Rational design of CdS-enwrapped polypyrrole nanoparticles for wastewater treatment: removal of hazardous pollutants in aqueous solutions.

The modern world requires a chemical industry that can run at low production costs while producing high-quality products with minimal environmental impact. The development of environmentally friendly, cost-effective, and efficient wastewater treatment materials remains a major problem for the sustainable approach. We prepared nanoscale cadmium sulfide (CdS)-enwrapped polypyrrole (PPy) polymer composites for degradation of organic pollutants. The prepared CdS@PPy nanocomposites were characterized by powder X-ray diffraction, scanning electron microscope (SEM), field emission scanning electron microscope (FESEM), Fourier transform infrared spectroscopy (FTIR), and ultraviolet-visible (UV) absorption spectroscopy, indicating proper intercalation between CdS and PPy. Consequently, the catalytic efficiency of the synthesized hybrid nanocomposites was analyzed through the degradation of methylene blue (MB) and rhodamine B (Rh B) under visible light irradiation. The measured degradation efficiency of the dye solutions under the photolysis process is about 18% and 23% for MB and Rh B dye, respectively. Furthermore, the recycle test result concludes that the CdS@PPy composite exhibits 91% and 89% of MB and Rh B dye degradation efficiency even at the 4th cycle, respectively. The positive synergistic impact of CdS and PPy may be the result of effective photocatalytic degradation of MB and RhB.

A High-Performance Supercapacitor Based on Hierarchical Template-Free Ni/SnO2 Nanostructures via Hydrothermal Method.

Novel flake-like Ni1-xSnxO2 particles were successfully prepared by template-free hydrothermal synthesis. The prepared samples were investigated for their properties by different characterization techniques. Scanning micrographs showed that the obtained particles consisted of nanoflakes. The X-ray diffraction results of the Ni1-xSnxO2 revealed the formation of mixed-phase Ni/SnO2 having the typical tetragonal structure of SnO2, and the cubic structure of Ni in a nanocrystalline nature. The doping with Ni had a certain influence on the host's lattice structure of SnO2 at different doping concentrations. Confirmation of the functional groups and the elements in the nanomaterials was accomplished using FTIR and EDS analyses. The electrochemical performance analysis of the prepared nanomaterials were carried out with the help of the CV, GCD, and EIS techniques. The specific capacitance of the synthesized nanomaterials with different concentrations of Ni dopant in SnO2 was analyzed at different scanning rates. Interestingly, a 5% Ni-doped SnO2 nanocomposite exhibited a maximum specific capacitance of 841.85 F g-1 at 5 mV s-1 in a 6 M KOH electrolyte. Further, to boost the electrochemical performance, a redox additive electrolyte was utilized, which exhibited a maximum specific capacitance of 2130.33 at 5 mV s-1 and an excellent capacitance retention of 93.22% after 10,000 GCD cycles. These excellent electrochemical characteristics suggest that the Ni/SnO2 nanocomposite could be utilized as an electrode material for high-performance supercapacitors.

Study to evaluate the Efficacy of Resin-modified Glass lonomer Cement Liner as a Direct Pulp Capping Material.

AIM: The aim of the present in vivo study was to compare efficacy of light-cured resin-modified glass ionomer liner, Vitrebond™ (3M ESPE) with Dycal® (Dentsply) on the healing of pulpal tissue in the event of a direct iatrogenic pulpal exposure. MATERIALS AND METHODS: Experimental group consisted of Vitrebond™ (3M ESPE) resin-modified glass ionomer liner, and Vitremer™ (3M ESPE) resin-modified glass ionomer cement (GIC) in comparison with the control group of Dycal® (Dentsply) as liner and Poly F® (Dentsply) dental cement. Class V cavities were prepared in 32 sound premolars that were scheduled for orthodontic extraction, and the exposures were capped according to groups. Five teeth from each group were extracted under local anesthesia after an interval of 24 hours, 35 and 60 days, and evaluated for inflammation, fibrotic changes, formation of reparative dentin and bacterial examination. RESULTS: The present study did not show any statistically significant difference between two groups in terms of inflammation, fibrosis, reparative dentin formation, and bacterial examination. CONCLUSION: This study shows that Vitrebond™ (3M ESPE) light-cured resin-modified glass ionomer liner can be used as an alternative to calcium hydroxide as a direct pulp capping material. CLINICAL SIGNIFICANCE: Light-cured resin-modified glass ionomer liner can be an alternative for the calcium hydroxide-based liner for capping iatrogenic pulp exposures.

Comparison of the remaining dentin thickness in the root after hand and four rotary instrumentation techniques: an in vitro study.

AIM: The aim of the present study was to compare the remaining dental thickness (RDT) in the mesiobuccal root of mandibular first molars at 3 and 7 mm from the anatomic apex after instrumentation with ProTaper, light speed LSX, K3 and M2 and to compare with that of K-files. MATERIALS AND METHODS: In this study, 60 extracted, untreated human mandibular first molars with fully formed apices, with curvature less than 35° and no root resorption were used. Prepared specimens were cut horizontally at 3 and 7 mm short of anatomic apex. The least dentin thickness from canal to external root surface was observed under 3× magnification and recorded using Clemax measuring tool and the sections were reassembled. Group I-instrumentation with ProTaper, group II-instrumentation with K3, group III-instrumentation with Light Speed LSX, group IV-instrumentation with M2 and group V- instrumentation with K-files and RDT was measured. RESULTS: Results showed that group V removed lesser amount of dentin compared to all other groups while all the three instrumentation techniques removed almost equal amount of dentin apically. CLINICAL SIGNIFICANCE: Cleaning and shaping of the root canal space involves the elimination of pathogenic contents as well as attaining a uniform specific shape. However, the RDT following the use of various intraradicular procedures is an important factor to be considered as an iatrogenic cause that may result in root fracture. To avoid this, newer rotary instruments are being introduced.