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1.
Nanomaterials (Basel) ; 7(11)2017 10 30.
Artigo em Inglês | MEDLINE | ID: mdl-29084146

RESUMO

The authors wish to make the following correction to this paper [1]. In Equation (8), logarithm (ln) term is missing[...].

2.
Nanomaterials (Basel) ; 7(7)2017 Jun 27.
Artigo em Inglês | MEDLINE | ID: mdl-28654011

RESUMO

P-type Mg doped CuCrO2 thin films have been deposited on fused silica substrates by Radio-Frequency (RF) magnetron sputtering. The as-deposited CuCrO2:Mg thin films have been annealed at different temperatures (from 450 to 650 °C) under primary vacuum to obtain the delafossite phase. The annealed samples exhibit 3R delafossite structure. Electrical conductivity σ and Seebeck coefficient S of all annealed films have been measured from 40 to 220 °C. The optimized properties have been obtained for CuCrO2:Mg thin film annealed at 550 °C. At a measurement temperature of 40 °C, this sample exhibited the highest electrical conductivity of 0.60 S·cm-1 with a Seebeck coefficient of +329 µV·K-1. The calculated power factor (PF = σS²) was 6 µW·m-1·K-2 at 40 °C and due to the constant Seebeck coefficient and the increasing electrical conductivity with measurement temperature, it reached 38 µW·m-1·K-2 at 220 °C. Moreover, according to measurement of the Seebeck coefficient and electrical conductivity in temperature, we confirmed that CuCrO2:Mg exhibits hopping conduction and degenerates semiconductor behavior. Carrier concentration, Fermi level, and hole effective mass have been discussed.

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