Synthesis of p-CuO/n-ZnO heterostructure by microwave hydrothermal method and evaluation of its photo and bio-catalytic performance.

The use of photocatalysts without noble metals is of great interest in the industrial field for the degradation of organic pollutants. In this study, a CuO/ZnO heterostructure was synthesized using the microwave hydrothermal method and characterized using various analytical techniques. The synthesized CuO/ZnO photocatalyst exhibited a low bandgap energy of 2.4 eV, enabling efficient visible light absorption. The photocatalytic activity of the CuO/ZnO heterostructure was evaluated for the degradation of Methyl Orange (MO) dye and showed a high degradation efficiency of 99 % due to its excellent electron-hole charge separation. The biological activity of the synthesized CuO/ZnO catalyst was further investigated through protein docking studies, which showed promising results. The CuO/ZnO was also evaluated for its anticancer and antibacterial properties. It exhibited effective anticancer activity against prostate cancer cells (PC-3) in a dose-dependent manner, with an IC50 value of 6.87 ± 8. In addition, it demonstrated potent antibacterial activity against Escherichia coli, Staphylococcus aureus, Bacillus cereous and Pseudomonas aeruginola. The results of this study demonstrate the potential of CuO/ZnO heterostructures as promising materials for various applications in the fields of photocatalysis, biomedicine and antimicrobial materials. Future research in this area will focus on further optimizing the properties of the CuO/ZnO heterostructure to enhance its performance in these applications.

Microwave hydrothermal preparation of reduced graphene oxide-induced p-AgO/n-MoO3 heterostructures for enhanced photocatalytic activity through S-scheme mechanism and its electronic performance.

Through a powerful and modest closed system Microwave hydrothermal process, a methodological analysis is made in the rational synthesis of the reduced graphene oxide-induced p-AgO/n-MoO3 (RGAM) heterostructures. These have strong p-n junction heterostructures with considerable electron-hole recombination functioning as solar catalysts. The enhanced photocatalytic activity through the plasmonic step scheme (S-scheme mechanism) describes the effective charge recombination process. The energy band positions, bandgap, and work function are determined to understand the Fermi level shifts; this describes the S-scheme mechanism by UPS analysis which assessed an electron transfer between AgO and MoO3, yielding work function values of 6.34 eV and 6.62eV, respectively. This photocatalytic activity aids in dye removal by 94.22%, and heavy metals such as chromium (Cr) are eliminated by the surface action of sunlight on the produced material during solar irradiation. Electrochemical studies such as photocurrent response, cyclic voltammogram, and electrochemical impedance spectroscopy for RGAM heterostructures were also carried out. The study helps to broaden the search for and development of new hybrid carbon composites for electrochemical applications.

Designing of graphene oxide-induced p-NiO/n-MoO3 heterostructures for improved photocatalytic activity through plasmon-enhanced S-scheme mechanism and its biological and electrochemical performance.

An environmentally benign, economically advantageous microwave hydrothermal approach is used in synthesis of desirably tailored graphene oxide-induced p-NiO/n-MoO3 (GNM) heterostructures. Various analytical techniques such XPS, XRD, UPS, EIS, and Mott-Schottky were conducted to comprehend complete morphology and functioning of the novel ternary heterostructure photocatalysts. Also, SEM and HR-TEM images were presented for better interpretation. The strategic plasmonic step scheme (S-scheme) charge migration approach was used to describe the effective charge recombination process. Hydroxyl and oxide active species were corollaries of the reactive radical-scavenging experiments and electron spin resonance. The work function has been confirmed using ultraviolet photoelectron spectroscopy (UPS), which assessed an electron transfer between NiO and MoO3, yielding work function values of 6.32 eV and 5.26 eV, respectively. The cell apoptosis of the HeLa cell line approves the material's biocompatibility. Cyclic voltammetry and electrochemical impedance spectroscopy reveal electrochemical performance of GNM heterostructures. We anticipate our results would pave the way for current and future applications. In order to ensure eco-restoration such photocatalyst which are eco and cost friendly are synthesized. Assessment of pollutant risks presents the impact of them on human and terrestrial and aquatic animals. Sustainability of material is acknowledge as they use solar light for photocatalysis and dye degradation, and hence can be green material. One such material for the treatment of wastewater, dye-infused waters, and industrial water has been tailored, which is capable of dye degradation, heavy metal, and other pollutant removal. Very importantly, the synthesized material is a biocompatible one.

Developing of semi-transparent α-Fe2O3/Cu2O heterostructures with S-scheme photocatalytic activity and biological interests.

The scarcity of water has been an outgrowing problem, while population is increasing so is the demand for the water. Hence conservation of water is most important and this material might bring in drastic changes in recycling the wastewater into portable ones. The α-Fe2O3/Cu2O is a desirably tailored nanomaterial synthesized using eco-friendly cost-effective hydrothermal method, where α-Fe2O3 and Cu2O were synthesized separately and later combined to produce an effective material. The material are characterized using advanced techniques like XPS, HR-TEM, XRD, FT-IR, BET, UV-DSR, ESR, LC-MS, ICP-AES, and UPS to understand complete morphology and functioning of the material. They are examined for various application in different fields such as dye degradation, heavy metal removal and organic pollutants elimination via photocatalysis under solar irradiation. The α-Fe2O3 and Cu2O had the work function of 6.10 and 5.49 eV respectively and band energy of 1.46 and 2.6 eV. Docking analysis was carried out to know the protein docking efficiency. Biocompatibility of the materials is addressed upon the HeLa cell line and α-Fe2O3/Cu2O exposure causes inflammation in the lung fluids in a mouse model using the Bronchoalveolar lavage (BAL) assay at high concentrations, proving that the materials can help with current and future biological applications.

Fabrication of spherical porous pAg2O-nWO3/Ag/GNS heterostructure with enhanced photocatalytic activity through plasmonic S-scheme mechanism and its complementing biological interest.

The synthesis and characterization of Ag2OWO3/Ag/GNS heterostructure with desired modifications has been elucidated in the contemporary study. The fabrication involves a simple hydrothermal method for the configuration of fascinating heterostructures intended to photo-catalytically degrade Eosin Yellow (EY) dye. The toxic dye molecules were converted into non-toxic molecular intermediates, also the elimination of heavy metals from industrial wastewater, being trapped in the pores of heterostructure. The pn junction photocatalyst with plasmonic resonance of Ag for abolition of electron and hole coupling, enhances the photo-response where the catalyst abides S-Scheme mechanism. The work functions of active photocatalysts as calculated for Ag2O is 6.61eV and WO3 is 6.04eV. Furthermore, the Ag2OWO3/Ag/GNS photocatalysts recovery and reuse in several trials without any noticeable loss of photocatalytic activity, complimented the recyclability of the heterostructure. To ensure the safety of the environment on heterostructure being released, toxicity analysis were carried out. These Ag2OWO3/Ag/GNS heterostructures had optimistic result on cytotoxicity assay, and on Musmusculus skin melanoma cells (B16-F10), with anti-microbial/fungal properties. Thereby, the contemporary experiment upholds efficient photocatalysis and ropes multiple errands on biological applications.

Dry-Coated Graphite onto Sandpaper for Triboelectric Nanogenerator as an Active Power Source for Portable Electronics.

Developing an eco-friendly, flexible and recyclable micro-structured dry electrode for sustainable life is essential. In this work, we have developed irregular, micro-structured sandpaper coated with graphite powder as an electrode for developing a simple, low-cost, contact-separation mode graphite-coated sandpaper-based triboelectric nanogenerator (GS-TENG) as a self-powered device and biomechanical sensor. The as-fabricated GS-TENG is a dielectric-conductor model. It is made up of a bottom layer with polytetrafluoroethylene (PTFE) as a triboelectric layer, which is attached onto a graphite-coated sandpaper-based electrode and a top layer with aluminum as another triboelectric layer as well as an electrode. The forward and reverse open-circuit voltages reach upto ~33.8 V and ~36.62 V respectively, and the forward and reverse short-circuit currents are ~2.16 µA and ~2.17µA, respectively. The output generated by GS-TENG can power 120 blue light-emitting diodes connected in series, liquid crystal display and can charge commercial capacitors along with the rectifier circuit. The capacitor of 22 µF is charged upto 5 V and is sufficient to drive digital watch as wearable electronics. Moreover, the device can track signals generated by human motion, hence it scavenges biomechanical energy. Thus, GS-TENG facilitates large-scale fabrication and has potential for future applications in wearable and portable devices.