1.
Angew Chem Int Ed Engl
; 62(5): e202214031, 2023 Jan 26.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36383088
RESUMO
Cyclopentannulation was explored as a strategy to access large, stable azaarenes. Buchwald-Hartwig coupling of previously reported di- and tetrabrominated cyclopentannulated N,N'-dihydrotetraazapentacenes furnished stable azaarenes with up to 13 six-membered rings in a row and a length of 3.1â nm. Their optoelectronic and semi-conducting properties as well as their aromaticity were investigated.