Overtone Spectroscopy for Sensing─Recent Advances and Perspectives.

In this perspective, we report an opinion on overtone spectroscopy for sensing and discuss the nature of the opportunities perceived for specialists. New spectroscopic strategies can potentially be extended to detect other common toxic byproducts in a chip-scale label-free manner and to enhance the functionality of chemical and biological monitoring. Nevertheless, the full potential of overtone spectroscopy is not yet exhausted, challenges must be overcome, and new avenues await. Within this Perspective, we look at where the field currently stands, highlight several successful examples of overtone spectroscopy based sensors and detectors, and ask what it will take to advance current state-of-the-art technology. It is our intention to point out some potential blind spots and to inspire further developments.

Efficient all-solid-state passively Q-switched SWIR Tm:YAP/KGW Raman laser.

We present an all-passive efficient KGW Raman laser with an external-cavity configuration in the 2 µm spectral regime. The Raman laser was pumped by a passively Q-switched Tm:YAP laser emitting at 1935 nm. Due to the bi-axial properties of the KGW crystal, the laser exhibits stimulated Raman emission at two separate spectral lines: 2272 nm and 2343 nm. The output energies achieved at these two lines are 340 µJ/pulse and 450 µJ/pulse, accordingly. The seed to Raman laser conversion efficiencies achieved of 19.2% and 23.5%, respectively, are comparable to actively Q-switched laser arrangements. To the best of our knowledge, this is the first time an efficient Raman laser in the 2 µm regime is demonstrated in a completely passive configuration.

Carrier-to-envelope phase-stable, mid-infrared, ultrashort pulses from a hybrid parametric generator: Cr:ZnSe laser amplifier system.

Our Cr:ZnSe laser amplifier, seeded by parametric difference mixing, produces 72fs long pulses at the central wavelength of ~2.37µm. The stability of the carrier-to-envelope phase of the amplified seed pulses, attained at the stage of their parametric generation, is preserved through 6 orders of magnitude of laser amplification.

Two-wavelength Tm:YLF/KGW external-cavity Raman laser at 2197 nm and 2263 nm.

This paper presents a KGW Raman laser with an external-cavity configuration at the 2 µm region. The Raman laser is pumped by an actively Q-switched Tm:YLF laser, especially designed for this purpose emitting at 1880 nm. Due to the KGW bi-axial properties, the Raman laser is able to lase separately at two different output lines, 2197 nm and 2263 nm. The output energies and pulse durations that were achieved for these two lines are 0.15 mJ/pulse at 21 ns and 0.4 mJ/pulse at 5.4 ns, respectively. To the best of our knowledge, this is the first time that the KGW crystal, which is well known for its wide use in shorter wavelengths, is demonstrated in a Raman laser in the 2 µm region. According to the achieved results and due to the KGW properties, it appears to be a suitable crystal for energy scaling and efficient Raman conversion in this spectral range. An estimation of the Raman gain coefficient for this wavelength is provided as well.

Actively Q-switched tunable narrow bandwidth milli-Joule level Tm:YLF laser.

A pulsed high energy and narrow bandwidth tunable Tm:YLF laser at the milli-Joule level is demonstrated. The spectral bandwidth was narrowed down to 0.15 nm FWHM, while 33 nm of tunability range between 1873 nm and 1906 nm was achieved using a pair of YAG Etalons. The laser was actively Q-switched using an acousto-optic modulator and mJ level pulse energy was measured along the whole tuning range at a repetition rate of 1 kHz. Up to 1.97 mJ of energy per pulse was achieved at a pulse duration of 37 ns at a wavelength of 1879 nm, corresponding to a peak-power of 53.2 kW and at a slope efficiency of 36 %. The combination of both high energy pulsed lasing and spectral tunability, while maintaining narrow bandwidth across the whole tunability range, enhances the laser abilities, which could enable new applications in the sensing, medical and material processing fields.

Watt-level tunable narrow bandwidth Tm:YAP laser using a pair of etalons.

We demonstrated in this paper a watt-level tunable, narrow band, end-pumped Tm:YAP laser. Spectral tunability of 35 nm ranging continuously between 1917-1951 nm with a spectral linewidth of 0.15 nm FWHM was achieved. The tuning and spectral band narrowing were obtained using a pair of YAG etalons. Watt-level output power was measured along the laser tunable range, obtaining a maximal output power of 3.88 W at 1934 nm. A slope efficiency of 44.8% is demonstrated for a maximal absorbed pump power of 12.1 W. The combination of the narrow bandwidth with tunability at those output power levels makes this laser a promising tool for biomedical, sensing, and material processing applications.