Hyporheic Exchange Controls Fate of Trace Organic Compounds in an Urban Stream.

First-order half-lives for 26 trace organic compounds (TrOCs) were determined in the hyporheic zone (HZ) and along a 3 km reach of a first-order stream in South Australia during both dry and wet seasons. Two salt tracer experiments were conducted and evaluated using a transient storage model to characterize seasonal differences in stream residence time and transient storage. Lagrangian and time-integrated surface water sampling were conducted to calculate half-lives in the surface water. Half-lives in the HZ were calculated using porewater samples obtained from a modified mini-point sampler and hyporheic residence times measured via active heat-pulse sensing. Half of the investigated TrOCs (e.g., oxazepam, olmesartan, candesartan) were not significantly removed along both the investigated river stretch and the sampled hyporheic flow paths. The remaining TrOCs (e.g., metformin, guanylurea, valsartan) were found to be significantly removed in the HZ and along the river stretch with relative removals in the HZ correlating to reach-scale relative removals. Using the modeled transport parameters, it was estimated that wet season reach-scale removal of TrOCs was predominately caused by removal in the HZ when the intensity of hyporheic exchange was also higher. Factors that increase HZ exchange are thus likely to promote in-stream reactivity of TrOCs.

Induced temperature gradients to examine groundwater flowpaths in open boreholes.

Techniques for characterizing the hydraulic properties and groundwater flow processes of aquifers are essential to design hydrogeologic conceptual models. In this study, rapid time series temperature profiles within open-groundwater wells in fractured rock were measured using fiber optic distributed temperature sensing (FO-DTS). To identify zones of active groundwater flow, two continuous electrical heating cables were installed alongside a FO-DTS cable to heat the column of water within the well and to create a temperature difference between the ambient temperature of the groundwater in the aquifer and that within the well. Additional tests were performed to examine the effects of pumping on hydraulic fracture interconnectivity around the well and to identify zones of increased groundwater flow. High- and low-resolution FO-DTS cable configurations were examined to test the sensitivities of the technique and compared with downhole video footage and geophysical logging to confirm the zones of active groundwater flow. Two examples are presented to demonstrate the usefulness of this new technique for rapid characterization of fracture zones in open boreholes. The combination of the FO-DTS and heating cable has excellent scope as a rapid appraisal tool for borehole construction design and improving hydrogeologic conceptual models.