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1.
Nanomaterials (Basel) ; 12(9)2022 Apr 27.
Artigo em Inglês | MEDLINE | ID: mdl-35564193

RESUMO

Microsatellites have stringent demands for thermal dissipation systems with high efficiency but low weight, which is a difficult combination to obtain using current technologies. The design method of a new cooling system consisting of hollow metallic microlattice material filled with liquid is developed and proposed, and its heat dissipation performance is analyzed through experimental tests and numerical simulations. Through the analysis results of the influences of the microstructures of the hollow microlattice material, it is found that the effective coefficient (the number of channels taking part in convection) has the highest influence on the heat dissipation performance. Numerical simulation results illustrated that the heating surface temperature can be reduced to 301.7 K through special design, which can meet the heat dissipation requirement of most microsatellites. The new microlattice cooling system in this study improves heat dissipation performance while having very low structural weight, thus providing a feasible substitute for thermal control systems in microsatellites.

2.
J Phys Chem A ; 125(1): 423-434, 2021 Jan 14.
Artigo em Inglês | MEDLINE | ID: mdl-33377778

RESUMO

The attainment of the efficient ignition of traditional liquid hydrocarbons of scramjet combustors at low flight Mach numbers is a challenging task. In this study, a novel chemical strategy to improve the reliable ignition and efficient combustion of hydrocarbon fuels was proposed. A directional hydroboration reaction was used to convert hydrocarbon fuel into highly active alkylborane, thereby leading to changes in the combustion reaction pathway of hydrocarbon fuel. A directional reaction to achieve the hypergolic ignition of 1-octene was designed and developed by using Gaussian simulation. Borane dimethyl sulfide (BDMS), a high-energy additive, was allowed to react spontaneously with 1-octene to achieve the hypergolic ignition of liquid hydrocarbon fuel at -15 °C. Compared with the ignition delay time of pure 1-octene (565 °C), the ignition delay time of 1-octene/BDMS (9:1.2) decreased by 3850% at 50 °C. Fourier transform infrared spectroscopy and gas chromatography-mass spectrometry confirmed the directional reaction of the hypergolic ignition reaction pathway of 1-octene and BDMS. Moreover, optical measurements showed the development trend of hydroxyl radicals (OH·) in the lower temperature hypergolic ignition and combustion of 1-octene. Finally, this study indicates that the enhancement of the low-temperature ignition performance of 1-octene by hydroboration in the presence of BDMS is feasible and promising for jet propellant design with tremendous future applications.

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