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Chem Commun (Camb) ; 58(44): 6401-6404, 2022 May 30.
Artigo em Inglês | MEDLINE | ID: mdl-35543291

RESUMO

Cu complexes with p-dimethylaminophenolate ligands were synthesized by the reaction of CuII ions with the ligands under inert gas atmosphere and characterized. The complexes showed a valence state change from CuII-phenolate to CuI-phenoxyl radical on loss of the coordinated solvent. The CuI-phenoxyl radical species showed the characteristic properties and reactivities.


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Cobre , Fenóis , Ligantes , Oxirredução
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