Manufacturing Options for Activated Carbons with Selected Synthetic Polymers as Binders.

Formed activated carbon (AC) is a multipurpose product with developed adsorption properties that is widely used in various areas of life. To create AC, hard coal has to go through various processes: grinding, granulation, carbonization, physical and/or chemical activation. Presented research was conducted in the professional company manufacturing activated carbons. Studied AC reached the demanded shape of grains thanks to binders added to granulation process. Research on the AC formed using new polymeric binders (applied so far in other branches: pharmacy and construction materials) is presented in this manuscript. Tested binders were not used before to manufacture ACs in the professional technological line. Such polymers as: sodium carboxymethylhydrocellulose (CMHC), poly[1-(2-oxo-1-pyrrolidinyl)ethylene] (POPE) and enriched methyl-hydroxypropyl cellulose MHPC were studied in this work. Conducted research has proven efficiency of 8% CMHC which allowed for proper granulation and carbonization and reached the best parameters. Single- and double-stage activation was investigated for AC with this binder. For newly manufactured AC BET surface and pore volume increased accordingly from 774 m2/g and 0.58 cm3/g (1-stage) to 968 m2/g and 0.72 cm3/g (2-stage). Chemical elemental features of surface of the best AC showed beside elementary carbon also calcium, silicon and aluminum ions as well as groups with an acidic character, phosphates, sulphates and chlorides. The new AC had a higher Mechanical Strength reaching 99.9% and a lower Ash content and Volatile Matter than AC manufactured with previous binder-molasse. The new AC is intended to be directed for full production line and implementation to usage after positive certification. It may be useful in water treatment. It will also find application in the treatment of industrial and municipal wastewater.

Biosorption of LMW PAHs on activated sludge aerobic granules under varying BOD loading rate conditions.

Polycyclic aromatic hydrocarbons belong to the main priority substances for the aquatic environment. One of the emission sources of these compounds to environment is wastewater discharged from conventional wastewater treatment systems, which are not designed to cope with this type of pollution. Thus, due to the widely discussed properties of aerobic granular activated sludge in the literature - a conducted study has proven its ability to remove LMW PAHs (naphthalene (Nap), acenaphthylene (Acy), acenaphthene (Ace), fluorene (Flu), phenanthrene (Phe) and anthracene (Ant)) from wastewater by biosorption process at varying loadings of organic compounds expressed as BOD (kg/kg·d) on the activated sludge mass. The maximum biosorption of Nap was 605 µg/kgd.m., Acy equals to 134 µg/kgd.m., Ace equals to 355 µg/kgd.m. Flu equals to 104 µg/kgd.m. Phe equal to 204 µg/kgd.m. and Ant equal to 173 µg/kgd.m. The study showed that the BOD loading rate is one of the factors affecting the biosorption process of LMW PAHs. However, as the amount of adsorbed LMW PAHs increased, the condition of aerobic granular activated sludge deteriorated, which was evidenced by gradual increase in the values of technological parameters of activated sludge (SVI, HRT, SRT) and a smaller increase in activated sludge dry mass.

Research on the Development of Technologies for the Production of Granulated Activated Carbons Using Various Binders.

Activated carbons (ACs) are processed carbon-rich materials with a highly developed inner surface and significant porosity used for different media treatment in municipal and industrial plants. Activated carbon may be manufactured as powdered activated carbon (PAC), gritty activated carbon (in a form of raw angels grains) or granulated activated carbon (GAC). The production of the GAC is based on carbonaceous raw materials and various types of binders. The carbon mass is mixed with the binder and formed in cylindrical granules. The binder's recognition is in a scientific literature side-topic and still needs wider examination. For many years GAC production have been concentrated on the possibility of using sodium carboxymethylcellulose (SCMC). Therefore, the aim of the research was to develop a new binder, in the available technology of granulated activated carbon production. Such binders were tested such as: tall oil (TO), sugar beet molasses (SBM), sodium carboxymethylcellulose (SCMC), SCMC using a verified technological process and SCMC with the addition of gas tar (GT). The conducted research shows that all the quality requirements were met by activated carbons with SBM as a binder. Additionally they showed very high adsorption properties. The manufacturing process was shorter in comparison to other tested binders and more efficient.

Alternated biodegradation of naphthalene (NAP), acenaphthylene (ACY) and acenaphthene (ACE) in an aerobic granular sludge reactor (GSBR).

The paper presents quantitative changes of selected 2- and 3-ring PAHs after process phases of GSBR reactor. The studies have been carried out for 264 cycles of GSBR reactor, during which concentration of naphthalene was increased in the range of 3.00-710.00 µg/L, acenaphthylene 1.00-160.00 µg/L, acenaphthene 3.00-440.00 µg/L. GSBR operating cycle consisted of filling (30 min), mixing (90 min), aeration (540 min), sedimentation (10 min), decanting (30 min) and downtime (20 min) phases. Activated sludge dry mass concentration was 4.00 kg/m3. Conducted studies showed that in GSBR reactor naphthalene was degraded with the highest intensity. Results of the statistical analysis confirmed that naphthalene concentrations were statistically significantly different (α = 0.05) after each individual GSBR process phase, while in case of acenaphthene and acenaphthylene, the differences were observed only between mixing and aeration phases. Additionally, equations estimating concentrations of PAHs in treated wastewater were developed. Selected activated sludge technological parameters (sludge volume index, sludge and hydraulic retention time) and concentration of PAHs were used for equations. The R2 coefficients of equations were above 0.99, which indicates a good adjustment of estimation to observed values.