1.
Beilstein J Org Chem
; 14: 531-536, 2018.
Artigo
em Inglês
| MEDLINE
| ID: mdl-29623114
RESUMO
[Bis(trifluoroacetoxy)iodo]benzene (BTI) and (diacetoxyiodo)benzene (DIB) efficiently promote the formation of acylnitroso species from hydroxamic acids in the presence of various dienes to give the corresponding hetero-Diels-Alder (HDA) adducts in moderate to high yields. The present method could be applied to the HDA reactions of acylnitroso species with o-benzoquinones generated by the oxidative dearomatization of guaiacols.
2.
Org Lett
; 17(21): 5212-5, 2015 Nov 06.
Artigo
em Inglês
| MEDLINE
| ID: mdl-26492530
RESUMO
Tetra-n-butylammonium iodide can efficiently catalyze direct azidation of aldehyde C-H bonds with thermally stable azidobenziodoxolone at room temperature. Compared to conventional methods, which require excessive amounts of highly explosive azide sources, this is a safe and convenient procedure.