1.
Angew Chem Int Ed Engl
; 44(10): 1508-10, 2005 Feb 25.
Artigo
em Inglês
| MEDLINE
| ID: mdl-15693038
2.
J Am Chem Soc
; 125(15): 4440-1, 2003 Apr 16.
Artigo
em Inglês
| MEDLINE
| ID: mdl-12683812
RESUMO
Reaction of TpR,MeCo(I) dinitrogen complexes (R = iPr, tBu) with trimethylsilyl azide yields structurally characterized compounds that imply the formation of reactive intermediates of the type TpR,MeCo=NSiMe3. These cobalt imido species apparently abstract hydrogen from the 3-substituent of the Tp-ligand, leading to the formation of amido complexes accompanied by either Co-C bond formation (R = tBu) or C-C bond formation (R = iPr).