Synthesis and low-order optical nonlinearities of colloidal HgSe quantum dots in the visible and near infrared ranges.

We synthesize colloidal HgSe quantum dots and characterize their nonlinear refraction and nonlinear absorption using a Nd:YAG laser and its second harmonic. The 7.5 nm quantum dots were synthesized using the hot-injection method. The nonlinear absorption (ß = 9×10-7 cm W-1) and negative nonlinear refraction (γ = -5×10-12 cm2 W-1) coefficients of colloidal quantum dots were determined using the 10 ns, 532 nm laser radiation. The joint influence of above processes was realized at a higher intensity of probe pulses. In the case of 10 ns, 1064 nm radiation, only negative nonlinear refraction dominated during z-scans of these quantum dots. The studies of optical limiting using two laser sources demonstrated the effectiveness of this process at 532 nm. The role of nonlinear scattering is analyzed. We discuss the mechanisms responsible for the nonlinear refraction processes in colloidal HgSe quantum dots.

Effective high-order harmonic generation from metal sulfide quantum dots.

In the past, common media for high-order harmonic generation (HHG) has been atoms and molecules. More recently, clusters, and nanoparticles have been introduced as HHG emitting media. Multi-particle media can enhance HHG yields but have more stringent requirements in determining the optimal parameters. Here, we demonstrate, for the first time, the effective application of 1-3 nm metal sulfide quantum dots (QDs) for harmonic generation in the 20 - 115 nm extreme ultraviolet range. We report on the syntheses, ablation of Ag2S, CdS, and ZnS QDs, and HHG from laser-produced plasmas by using single- and two-color pumps. We compare HHG efficiency from the ablated QDs to that of bulk metal sulfides and show a seven-fold increase in harmonic yields. Further, the study also allows us to understand the effects of QD-contained plasma spreading dynamics on HHG yield.