Flexible molecularly imprinted glucose sensor based on graphene sponge and Prussian blue.

To enhance the sensitivity of flexible glucose sensors made with 3-aminophenylboronic acid and pyrrole as functional molecules and a carbon tri-electrode as substrate, graphene sponge (GS) and Prussian blue (PB) were used to enhance the charge transfer between the molecularly imprinted cavities and the electrodes. Electrochemical impedance spectroscopy and cyclic voltammetry showed that modifying the electrode with GS and PB significantly reduced the charge transfer impedance and increased the redox current of the sensor. The sensor has a sensitivity of up to 25.81 µA⋅loge (µM)-1⋅cm-2 for the detection of glucose using differential pulse voltammetry in the range of 7.78 to 600 µM, with a low detection limit of 1.08 µM (S/N = 3). When the pH varies in the range of 5.5 to 7.5, the sensor maintains a certain level of stability for glucose detection. The presence of lactic acid, urea, and ascorbic acid had minimal impact on glucose detection by the sensor. After 20 days of storage at room temperature, the sensor maintains 80 % efficiency. This study supports the development of wearable glucose sensors with high sensitivity, specificity, and stability through molecular imprinting.

Fine-Tuning Bi2Te3-Copper Selenide Alloys Enables an Efficient n-Type Thermoelectric Conversion.

Bismuth tellurides is one of the most promising thermoelectric (TE) material candidates in low-temperature application circumstances, but the n-type thermoelectric property is relatively low compared to the p-type counterpart and still needs to be improved. Herein, we incorporated different copper selenides (CuSe, Cu3Se2 and Cu2-xSe) into a Bi2Te3 matrix to create the alloy by grinding and successive sintering to enable higher thermoelectric performance. The results demonstrated that all alloys achieved n-type TE characteristics and Bi2Te3-CuSe exhibited the best Seebeck coefficient and power factor among them. Along with the low thermal conductivity, the maximum dimensionless TE figure of merit (ZT) value of 1.64 at 573 K was delivered for Bi2Te3-CuSe alloy, which is among the best reported results in the n-type Bi2Te3-based TE materials to the best of our knowledge. The improved TE properties should be related to the co-doping process of Se and Cu. Our investigation shows a new method to enhance the performance of n-type TE materials by appropriate co-doping or alloying.

Environmentally Tolerant Ionic Hydrogel with High Power Density for Low-Grade Heat Harvesting.

Harvesting low-grade heat by an ionic hydrogel thermoelectric generator (ITEG) into useful electricity is promising to power flexible electronics. However, the poor environmental tolerance of the ionic hydrogel limits its application. Herein, we demonstrate an ITEG with high thermoelectric properties, as well as excellent capabilities of water retention, freezing resistance, and self-regeneration. The obtained ITEG can maintain the original water content at ambient conditions (302 K, 65% relative humidity (RH)) for 7 days and keep unfreezing at a low temperature (253 K). It can even be self-regenerated and recovered to its original state after a water loss in high-temperature conditions. Furthermore, a high ionic Seebeck coefficient of 11.3 mV K-1 and an impressive power density of 167.90 mW m-2 are achieved under a temperature difference of 20 K. A high power density of 60.00 mW m-2 can also be maintained even at 258 K. After drying and regeneration, ITEG-re could even exhibit a higher ionic Seebeck coefficient of 11.8 mV K-1. Successful lighting of light-emitting diodes (LEDs) and charging of capacitors demonstrate the great potential of ITEG to provide continuous energy supply for powering flexible electronics.

Facile synthesis of copper selenides with different stoichiometric compositions and their thermoelectric performance at a low temperature range.

Copper selenide is widely considered to be a promising candidate for high-performance flexible thermoelectrics; however, most of the reported ZT values of copper selenides are unsatisfactory at a relatively low temperature range. Herein, we utilized some wet chemical methods to synthesize a series of copper selenides. XRD, SEM and TEM characterizations revealed that CuSe, Cu3Se2 and Cu2-x Se were prepared successfully and possessed different morphologies and sizes. Based on the analysis of their thermoelectric properties, Cu2-x Se exhibited the highest Seebeck coefficient and lowest thermal conductivity among the three samples owing to its unique crystal structure. After being sintered at 400 °C under N2 atmosphere, the electrical conductivity of Cu2-x Se enhanced considerable, resulting in a significant improvement of its ZT values from 0.096 to 0.458 at 30 to 150 °C. This result is remarkable for copper selenide-based thermoelectric materials at a relatively low temperature range, indicating its brilliant potential in the field of flexible thermoelectric devices.