produce natural polyphenol adhesives reinforced with rice husk and its ash to increase the mechanical resistance and moisture resistance of the glue line in wood bonded joints. Polyphenols were extracted from the bark of Stryphnodendron adstringens (Mart.) Coville (barbatimão). Adhesives were produced with a 50 % solid and 50 % liquid composition. Rice husk and husk ash underwent X-ray fluorescence analysis (XRF). Adhesives and reinforcement material were characterized by Fourier transform infrared (FTIR) and thermogravimetric analyses (TGA). The adhesives were glued in a mechanical press in specimens made of Pinus elliottii, which were subjected to shear testing of the wet and dry glue line. As a result, the chemical components present in rice husk and its ash positively influenced the properties of the adhesives. The mechanical glue line shear test showed that the adhesive reinforced with rice husk ash did not show a statistically significant difference. However, natural adhesives based on polyphenols from barbatimão strengthened with rice husk and ash showed improved properties, demonstrating how much it pays to use the residue of rice production to reinforce the matrix of tannin adhesives. Thus, it can be determined that reinforcement with rice husk and ash is efficient in improving some properties of natural adhesives based on polyphenols.

Effect of different pre-treatments on the redispersion capacity of spray-dried microfibrillated cellulose: Elaboration and characterization of biofilms.

This study aimed to evaluate the influence of the addition of the cationic surfactant cetyltrimethylammonium bromide (CTAB) in microfibrillated cellulose (MFC/CNFs) suspensions submitted to different pretreatments to produce redispersible spray-dried (SD) MFC/CNFs. Suspensions pretreated with 5 % and 10 % sodium silicate and oxidized with 2,2,6,6,-tetramethylpiperidinyl-1-oxyl (TEMPO) were modified with CTAB surfactant and subsequently dried by SD. The SD-MFC/CNFs aggregates were redispersed by ultrasound to produce cellulosic films by the casting method. In summary, the results demonstrated that the addition of CTAB surfactant to the TEMPO-oxidized suspension was critical to achieving the most effective redispersion. The experimental results obtained using micrographs, optical (UV-Vis), mechanical, water vapor barrier properties, and the quality index confirmed that the addition of CTAB to the TEMPO-oxidized suspension favored the redispersion of spray-dried aggregates, development of cellulosic films with attractive properties, offering possibilities for the elaboration of new products, for example, in the production of bionanocomposites with higher mechanical performance. This research brings interesting insights into the redispersion and application of SD-MFC/CNFs aggregates, strengthening the commercialization of MFC/CNFs for industrial use.

Substitution of petrochemical compounds for polyphenols of natural origin reinforced with cellulose nanofibrils to formulate adhesives for wood bonding.

Vegetable tannins are excellent options to produce adhesives for the panel industry since they have the capacity to reduce formaldehyde emissions and are derived from renewable sources. They also allow for the possibility of increasing the resistance of the glue line through the use of natural reinforcements such as cellulose nanofibrils. Condensed tannins, polyphenols isolated from tree bark, are widely studied for the production of natural adhesives as an alternative to commercial synthetic adhesives. So, the purpose of our research is to show a natural adhesive alternative for wood bonding. Therefore, the objective of the study was to evaluate the quality of tannin adhesives of different species reinforced with different nanofibrils and thus predict which adhesive is the most promising at different concentrations of reinforcement and with different types of polyphenols. To meet this objective, polyphenols were extracted from the bark, nanofibrils were obtained, and both processes followed the current standards. Then, the adhesives were produced, their properties were characterized, and they were chemically analyzed via Fourier transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA). A mechanical shear analysis of the glue line was also performed. According to the results, the addition of cellulose nanofibrils affected the physical properties of the adhesives, mostly the content of solids and the gel time. In the FTIR spectra, the OH band of the 5% Pinus and 5% Eucalyptus (EUC) TEMPO in the barbatimao adhesive and the 5% EUC of the cumate red adhesive were reduced, possibly due to their higher moisture resistance. Mechanical tests of the glue line showed that barbatimao with 5% Pinus and cumate red with 5% EUC performed best in the dry and wet shear tests. The control was the best-performing sample in the test of the commercial adhesives. The cellulose nanofibrils used as reinforcement did not change the thermal resistance of the adhesives. Therefore, the addition of cellulose nanofibrils to these tannins is an interesting means of increasing the mechanical strength, as occurred in commercial adhesive with 5% EUC. Thus, the physical and mechanical properties of tannin adhesives were better with reinforcement, making it possible to expand the use of these adhesives in the panel industry. At the industrial level, it is important to replace synthetic products with natural ones. Besides environmental and health issues, there is the question of the value of petroleum-based products, which have been widely studied so that they can be replaced.

Mandacaru cactus as a source of nanofibrillated cellulose for nanopaper production.

In this work, nanofibrillated cellulose (NFC) was extracted from cactus Cereus jamacaru DC. (mandacaru) for nanopaper production. The technique adopted includes alkaline treatment, bleaching, and grinding treatment. The NFC was characterized according to its properties and scored based on a quality index. Particle homogeneity, turbidity, and microstructure of the suspensions were evaluated. Correspondingly, the optical and physical-mechanical properties of the nanopapers were investigated. The chemical constituents of the material were analyzed. The sedimentation test and the zeta potential analyzed the stability of the NFC suspension. The morphological investigation was performed using environmental scanning electron microscopy (ESEM) and transmission electron microscopy (TEM). X-ray diffraction (XRD) analysis revealed that Mandacaru NFC has high crystallinity. Thermogravimetric analysis (TGA) and mechanical analysis were also used and revealed good thermal stability and good mechanical properties of the material. Therefore, the application of mandacaru is interesting in sectors such as packaging and electronic device development, as well as in composite materials. Given its score of 72 points on a quality index, this material was presented as an attractive, facile, and innovative source for obtaining NFC.

Evaluation of Queen Palm residues and kraft lignin in the production of biofuels using densification and slow pyrolysis technology.

This study aims to enhance the energy use of two products of industry - Queen Palm residue and kraft lignin (KF) - through the combination of two technologies - briquetting and slow pyrolysis. The addition of 20% KF provided briquettes with higher physical, energy, and mechanical properties. The yields of the pyrolysis products were affected by both the pyrolysis temperature and the addition of KF. In the bio-oil, the presence of phenols, methyl phenols, and methoxy phenols was highlighted; these compounds were present in greater quantities in the treatments with KF. It is concluded that combining the briquetting and pyrolysis processes produces both energy and economic benefits because it is possible to transport lighter loads with the same amount of energy per volume. Under the briquetting conditions adopted in this study, the addition of KF as a binder is necessary because this results in briquettes with better physical, energy and mechanical properties.

Influence of wood species and adhesive type on the performance of multilaminated plywood.

The quality of plywood depends on factors such as the forest species and the adhesive used in their production, and understanding the interferences of these factors in the final properties of the plywood is of fundamental importance. The study aimed to develop multilayer plywood with two forest species and two types of adhesive and to evaluate the influences of these factors (forest species and adhesive) on the physical and mechanical properties of the plywood. The panels were produced with wood veneers of parica and pine with two types of adhesives, urea-formaldehyde and phenol-formaldehyde, with a weight of 150 g.m2. Then, each set was pressed for 10 min under a specific pressure of 0.98 MPa at a temperature of 150 °C. Three panels were produced for each type of veneer and adhesive, totaling four treatments. The plywood was evaluated for physical properties (moisture content, bulk density, and water absorption) and mechanical properties (parallel and perpendicular static bending strength and shear strength). The results showed that the forest species had a greater influence on physical and mechanical properties, with the best results being observed for plywood produced with pine and PF adhesive. The specific mass of the panels should be considered as it positively influenced the mechanical properties and negatively impacted water absorption. The PCA was used to reduce the dimensionality of the data from 9 dependent variables to 2 main components, explaining 76.70% of the total variance of the data. The multivariate analyzes of the differentiated independent factors showed that both the species and the adhesive affected as properties of the plywood and both independent variables must be taken into account in the production of the plywood. It is concluded that the porosity and specific mass of the paricá veneers contributed to a greater penetration of the adhesives, resulting in lower physical and mechanical properties than the pine veneers. However, in general, it is concluded that the plywoods produced can be used for internal and external applications. However, it is not indicated for structural purposes as it did not meet the requirements of the NBR 31.000.001/2:2001.

Influence of particle size on the physico-mechanical and energy properties of briquettes produced with coffee husks.

Briquetting is a technology with the potential to convert agricultural wastes into solid biofuels with improved handling, transport, storage, and energy efficiency characteristics. It is important to study the variables related to the briquetting process and the raw material because these parameters can affect the quality of the final product. Thus, the objective of this study was to investigate the influence of particle size on the physico-mechanical and energy properties of briquettes produced with coffee husks. Three particle size fractions were obtained: particles larger than 1.8 mm, in the range of 1.8-1.2 mm, and smaller than 1.2 mm. The coffee husk briquettes were prepared in a densification system at 120 °C and 15 MPa for 15 min. The physical, mechanical, and energy characteristics such as apparent density, volumetric expansion, compressive strength, abrasion resistance, and energy density were determined. A combustibility test was also carried out. The results showed that particle size influenced the apparent density, compressive strength, and energy density of the briquettes. However, there was no significant difference in the volumetric expansion or abrasion resistance of the densified products among the treatments. In general, the briquettes made with particles smaller than 1.2 mm had better physico-mechanical and energy characteristics.