Effects and driving mechanisms of bioremediation on groundwater after the neutral in situ leaching of uranium.

The remediation of groundwater subject to in situ leaching (ISL) for uranium mining has raised extensive concerns in uranium mill and milling. This study conducted bioremediation through biostimulation and bioaugmentation to the groundwater in an area in northern China that was contaminated due to uranium mining using the CO2 + O2 neutral ISL (NISL) technology. It identified the dominant controlling factors and mechanisms driving bioremediation. Findings indicate that microorganisms can reduce the uranium concentration in groundwater subject to NISL uranium mining to its normal level. After 120 days of bioaugmentation, the uranium concentration in the contaminated groundwater fell to 0.36 mg/L, achieving a remediation efficiency of 91.26 %. Compared with biostimulation, bioaugmentation shortened the remediation timeframe by 30 to 60 days while maintaining roughly the same remediation efficiency. For groundwater remediation using indigenous microbial inoculants, initial uranium concentration and low temperatures (below 15 °C) emerge as the dominant factors influencing the bioremediation performance and duration. In settings with high carbonate concentrations, bioremediation involved the coupling of multiple processes including bioreduction, biotransformation, biomineralization, and biosorption, with bioreduction assuming a predominant role. Post-bioremediation, the relative abundances of reducing microbes Desulfosporosinus and Sulfurospirillum in groundwater increased significantly by 10.56 % and 6.91 %, respectively, offering a sustainable, stable biological foundation for further bioremediation of groundwater.

Evaluation of the water quality monitoring network layout based on driving-pressure-state-response framework and entropy weight TOPSIS model: A case study of Liao River, China.

The establishment of river water quality monitoring network is crucial for watershed protection. However, the evaluation process of monitoring network layout involves significant subjectivity and has not yet to form a complete indicator system. This study constructed an indicator system based on the DPSR (Driving-Pressure-State-Response) framework in the Liao River Basin, China. SWAT model and ArcGIS were used to quantify the indicators. And the entropy weight-TOPSIS method was employed to rank monitoring points. The results showed that pressure and state indicators had a greater impact on the network layout, with the indicator for proportion of land use in residential areas carrying the largest weight of 0.136. It suggested that the risk of river pollution remained high, and the governance strategies needed to be improved. Priority monitoring points were mainly located in the east and middle of the basin, consistent with the distribution of human activities such as urban areas and farmland. In addition, the redundancy of points should be avoided, and evaluation results should be adjusted based on the actual situation. The study provided an evaluation method for the layout of monitoring points.

From field soil sampling to watershed model: Upscaling by integrating information entropy and interpolation method.

Soil property data plays a crucial role in watershed hydrology and non-point source (H/NPS) modeling, but how to improve modeling accuracy with affordable soil samplings and the effects of sampling information on H/NPS modeling remains to be further explored. In this study, the number of sampling points and soil properties were optimized by the information entropy and the spatial interpolation method. Then the sampled properties were parameterized and the effects of different parameterization schemes on H/NPS modeling were tested using the Soil and Water Assessment Tool (SWAT). The results indicated that the required sampling points increased successively for soil bulk density (SOL_BD), soil saturated hydraulic conductivity (SOL_K) and soil available water capacity (SOL_AWC). Compared to the traditional database (Harmonized world soil database), the NSE and R2 performance by new scheme increased by 22.8% and 10.5%, respectively. The entropy-based optimization reduced the sampling points by 13.2%, indicating a more cost-effective scheme. Compared to hydrological simulation, sampled properties showed greater effects on NPS modeling, especially for nitrogen. This proposed method/framework can be generalized to other watersheds by upscaling field soil sampling information to the watershed scale, thus improving H/NPS simulation.

Uncertainty analysis and economic value prediction of water environmental capacity based on Copula and Bayesian model: A case study of Yitong River, China.

Water environmental capacity (WEC) is an indicator of environment management. The uncertainty analysis of WEC is more closely aligned with the actual conditions of the water body. It is crucial for accurately formulating pollution total emissions control schemes. However, the current WEC uncertainty analysis method ignored the connection between water quality and discharge, and required a large amount of monitoring data. This study analyzed the uncertainty of the WEC and predicted its economic value based on Copula and Bayesian model for the Yitong River in China. The Copula model was employed to calculate joint probabilities of water quality and discharge. And the posterior distribution of WEC with limited data was obtained by the Bayesian formula. The results showed that the WEC-COD in the Yitong River was 9009.67 t/a, while NH3-N had no residual WEC. Wanjinta Highway Bridge-Kaoshan Town reach had the most serious pollution. In order to make it have WEC, the reduction of COD and NH3-N was 5330.47 t and 3017.87 t. The economic value of WEC-COD was 5.97 × 107 CNY, and the treatment cost was 2.04 × 108 CNY to make NH3-N have residual WEC. The economic value distribution of WEC was extremely uneven, which could be utilized by adjusting the sewage outlet. In addition, since the treated water was discharged into the Sihua Bridge-Wanjinta Highway Bridge reach, the WEC-COD and the economic value were 19,488.51 t/a and 8.24 × 107 CNY. Increasing the flow of rivers could effectively improve WEC and economic value. This study provided an evaluation tool for guiding river water environment management.

Farmland Microhabitat Mediated by a Residual Microplastic Film: Microbial Communities and Function.

How the plastisphere mediated by the residual microplastic film in farmlands affects microhabitat systems is unclear. Here, microbial structure, assembly, and biogeochemical cycling in the plastisphere and soil in 33 typical farmland sites were analyzed by amplicon sequencing of 16S rRNA genes and ITS and metagenome analysis. The results indicated that residual microplastic film was colonized by microbes, forming a unique niche called the plastisphere. Notable differences in the microbial community structure and function were observed between soil and plastisphere. Residual microplastic film altered the microbial symbiosis and assembly processes. Stochastic processes significantly dominated the assembly of the bacterial community in the plastisphere and soil but only in the plastisphere for the fungal community. Deterministic processes significantly dominated the assembly of fungal communities only in soil. Moreover, the plastisphere mediated by the residual microplastic film acted as a preferred vector for pathogens and microorganisms associated with plastic degradation and the nitrogen and sulfur cycle. The abundance of genes associated with denitrification and sulfate reduction activity in the plastisphere was pronouncedly higher than that of soil, which increase the potential risk of nitrogen and sulfur loss. The results will offer a scientific understanding of the harm caused by the residual microplastic film in farmlands.

The cumulative effects of cascade reservoirs control nitrogen and phosphorus flux: Base on biogeochemical processes.

The reservoir serves as a water source, a flood control structure, a navigational aid, and also impacts the downstream ecosystem as well as the reservoir zone. However, debate exists about effectiveness of cascade reservoirs in controlling the transportation of nutrients, particularly in the Yangtze River basin, which has been significantly affected by reservoir development. This research develops a new model X-NPSEM (X with Nitrogen and Phosphorus Steady-state Reservoir Model) based on biogeochemical processes of nitrogen and phosphorus reaction for investigating the dynamic storage capacity of cascade reservoirs at both reservoir- and watershed scales. Then the cumulative effects of cascade reservoirs and the related mechanism were investigated in Fujiang watershed, China. Based on the results, cascade reservoirs retained 16.3 % of nitrogen fluxes and 37.6 % of phosphorus fluxes annually. Downstream reservoirs have higher retention rates of phosphorus (0.48/d) compared to upstream reservoirs (0.10/d), mainly due to inflow sediment. Nitrogen retention rates show seasonal variations: wet season (0.21/d) and dry season (0.17/d). These fluctuations in nitrogen retention are primarily influenced by changes in temperature rather than other factors such as operation period, nitrogen and phosphorus concentration, or the nitrogen/phosphorus ratio. In upstream, the concentration of sediment entering the reservoir plays a decisive role in the transformation of P retention from sink to source. The X-NPSRM coupler model could be used for global reservoir operation and watershed management.

Influence of landscape patterns on nitrate and particulate organic nitrogen inputs to urban stormwater runoff.

This study investigated the effect of the landscape pattern of permeable/impermeable patches on NO3--N and particulate organic nitrogen (PON) concentrations during stormwater runoff transport and their source contributions. Six landscape pattern indices, namely, mean proximity index (MPI), largest patch index (LPI), mean shape index (MSI), landscape shape index (LSI), connect index (CONNECT), and splitting index (SPLIT), were selected to reflect the fragmentation, complexity, and connectivity of permeable patches in urban catchments. The results show that lower fragmentation, higher complexity, and greater connectivity can reduce NO3--N concentrations in road runoff and drainage flow (i.e., the flow in the stormwater drainage network), as well as PON concentrations in road runoff. Further, the above landscape pattern is effective for mitigating the contributions of NO3--N and PON from road runoff. Low impact development (LID) can be incorporated with the landscape pattern of permeable/impermeable patches to mitigate nitrogen pollution in urban stormwater at the catchment scale by optimizing the spatial arrangement.

[Simulation of Pollution Apportionment and Optimization of Control Methods in Watershed Scale: A Case Study of the Shun'an Watershed in Tongling City].

The protection of the Yangtze River is an important national strategy in China, but it faces many problems such as difficult water environment protection, unclear pollution sources, and low integration of measures. Aimed at addressing watershed scale multi-source pollution together with facing the bottleneck method, by combining research data analysis, mechanism model, and intelligent algorithm optimization, this study built the framework for accurate pollution apportionment, measures evaluation, and overall measure optimization. Shun'an watershed in Tongling City of Anhui Province was set as an example for the application. The results showed that the new method could accurately quantify the impacts of planting industry, rural life, livestock and poultry breeding, aquaculture, industrial sewage, and domestic sewage in the watershed and evaluate the overall effects of various measures. The multi-objective optimization algorithm provided a cooperative multi-source pollution control scheme with higher cost performance and better environmental benefit by comparing the cost effectiveness of various schemes systematically. The optimization scheme showed that total nitrogen could be reduced by 1274.24 t·a-1 in wet years, 855.24 t·a-1 in normal years, and 381.96 t·a-1 in dry years. Total phosphorus was reduced by 321.42 t·a-1 in wet years, 159.80 t·a-1 in normal years, and 42.93 t·a-1 in dry years, such that the water quality reached the surface class Ⅲ water quality standard. These research results can be extended to other watersheds and provide a method reference for water environment protection under the background of the high-quality development of watersheds.

Integrating source apportionment and landscape patterns to capture nutrient variability across a typical urbanized watershed.

Effective integrated watershed management requires models that can characterize the sources and transport processes of pollutants at the watershed with multiple landscape patterns. However, few studies have investigated the influence of landscape spatial configuration on pollutant transport processes. In this study, the SPARROW_TN and SPARROW_TP models were constructed by combining direct pollution source data and landscape pattern data to investigate the source composition and nutrient transport processes and to reveal the influence of landscape patterns on nutrient transport in the urbanized Beiyun River Watershed. The introduction of landscape metrics significantly improved the simulation results of both models, with R2 increasing from 0.89 to 0.85 to 0.93 and 0.91, respectively. Spatial variations existed in TN and TP loads and yields, as well as the source compositions. Pollution hotspots were effectively identified. Source apportionment showed that for the entire watershed, TN came from atmospheric nitrogen deposition (35.25%), untreated sewage (28.23%), agricultural sources (22.60%), and treated sewage (13.92%). In comparison, TP came from untreated sewage (44.94%), agricultural sources (40.22%), and treated sewage (11.51%). In addition, the largest patch index of grassland correlated positively with both TN and TP, whereas the largest shape index of buildup land and interspersion and juxtaposition index of forest were negatively correlated with TN and TP, respectively. The results of this study will provide insight into effective nutrient control measures that consider spatially varying nutrient sources and associated nutrient transport processes.

Source appointment at large-scale and ungauged catchment using physically-based model and dynamic export coefficient.

Data scarcity has caused enormous problems in non-point pollution predictions and the related source apportionment. In this study, a new framework was developed to undertake the source apportionment at a large-scale and ungauged catchment, by integrating the physically-based model and a surrogate model. The improvements were made, in terms of the application of a physically-based model in an ungauged area for the transfer process and the parametric transplantation process. The new framework was then tested in the Chaohu Lake basin, China. The result suggested that there has been a good match between simulated and observed data. Although the planting industry was the largest emission source with 48.16% of nitrogen (N), itonly contributed 12.61% of N flux to the Chaohu Lake. The ungauged catchments surrounding the Chaohu Lake were identified as non-negligible sources with 8.46% of phosphorus (P) contribution. The rainfall conditions could have great impacts on source apportionment results; e.g., the planting industry contributed from 68.17t of P in dry year to 436.02t in wet year. The new framework could be extended to other large-scale watersheds for source apportionment with data limitations.

Drought impacts on hydrology and water quality under climate change.

The Intergovernmental Panel on Climate Change (IPCC) has predicted that droughts are projected to affect global hydrology and water quality in varying ways, resulting in a considerable challenge to water availability for society, environment, and ecosystems. This study employed the Soil and Water Assessment Tool to evaluate how drought affects hydrology and water quality in the Miyun Reservoir watershed, coupled with bias-corrected climate projections in the Representative Concentration Pathway 8.5 scenario, accommodating the intercoupling effects of precipitation shifts and rising temperatures. The standardized precipitation index (SPI), standardized runoff index (SRI), and standardized soil moisture index (SSWI) were used to characterize meteorological, hydrological, and agricultural droughts that occur in the different phases in the hydrological cycle. Climate change had the most significant impact on agricultural drought. SSWI were projected to considerably increase in intensity, frequency, and duration in most subbasins by up to 15 %, 55 %, and 45 %, respectively, and showed a strong correlation with meteorological and hydrological droughts (correlation coefficients r = 0.54, 0.57, and 0.60 with SPI for the baseline, near future and far future periods, and 0.91, 0.87, and 0.89 with SRI for the three periods, respectively). Hydrological components, sediment export, and nutrient loss were highly correlated with changes in drought indexes, with r ranging between -0.68 and 0.34 in the near future period and -0.62 and 0.53 in the far future period. Drought conditions of surface runoff and soil water dominated the changes in sediment export, and hydrological drought was the major cause for reduced nutrient loads. In addition to drought impacts, the synergistic effects of increasing precipitation and rising temperature led to a certain degree of increase in sediment and nutrient exports. The results of this study emphasize the need to enhance the resilience of watershed systems to the predicted increases in the intensity, frequency, and duration of droughts.

Copula-based analysis of socio-economic impact on water quantity and quality: A case study of Yitong River, China.

Socio-economic development has a significant impact on both water quantity and quality. However, few studies have considered the complex relationship between water quantity and quality when evaluating such impact. In this study, three indicators based on copula model were proposed, namely, water quantity improvement degree (WQIDw), water quality improvement degree (WQIDq) and water quantity and quality joint improvement degree (WQJID). These indicators were used to assess the impact of social economy on water quantity and quality, and applied to a case study in Yitong River in Northeast China from 2021 to 2025. Four scenarios were set to explore the impact of socio-economic development and water resources protection on WQIDw, WQIDq and WQJID. The maximum WQIDw, WQIDq and WQJID were <1 under the business-as-usual scenario, which showed that the present socio-economic pattern caused great damage to river water quantity and quality. The combined effect of socio-economic development and water resources protection increased the WQJID of COD and NH3-N by 1.67 and 1.30. This showed that attention should be paid to water resources protection while developing social economy. Compared with comprehensive evaluation, separate evaluation of water quality will underestimate the impact of social economy on rivers, while separate evaluation of water quantity will overestimate the impact. The relationships between WQIDw, WQIDq and WQJID were quantified. Meanwhile, the uncertainty of the evaluation was controlled by the selection of water quality indicators. The WQIDq, WQIDw and WQJID proposed in this study provide a comprehensive assessment tool for guiding water resources management.

New method for scaling nonpoint source pollution by integrating the SWAT model and IHA-based indicators.

Nonpoint source (NPS) pollution shows spatial scaling effects because it is affected by topography, river networks, and many other factors. Currently, the lack of an integrated methodology for quantifying the scaling effect has become a crucial barrier in evaluating NPS pollution. In this study, a new method was proposed for scaling NPS pollution by integrating hydrological model and hydrological alteration indicators. Nested catchments were delineated by eight-direction algorithm, and a semidistributed hydrological model was used to simulate the interannual process within the drainage area and to obtain data series of runoff, sediment, and total phosphorus (TP) at different spatial scales. In addition, the average, the extrema, the change rate and feature variables of each type of indicators were proposed to quantitatively describe the pattern of NPS pollution at different spatial scales. The results show the coefficients of variation (CVs) of most runoff and TP indicators are 0.6-0.8, while those of sediment vary greatly from 0.4 to 1.6 with the threshold of those indicators being 0.33. With the increase in drainage area, the NPS load-related indicators show an increasing trend, while load intensity indicators show a decreasing trend and their changing patterns are affected by the heterogeneity of topographic or hydrological information included. Based on logarithmic variance of the change rate, 825 km2 was identified as the turning point for scaling transformation where the slope changes dramatically. The proposed methodology comprehensively describes features of the NPS scaling effect that could be utilized for targeted monitoring and control of NPS pollution in other watersheds.

Pesticide fate at watershed scale: A new framework integrating multimedia behavior with hydrological processes.

Pesticide pollution has been one serious ecological and environmental issue due to its wide application, high toxicity, and complex environmental behavior. The fugacity model has been widely used to quantify biogeochemical cycles of pesticides due to its clear compartments, simple structure, and easy-accessible data. However, the lack of detailed hydrological processes limits its application for large and heterogeneous watershed. In present study, a new framework was proposed through integration of hydrological processes of SWAT and pesticide fate of fugacity model, and was applied into a typical watershed in the Three Gorges Reservoir Area, China. The results showed that surface runoff, soil erosion, and percolation varied spatiotemporally, which highlighted the importance of considering regional and seasonal heterogeneity of pesticide transport variables in the fugacity model. The amount of dichlorvos (DDV) and chlorpyrifos (CHP) in air, water, soil, and sediment phase were estimated as 0.26 kg, 19.77 kg, 1.06 × 104 kg, and 0.55 kg, respectively. Spatiotemporally, pesticide concentrations in water phase peaked in summer, while the middle and southwest regions of the watershed were identified as the hotspots for pesticide pollution. Compared with the classical model, the new framework provided technical support for the pesticide assessment at watershed scale with heterogeneous hydrological conditions, which can be easily extended to other watersheds, and integrated with other models for comprehensive agricultural management.

Nitrogen transport and sources in urban stormwater with different rainfall characteristics.

Nitrogen pollution in urban stormwater has led to serious quality issues in urban water. Nitrogen pollution mitigation requires fully understanding the transport process and major nitrogen sources in urban stormwater. In this study, the concentrations and flux of various nitrogen forms during urban stormwater transport were analyzed. It was found that the concentration and flux of NO3--N and NH3-N decreased in the order of roof runoff, road runoff, and drainage runoff, while the concentration and flux of dissolved organic nitrogen (DON) and particulate nitrogen (PN) were found to be the highest in road runoff. Source quantification found that roof runoff (34%) and rainwater (34%) were the main contributors to nitrate pollution during light and moderate rains (<25 mm), while road runoff was identified as the major source (49%) of nitrate pollution during heavy rains (>25 mm) due to the large road runoff volume. Regarding particulate organic nitrogen (PON), the road runoff in commercial areas contributed most (23%) to PON pollution during light and moderate rains, while the runoff generated from pervious surfaces and drainage sediments were the primary two sources (22%) of PON during heavy rains. Moreover, the influence of rainfall characteristics on nitrate and PON source contributions was identified. The results show that antecedent dry periods were an important factor influencing nitrogen source contributions during light and moderate rains, while rainfall amount and intensity were critical factors impacting the nitrogen source contributions during heavy rains. Taking various transport processes, source contributions, and rainfall characteristics into consideration, several recommendations were given for the mitigation of nitrogen pollution in urban stormwater. This study can provide a useful perspective to understand the transport and sources of nitrogen, thus developing constructive strategies to control urban nonpoint source pollution management.

Microplastic bioaccumulation in estuary-caught fishery resource.

The environmental behavior of microplastics (MPs) in estuaries with saline and freshwater intersections is extremely complex. This increases the chance of MP ingestion by fishery resources, posing potentially tremendous health risks for humans. Herein, a total of 105 fishes from 14 different species, and 86 crustaceans (including shrimps and crabs) from five different species were sampled in the Yangtze River estuary and offshore, and MP bioaccumulation, accumulative organ, and the influencing factors were comprehensively studied. The results elucidated that MP accumulation in benthos was significantly higher than that in pelagic animals due to the lower acceptance threshold, assimilation efficiency and egestion rate for benthos. The MP content in crustaceans with the burrowing favoring the MP retention was significantly higher than that in fishes. MPs ingested by fish can accumulate in skin, gills and viscera rather than muscles. Most MPs accumulated in fishery resources were cellulose and polyethylene terephthalate characterized by black and gray fibrous and lengths ranging from 0.1 mm to 1 mm. The gill retention capacity of pelagic fish to smaller-size (<0.1 mm) MPs was pronouncedly stronger than that of benthic fish. It was more accurate to assess the ecological risk of MPs in terms of the maximum size of MPs accumulated in organisms. Compared with the offshore area, the incidence of MP uptake was higher in the estuary owing to anthropogenic impacts. This study helps understand the transfer of MPs in aquatic food webs and offers a foundation for assessing the risk of human exposure to MPs.

Sources of nitrate­nitrogen in urban runoff over and during rainfall events with different grades.

Nitrogen discharged from urban areas greatly deteriorates the water quality of downstream surface water. In this study, sub-hourly high-frequency samples of urban runoff during six rainfall events were collected at the outfall of the stormwater network in an urban watershed in Beijing to explore nitrate export and transportation. Isotopic values of local road dust, soil, and network sediment were measured and used as the sources of nitrate to better elucidate the sources of the urban watershed. The contributions of various sources over and during three rainfall events with different grades were quantified and compared. The results showed that the contribution of sources changed dramatically over and during rainfall events. Along with the increase in the total rainfall amount and the going on of rainfall events, the wash-off effect in the atmosphere and on land surfaces played a more important role in nitrate output. Atmospheric deposition was the dominant contributor of nitrate in heavy and storm events (mean 59.3% and 64.8%, respectively). Network sediment contributed large proportions of nitrate in moderate and heavy events (mean 35.6% and 15.9%, respectively). The contribution of soil increased substantially in the storm event (mean 26.1%). Road dust and network sediment contributed greatly in the early stage of the heavy event. The contribution of fertilizer in heavy events was mainly because of the wash-off of road dust. The changing pattern of sources from atmospheric deposition to inorganic N fertilizer existed during the process of the storm event. The contribution of NO3- fertilizer from soil surfaces increased substantially in the later stage of the storm event. These results provide valuable references for urban nutrient management and mitigation measures implementation.

New framework for assessing urban stormwater management measures in the context of climate change.

Global climate change has necessitated the update of urban stormwater management measures (SMMs), but this task is extremely difficult due to the deficiency of evaluation caused by discreteness and the limitation of selected storm events, the ignorance of antecedent dry day (ADD) and lack of suitable stochastic storm generation method. In this study, a new framework that considers both stochastic precipitation and ADD is introduced to evaluate urban SMMs more adequately. Gamma distribution fitting, the space discarding method, the production of probability density distribution maps and multiple nonlinear regression were combined with a physical-based model to assess the effectiveness of SMMs under changing climates. Taking low impact development practices (LIDs) as an example of SSMs, the case study showed that the proposed framework provided effectiveness probability density distribution map and regression equations with more evaluation details by increasing the number and type of storm events compared with current monitoring. Moreover, it is demonstrated that ADD should be considered as one important factor in the design of LIDs, especially for controlling urban non-point source pollution. The value of ADD will significantly affect the control effect of LIDs on pollutant loads and event mean concentration in runoff, which varied for different pollutants. Through case study, it shows there is a risk that LIDs would be less effective at controlling runoff and non-point source pollution in future climate scenarios, especially for RCP 8.5 which is more extreme. Therefore, adaptation capacity of climate change should be considered in the design of SMMs. The proposed framework will be a useful tool in the assessment, design and planning of urban SMMs considering climate change.

Transport and sources of nitrogen in stormwater runoff at the urban catchment scale.

Revealing the transport and sources of nitrate in urban stormwater runoff can effectively manage nitrate pollution in urban areas. This study used the chemical properties of stormwater along with δ15N-NO3- and δ18O-NO3- isotopes to identify the transport and sources of nitrate within an urban catchment. The results showed that the NO3-N concentration and total dissolved nitrogen (TDN) composition differed among roof runoff, road runoff, and drainage runoff. The highest NO3-N concentration was found in roof runoff and NH3-N dominated the TDN composition. However, the erosion of pervious surfaces and litter may have led to higher DON/TDN values in road runoff. The TDN composition of drainage runoff was consistent with that of roof runoff. Furthermore, among the various rainfall characteristics, the depth and intensity of rainfall were significantly correlated with the NO3-N concentrations in roof runoff and road runoff, while antecedent dry days had little effect. According to a Bayesian mixing model, the average contributions of the nitrate load in drainage runoff were ranked as road runoff (51.6%) > rainwater (29.2%) > and roof runoff (15%), which is consistent with the results of previous studies. Rainwater nitrate may have ranked second due to the confluence time, pollution level, and other factors that made rainwater reduce the pollution characteristics of roof runoff. The dominant contribution of road runoff to the NO3-N concentration of drainage runoff could be attributed to the large runoff volume. Hence, effective measures should be taken to minimize the NO3-N concentration in roof runoff, while runoff volume reduction should be the primary concern for controlling road runoff pollution. This work is helpful for obtaining a better understanding of the transport and sources of nitrate that vary dynamically within different hydrological flow pathways, and the outcomes are expected to enhance targeted measures to mitigate nitrate pollution in urban water systems.

New framework for managing the water environmental capacity integrating the watershed model and stochastic algorithm.

Integrated calculations of pollution load and water environmental capacity (WEC) are essential for effective water quality management. However, few studies have focused on the dynamic WEC and pollution load in a nonpoint source pollution (NPS)-dominant temperate monsoon watershed under changing rainfall conditions. In this study, a new framework based on the watershed model and WEC calculation with stochastic rainfall input (SR-WEC), was proposed to reveal the dynamic WEC and pollution load under changing rainfall conditions. Stochastic rainfall series was generated by a first-order Markov chain and gamma distribution, and further input into the Soil and Water Assessment Tool (SWAT) to explore the dynamic response of water quality to rainfall. The framework was applied to the Daning River watershed, Three Georges Reservoir Region, China. The results suggested that compared with the new SR-WEC, the traditional return period method with limited observed rainfall input would result in an underestimation of ideal WEC and NPS pollution load by 23% and 48% for TN and 48% and 51% for TP, respectively. Approximately 46% of the annual TN reduction and 51% of the annual TP reduction were concentrated from April to June in a relatively small area. The regression relationships between rainfall and the ideal WEC, pollution load and remnant WEC obtained by the SR-WEC were superior to those of the traditional method, with R2 values increasing from 0.005-0.797 to 0.718-0.989. Specific threshold (120 mm/month for the study area) was observed for the effect of rainfall on water quality, beyond which the remnant WEC of organic N would change from decreasing to increasing. The new framework proposed identifies the key periods and areas with consideration of uncertainty of rainfall on water quality, and provides basis for NPS pollution management.