1.
Chem Commun (Camb)
; 51(7): 1282-4, 2015 Jan 25.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25476754
RESUMO
An electrochemical flow-cell for highly efficient and selective generation of Cu(I)-N-heterocyclic carbene complexes under neutral and ambient conditions is reported. The feasibility of the flow-cell is demonstrated through the electrochemical synthesis of [Cu(IMes)Cl] and subsequent in situ flow directly into hydrosilylation reactions, with equal efficiency to the purified catalyst.