RESUMO
Chemical gardens are self-organized precipitate structures such as thin-walled tubes and membrane-bound cells reminiscent of biological shapes. These usually inorganic precipitates compartmentalize the reaction system and allow the study of materials synthesis in very steep concentration gradients. We create such tubes by steadily injecting a mixture of MnCl2 and CuSO4 solutions into a large reservoir of sodium silicate solution. The growing tube is open at its tip and ejects a stream of colloidal particles that aggregate to form a secondary tube above the original one. This secondary tube can coil into a tightly wound nest-like structure, freely suspended underneath the solution-air interface. Using three-dimensional image reconstruction, we analyze the onset of coiling and show that the structure is helical with a helix radius that increases in the vertical direction. The height at which the coiling begins is lowered with each successive repeat of the growth experiment, suggesting that coiling is induced by small variations in the density of the silicate solution.
