RESUMO
With the COVID-19 outbreak, many challenges are posed before the scientific world to curb this pandemic. The diagnostic testing, treatment, and vaccine development for this infection caught the scientific community's immediate attention. Currently, despite the global proliferation of COVID-19 vaccination, the specific treatment for this disease is yet unknown. Meanwhile, COVID-19 detection or diagnosis using polymerase chain reaction (PCR)-based me hods is expensive and less reliable. Moreover, this technique needs much time to furnish the results. Thus, the elaboration of a highly sensitive and fast method of COVID-19 diagnostics is of great importance. The spectroscopic approach is herein suggested as an efficient detection methodology for COVID-19 diagnosis, particularly Raman spectroscopy, infrared spectroscopy, and mass spectrometry.
RESUMO
A novel organic-inorganic nanocomposite cation-exchanger has been synthesized via sol-gel method. It was characterized on the basis of FTIR, XRD, SEM, TEM, AFM and Raman studies. The structural studies reveal semi-crystalline nature of the material with the particle size ranging from 1-5 nm. Physiochemical properties such as ion-exchange capacity, chemical and thermal stability of composite material have also been determined. Bifunctional behavior of the material has been indicated by its pH titrations curves. The nanocomposite material exhibits improved thermal stability, higher ion-exchange capacity and better selectivity for toxic heavy metals. The ion-exchange material shows an ion-exchange capacity of 1.8 meq g(-1) for Na(+) ions. Sorption behavior of metal ions on the material was studied in different solvents. The cation exchanger was found to be selective for Pb(II), Hg(II) and Zr(IV) ions. The limit of detection (LOD) and the limit of quantification (LOQ) for Pb(II) ion was found to be 0.85 and 2.85 µg L(-1). Analytically important separations of heavy metal ions in synthetic mixtures as well as industrial effluents and natural water were achieved with the exchanger. The practical utility of polyanilineZr(IV)sulphosalicylate cation exchanger has been established for the analysis and recovery of heavy metal ions in environmental samples.
