Removal of dimethyl sulphide via a bio-scrubber under anoxic conditions.

The removal performance of dimethyl sulphide (DMS) by anoxic laboratory-scale bio-scrubber was studied under different operation conditions for 315 days. DMS removal in bio-scrubber system was performed by controlling and changing the operation parameters, including inlet concentration, empty bed residence time (EBRT) and spraying density (SD) of irrigation. Best conditions in the system were achieved for SD of 0.18 m3/m2 h within EBRT of 40 s at an inlet gas concentration of 150 mg/m3 in which 93% of waste gas stream was removed in the bio-scrubber column and bio-degradation in the bio-reactor tank led to 89% of DMS removal from the transferred bio-reactor, while 91.5% of input chemical oxygen demand (COD) was successfully removed. The use of closer values of the average experimental yield to the theoretical value (YNO3/NO3 -) of 0.74 led to the production of elemental sulphur (S°) and other sulphur forms rather than sulphate (SO42-) , which was also was recognized as a pale-yellow coloured substance of S° that appeared within the biomass.

Removal of ethanethiol using a biotrickling filter with nitrate as an electron acceptor.

Many studies have discussed the biotreatment of ethanethiol (ET) under aerobic conditions. However, O2 free conditions offer bio-conversion of ET gas into elemental sulphur and/or sulphate using [Formula: see text] as electron acceptor, and this has been not studied. In this study, an anoxic biotrickling filter was tested in lab-scale conditions with ET/[Formula: see text] ratio 0.74 and 0.34 mole/mole to remove malodorous ET waste gas. The study examined the effect of three operational parameters: ET inlet concentrations (150, 300, 800, and 1500 mg/m3), trickling velocities (0.12, 0.18, 0.24, 0.3, and 0.45 m/h), and empty bed residence times (30, 60, 90, and 120 s). It found that the effect of trickling velocity on removal efficiency depended on inlet concentrations; 0.24 m/h trickling velocity resulted in efficient ET removal (higher than 90.8% for 150 mg/m3 of inlet concentration) while 0.45 m/h trickling velocity could only achieve a removal of 80.6% for 1500 mg/m3 of inlet concentration at fixed EBRT 60 s. Increasing the EBRT up to 60 s was adequate to achieve removal efficiency, i.e. 92 and 80% for ET inlet concentrations 150 and 1500 mg/m3 respectively, and the maximum elimination capacity was 75.18 g/m3/h at 0.45 m/h. Overall, the anoxic conditions enhanced the low oxidation rates of ET in an anoxic biotrickling filter despite mass transfer limitations and poor solubility of ET.

Ethanethiol gas removal in an anoxic bio-scrubber.

The performance of ethanethiol removal in an anoxic lab-scale bio-scrubber was investigated under different operating parameters and conditions for 300 days. The removal efficiency (RE) of ethanethiol was examined as a function of inlet concentration, empty bed residence time (EBRT) and spray density of irrigation. The results showed the best operation conditions and operation characteristics of the bio-scrubber for this study were at an inlet concentration of 150 mg/m3, a spray density of 0.23 m3/m2 h and an EBRT of 90 s. An average RE of 91% and elimination capacity (EC) of 24.74 g/m3 h was found for all inlet ethanethiol concentrations. Variations in spray density higher than 0.23 m3/m2 h had no effect on ethanethiol RE at different ethanethiol concentrations. The average experimental yield values were closer to the YET/NO3- theoretical value of 0.74 when the main product was elemental sulphur (So). This indicates that So and other forms of sulphur were formed rather than sulphate (SO42-) as the end product. Furthermore, growth kinetics for bio-degradation were evaluated in batch culture experiments using the Monod model, and bio-kinetic parameters of µmax, Ks, Yxs and qmax were obtained as 0.14 1/h, 1.17 mg/L, 0.52 gx/gs and 0.26 gs/gx h, respectively.