A Magneto-Heated Ferrimagnetic Sponge for Continuous Recovery of Viscous Crude Oil.

The high viscosity and low fluidity of heavy crude oil hinder its sorption by conventional porous sorbents, so the efficient clean-up of such heavy crude oil spills is challenging. Recently, Joule heating has been emerging as a new tool to reduce the viscosity of heavy crude oil dramatically. However, this direct-contact heating approach presents a potential risk due to the high voltage applied. To develop a non-contact recovery of viscous crude oil, here, a new approach for the fabrication of a series of ferrimagnetic sponges (FMSs) with hydrophobic porous channels is reported, whose surface can be remotely heated to 120 °C within 10 s under an alternating magnetic field (f = 274 kHz, H = 30 kA m-1 ). Compared with the solar-driven superficial heating, the integral magnetic heating in FMSs can result in a higher internal temperature of the sponges because of the confinement of thermal transport in the porous channels, which contributes to a dramatic decrease in oil viscosity and a significant increase in oil flow into the pores of FMSs. Furthermore, FMSs assembled with a self-priming pump can achieve continuous recovery of viscous crude oil (33.05 g h-1 cm-2 ) via remotely magnetic heating.

Boosting photoelectrochemical efficiency by near-infrared-active lattice-matched morphological heterojunctions.

Photoelectrochemical catalysis is an attractive way to provide direct hydrogen production from solar energy. However, solar conversion efficiencies are hindered by the fact that light harvesting has so far been of limited efficiency in the near-infrared region as compared to that in the visible and ultraviolet regions. Here we introduce near-infrared-active photoanodes that feature lattice-matched morphological hetero-nanostructures, a strategy that improves energy conversion efficiency by increasing light-harvesting spectral range and charge separation efficiency simultaneously. Specifically, we demonstrate a near-infrared-active morphological heterojunction comprised of BiSeTe ternary alloy nanotubes and ultrathin nanosheets. The heterojunction's hierarchical nanostructure separates charges at the lattice-matched interface of the two morphological components, preventing further carrier recombination. As a result, the photoanodes achieve an incident photon-to-current conversion efficiency of 36% at 800 nm in an electrolyte solution containing hole scavengers without a co-catalyst.

Ultralow-Voltage-Driven Smart Control of Diverse Drop's Anisotropic Sliding by in Situ Switching Joule Heat on Paraffin-Infused Microgrooved Slippery Surface.

Stimuli-responsive anisotropic slippery surfaces (ASSs) have demonstrated intriguing performance in manipulating the behaviors of some liquids. However, most present methods have been limited to conductive droplets, certain specific conductive platforms, and higher manipulation temperature that greatly hinder its practical applications. Here, an electric-responsive paraffin-infused ASS (ER-PIASS) composed of paraffin, microgrooved PDMS, and flexible embedded silver nanowire heater is reported. Owing to the fast electric-response of ER-PIASS, smart control between anisotropic sliding and pinning for diverse liquids can be realized by remotely loading and discharging electric-stimuli. The underlying mechanism is that the generated Joule heat melts the solidified paraffin to slide a pinning droplet once an electric-trigger is loaded due to the formation of a slippery air/liquid/liquid/solid system. Once the voltage is discharged, the liquefied paraffin would rapidly solidify to stick to a slipping droplet because of the recovery of a frictional air/liquid/solid system. Additionally, the effect of the groove's height (h), spacing between two adjacent grooves (d), and thickness of the paraffin layer on the anisotropic degree was quantitatively studied and an optimized value of 75° is thus harvested. Through tuning the recipe of the hybrid lubricant, the responsive voltage and temperature for ER-PIASS can be dramatically decreased to ultralow figures of 2.0 V and 34.2 °C. By taking advantage of this ultralow-voltage-driven biocompatible ER-PIASS, we enable the anisotropic smart control of cell culture medium and yeast droplets for their directional coalesce, growth, and fission. We believe that such stimuli-responsive surfaces will be promising candidates for manipulating droplets' directional sliding behavior and further bloom the studies of flexible microfluidics devices.

Photothermal Actuation of Diverse Liquids on an Fe3O4-Doped Slippery Surface for Electric Switching and Cell Culture.

The photoinduced manipulation of liquids on a slippery lubricant-infused porous surface (SLIPS) has attracted a tremendous amount of attention because of its merits of contactless stimulation and excellent spatial and temporal control. However, tedious fabrication methods by a combination of template transfer and fluorination for a photothermal-material-doped SLIPS and the lack of deeper systematically quantitative analysis with respect to droplet hydrokinetics are greatly perplexing in both academic research and industrial applications. Here we demonstrate a kind of Fe3O4-doped SLIPS by one-step femtosecond laser cross-scanning, which can readily steer diverse liquids toward arbitrary directions with a fast velocity of up to 1.15 mm/s in the presence of a unilateral NIR stimulus. The underlying mechanism is that the wettability gradient force (Fwet-grad) induced by the temperature gradient arising from asymmetric near-infrared-irradiation (NIR) loading would be generated within 1 s to actuate a targeted droplet's sliding behavior. Through tuning the NIR irradiating sites, we can slide a targeted droplet with controllable directions and routes. On the basis of fundamental physics, we have quantitatively analyzed the relationship among Fe3O4-doped content, lubricant rheological performance, droplet wettability variations, Fwet-grad, and the sliding velocity for diverse liquid species. Accordingly, we can remotely steer liquid droplets to realize the on-off state of an electrical circuit on demand, the droplet fusion of a microfluidic reactor, and the culture/inhibition of biological cells.

In Situ Reversible Control between Sliding and Pinning for Diverse Liquids under Ultra-Low Voltage.

Thermally responsive paraffin-infused slippery surfaces have demonstrated intriguing performance in manipulating the behaviors of versatile droplets. However, present methods have been limited to ex situ rigid heat sources with a high voltage of 220 V or certain specific photothermal materials, which greatly hinders its practical applications. To solve this problem, an intelligent droplet motion control actuator (DMCA) composed of paraffin wax, hydrophobic micropillar-arrayed ZnO film, and a flexible transparent silver nanowire heater (SNWH) is reported in this work. Due to the good portability of DMCA, in situ switchable wettability for several liquid droplets with different surface tensions can be achieved by simply loading and unloading Joule heat at an ultra-low voltage (12 V). The relationship among sliding velocity and droplet volume and inclined angles was quantitatively investigated. By virtue of the flexible and mechanical endurance, this smart DMCA is dramatically functional for droplet motion manipulation ( e.g., reversible control between sliding and pinning) on complex 3D surfaces. Significantly, an impressive self-healing ability within 22 s is also demonstrated through the in situ application of Joule heat on the scratched DMCA, which renders its practical usability in various harsh conditions. This work provides insights for designing intelligent, flexible, and portable actuators dealing with the challenges of smart temperature-responsive surfaces.

Joule-heated graphene-wrapped sponge enables fast clean-up of viscous crude-oil spill.

The clean-up of viscous crude-oil spills is a global challenge. Hydrophobic and oleophilic oil sorbents have been demonstrated as promising candidates for oil-spill remediation. However, the sorption speeds of these oil sorbents for viscous crude oil are rather limited. Herein we report a Joule-heated graphene-wrapped sponge (GWS) to clean-up viscous crude oil at a high sorption speed. The Joule heat of the GWS reduced in situ the viscosity of the crude oil, which prominently increased the oil-diffusion coefficient in the pores of the GWS and thus speeded up the oil-sorption rate. The oil-sorption time was reduced by 94.6% compared with that of non-heated GWS. Besides, the oil-recovery speed was increased because of the viscosity decrease of crude oil. This in situ Joule self-heated sorbent design will promote the practical application of hydrophobic and oleophilic oil sorbents in the clean-up of viscous crude-oil spills.

Advanced Sorbents for Oil-Spill Cleanup: Recent Advances and Future Perspectives.

Oil sorbents play a very important part in the remediation processes of oil spills. To enhance the oil-sorption properties and simplify the oil-recovery process, various advanced oil sorbents and oil-collecting devices based on them have been proposed recently. Here, we firstly discuss the design considerations for the fabrication of oil sorbents and describe recently developed oil sorbents based on modification strategy. Then, recent advances regarding oil sorbents mainly based on carbon materials and swellable oleophilic polymers are also presented. Subsequently, some additional properties are emphasized, which are required by oil sorbents to cope with oil spills under extreme conditions or to facilitate the oil-collection processes. Furthermore, some oil-collection devices based on oil sorbents that have been developed recently are shown. Finally, an outlook and challenges for the next generation of oil-spill-remediation technology based on oil-sorbents materials are given.

A Stretchable Electronic Fabric Artificial Skin with Pressure-, Lateral Strain-, and Flexion-Sensitive Properties.

A stretchable and multiple-force-sensitive electronic fabric based on stretchable coaxial sensor electrodes is fabricated for artificial-skin application. This electronic fabric, with only one kind of sensor unit, can simultaneously map and quantify the mechanical stresses induced by normal pressure, lateral strain, and flexion.