Gum acacia based hydrogels and their composite for waste water treatment: A review.

The non-toxic nature of natural polysaccharides and their biodegradability makes them the first choice of researchers. Various natural polysaccharides are available nowadays, like cellulose, starch, chitosan, gum acacia, guar gum etc. Among these, gum acacia is a common natural polysaccharide presently used in research and technology. It is highly biodegradable, pH stable and shows appropriate water solubility. It is used in research to synthesize hydrogels and hydrogel nanocomposites for various applications because of its antimicrobial, anti-inflammatory and excellent absorption properties. The major fields of applications include the stabilization of metal nanoparticles in the form of nanocomposites, wound dressing materials, delivery systems of various drugs and pharmaceutical agents, bioengineering, tissue engineering, purification of water, synthesis of antibacterial and antifungal composites for agricultural improvements, and many others. Due to the increasing problem of water pollution, the major focus is on research helping to reduce this problem. Gum acacia-based hydrogel and hydrogel composites were synthesized and tested for pollutant removal efficiency from wastewater by different researchers. The research on gum acacia hydrogel and their hydrogel composite applications for water purification, as well as their synthesis processes and properties, are summarized in this review article.

Antimicrobial potential of phytocompounds of Acorus calamus: in silico approach.

Medicinal plants are used from prehistoric time to cure various life-threatening bacterial diseases. Acorus calamus is an important medicinal plant widely used to cure gastrointestinal, respiratory, kidney and liver disorders. The objective of the current research was to investigate the interaction of major phytoconstituents of Acorus calamus with bacterial (6VJE) and fungal (1EA1) protein targets. Protein-ligand interactions were estimated using the AutoDock software, drug likeness was predicted by using the molinspiration server and toxicity was predicted with the swissADME and protox II servers. MD simulation of phytocompounds with the best profiles was done on the GROMACS software for 100 ns. Molecular docking results showed among all the selected major phytoconstituents, that ß-cadinene showed best binding interaction in complex with bacterial (6VJE) and fungal (1EA1) protein targets with binding energy -7.66 ± 0.1 and -7.73 ± 0.15 kcal mol-1, respectively. Drug likeness and toxicity predictions showed that ß-cadinene follows all rules of drug likeness and toxicity. MD simulation study revealed that ß-cadinene fit in binding pocket of bacterial and fungal targets and found to be stable throughout the duration of the simulation. Based on the observations from this in-silico study it is being proposed that ß-cadinene, a major phytocompound of Acorus calamus, can be considered for the treatment of bacterial and fungal infections since the study shows that it might be one of the compounds that contributes majorly to the plant's biological activity. This study needs in vitro and in vivo validation.Communicated by Ramaswamy H. Sarma.

Carbon dots for photothermal applications.

Carbon dots are zero-dimensional nanomaterials that have garnered significant research interest due to their distinct optical properties, biocompatibility, low fabrication cost, and eco-friendliness. Recently, their light-to-heat conversion ability has led to several novel photothermal applications. In this minireview, we categorize and describe the photothermal application of carbon dots along with methods incorporated to enhance their photothermal efficiency. We also discuss the possible mechanisms by which the photothermal effect is realized in these carbon-based nanoparticles. Taken together, we hope to provide a comprehensive landscape highlighting several promising research directions for using carbon dots for photothermal applications.

Properties, optimized morphologies, and advanced strategies for photocatalytic applications of WO3 based photocatalysts.

The development of WO3 based photocatalysts has gained considerable attention across the world, especially in the realm of environmental remediation and energy production. WO3 has a band gap of 2.5- 2.7 eV that falls under the visible region and is thus a potential candidate to utilize in various photocatalytic processes. As an earth-abundant metal oxide, WO3 discovered in 1976 displayed excellent electronic and morphological properties, good stability, and enhanced photoactivity with diverse crystal phases. Also, it unveils non-toxicity, high stability in drastic conditions, biocompatibility, low cost, excellent hole mobility (10 cm2 V-1s-1), and tunable band gap. This review provides a comprehensive overview of the different properties of WO3 inclusive of crystallographic, electrical, optical, thermoelectrical, and ferroelectric properties. The different morphologies of WO3 based on dimensions were obtained by adopting different fabrication methods including inspecting their effects on the efficiency of WO3. Numerous strategies to construct an ideal photocatalyst such as engineering crystal facets, surface defects, doping, heterojunction formation explaining specifically type-II, Z-scheme, and S-scheme mechanisms with addition to carbonaceous based WO3 nanocomposites are summed up to explore the photocatalytic performance. The typical application of WO3 is deliberated in detail involving the role and efficiency of WO3 in pollutant degradation, CO2 photoreduction, and water splitting. Besides, other applications of WO3 as gas-sensor, bio-sensor, decomposition of VOCs, heavy metals ions adsorption, and antimicrobial property are also included. Moreover, the numerous aspects responsible for the high efficiency of WO3-based nanocomposites with their challenges, opportunities, and future aspects are summarized. Hopefully, this review may inspire researchers to explore new ideas to boost the production of clean energy for the next generation.

Photocatalytic dye degradation and antimicrobial activities of Pure and Ag-doped ZnO using Cannabis sativa leaf extract.

A facile green route has been employed for the synthesis of ZnO and Ag-doped ZnO using Cannabis sativa as a reducing and stabilizing agent. The as-synthesized nanoparticles were characterized and tested for photocatalytic dye degradation and antimicrobial activity. The results suggested that nanoparticles have shown antimicrobial activity against different human pathogenic bacteria (Escherichia coli, Klebsiella pneumonia, MRSA, Pseudomonas aeruginosa, Salmonella typhi, Staphylococcus aureus) and fungal strains (Fusarium spp. and Rosellinia necatrix). Ag-doped nanoparticles comparatively have shown better removal Congo red and methyl orange under visible light. Therefore, green synthesized nanoparticles could have beneficial applications in environmental science and biological field.