Kill two birds with one stone: simultaneous removal of volatile organic compounds and ozone secondary pollution by a novel photocatalytic process.

Volatile organic compounds (VOCs) originating from diverse sources with complex compositions pose threats to both environmental safety and human health. Photocatalytic treatment of VOCs has garnered attention due to its high efficacy at room temperature. However, the intricate photochemical reaction generates ozone (O3), causing secondary pollution. Herein, our work developed a novel "synergistic effect" system for photocatalytic co-treatment of VOCs and O3 secondary pollution. Under the optimized reactor conditions simulated with computational fluid dynamics (CFD), MgO-loaded g-C3N4 composites (MgO/g-C3N4) were synthesized as efficient catalysts for the photocatalytic synergistic treatment process. Density functional theory (DFT) calculations, characterization, and electron paramagnetic resonance (EPR) tests revealed that the addition of MgO reduced the band gap of g-C3N4, and increased O3 molecule adsorption in the composites, efficiently harnessing the synergistic effect of O3 to generate a significant quantity of reactive oxygen radicals, thereby facilitating the removal of VOCs and O3. This study provides new insights for simultaneous elimination of VOCs and O3 secondary pollution by a photocatalytic process.

New insights on precise regulation of pollutant distribution inside a street canyon by different vegetation planting patterns.

Mixed-vegetation planting patterns are commonly seen in urban areas for specific reasons like aesthetic, cooling, and particle deposition effects of the vegetation. However, they may have a negative impact on human health by worsening the air quality inside the street canyon due to the decreased air exchange rate. From the view of precise control of pollutant concentration in the sensitive areas of people's concern in the existed street canyons, thirty-four cases with different vegetation planting patterns and pressure loss coefficients (λ) are studied numerically to investigate the effects of vegetation on airflow and pollutant dispersion inside the canyon. The cases of treeless and 2 rows of tree planting patterns in wind-tunnel measurements were selected for the model validation. The results demonstrate that compared to the treeless case, the greenbelts can greatly change the airflow features and reduce the pollutant concentration at the leeward side, while the only-tree planting patterns have little impact on the flow and deteriorate dispersion within the street canyon. Moreover, rows of greenbelts planted under the corresponding trees can reduce the average pollutant concentrations on the leeward wall and the footpath of the street canyon by up to 22.6% and 33.2%, respectively. Besides, the pattern of 1 row of trees with 1 row of greenbelts planted in the street canyon center should be suggested as the optimal mixed vegetation configuration in this study. That is because compared to the treeless case the pollutant concentration on leeward wall, windward wall, leeward footpath, and windward footpath can be reduced by 14.2%, 10.0%, 24.6%, and 37%, respectively. It is helpful to the city planners to consider whether the disadvantages of planting vegetation inside the street canyon would overwhelm the advantages.

Evaluation on ventilation and traffic pollutant dispersion in asymmetric street canyons with void decks.

With continuous global warming, growing urban population density, and increasing compactness of urban buildings, the "void deck" street canyon design has become increasingly popular in city planning, especially for urban streets located in tropical areas. Nevertheless, research on traffic pollutant dispersion in street canyons with void decks (VDs) is still at its early stage. This study quantitatively evaluates the effects of void deck height and location on the canyon ventilation and pollutant dispersion in asymmetric street canyons with void decks, and the pollutant exposure risk level for pedestrians and street dwellers. Void decks introduce more fresh air, thereby greatly improving the ventilation properties of the asymmetric canyon. The air exchange rate (ACH: 147.9%, 270.9%) and net escape velocity (NEV*: 416.7%, 915.8%) of the step-up and step-down canyons with VDs (3 m high at full scale) at both buildings are higher than those of regular asymmetric canyons. Moreover, the mean dimensionless pollutant concentration (K) on the building wall and pedestrian respiration plane in which VDs are located stands at a low level, because pollutants are removed by the airflow entering or exiting through the void decks. Increased VD height (4.5 m at full scale) enhances the strength of airflow flowing into and out of the canyon, significantly increasing ACH (177.3%, 380.9%) and NEV* (595.2%, 1268.4%) and decreasing the mean K on both pedestrian respiration planes and canyon walls. In particular, the K values on both pedestrian respiration planes and both walls are almost zero for the canyons with VDs at both buildings. Therefore, among the three VD locations, both VDs provide the best living environment for pedestrians and near-road residents. These findings can help to design urban street canyons for mitigating traffic pollution risk and improving ventilation in tropical cities.

Optimization of biodiesel production process from soybean oil using the sodium potassium tartrate doped zirconia catalyst under Microwave Chemical Reactor.

A solid base catalyst was prepared by the sodium potassium tartrate doped zirconia and microwave assisted transesterification of soybean oil was carried out for the production of biodiesel. It was found that the catalyst of 2.0(n(Na)/n(Zr)) and calcined at 600°C showed the optimum activity. The base strength of the catalysts was tested by the Hammett indicator method, and the results showed that the fatty acid methyl ester (FAME) yield was related to their total basicity. The catalyst was also characterized by FTIR, TGA, XRD and TEM. The experimental results showed that a 2.0:1 volume ratio of methanol to oil, 65°C reaction temperature, 30 min reaction time and 10 wt.% catalyst amount gave the highest the yield of biodiesel. Compared to conventional method, the reaction time of the way of microwave assisted transesterification was shorter. The catalyst had longer lifetime and maintained sustained activity after being used for four cycles.