Ecotoxicological Assessment of Potentially Toxic Elements (as, Cd, Ni and V) Contamination in the Sediments of Southern Part of Caspian Sea, the Case of Khazar Abad, Mazandaran Province, Iran.

In this study, the contamination of arsenic, cadmium, nickel and vanadium in the surface sediments of Khazar Abad, in the southern part of the Caspian Sea was analyzed in 2019 using ecotoxicological indices. The geoaccumulation index (Igeo) values showed that the sediment samples of the study area could be classified as 'unpolluted' to 'strongly polluted', while, the values of toxic units (TUs) with an average value of 0.591 indicated that all samples could be classified as 'at low toxicity level'. Moreover, the ecotoxic risk level (TRI) in the studied sediments was classified at the level of 'no toxic risk' for Cd and 'considerable toxic risk' for As and Ni. On the whole, the results showed that the levels of contamination were higher in the areas where industrial, domestic and agricultural wastewater was discharged (i.e. S4, S7, S10, S11 and S12). Finally, to avoid and/or reduce ecotoxicological dangers, periodic monitoring of PTEs in the coastal strip of the southern part of the Caspian Sea is recommended.

Using a modified version of Airpacts model for estimating the damage posed by sulfur dioxide emission from power plants to urban and rural building façades (case study: Shahid Rajaee power plant, Qazvin Province, Iran).

This study aimed at upgrading the Air Indicator Report for Public Awareness and Community Tracking (Airpacts) model to evaluate the physical effects of sulfur dioxide (SO2) emissions from Shahid Rajaee power plant on the building façades in Qazvin, Iran in 2018. For this purpose, first, the methodological requirements of the model for the study area, including wind speed, relative humidity, and temperature, were analyzed. Then, the concentration of SO2 emission from the power plant stack was calculated using the Aeroqual Model 200. The obtained data were processed and loaded into the Airpacts model version 1.0. After localization of the costs for reconstruction of 1 m2 of façade, including the costs of purchasing materials, installation, and transport from the power plant, the damage posed by SO2 to the building façades in Qazvin was calculated. Outputs of the modified model suggested that the damage to the building façades included cleansing in contact with SO2 was 494,558,878.12 m2. Based on the calculations, the cost of damage caused by SO2 was estimated to be $0.25 per Megawatt-hour (MWh) electricity generation, reaching an amount of $29,422 annually. Based on the localized results obtained by the modified Airpacts, the external cost of damage to the façades was $0.3 per MWh electricity generation, reaching an amount of $35,720 annually. To overcome the constraints of the original model concerning the constant parameters of mixing height and wind speed in the default model algorithm, the two parameters were considered dynamic variables in the modified model.

Potential health risk assessment of heavy metals via consumption of caviar of Persian sturgeon.

Caviar may contain high levels of toxic metals. Therefore determination of health risk assessment of the heavy metals in this luxury product is vital. In this study, an Inductively Coupled Plasma-Optical Emission Spectrometer and a Direct Mercury Analyzer were used to assess the contents of elements in caviar of wild Persian sturgeon. The results showed that the contents of Ba, Cr, Fe, Hg, Mn and Zn (mgkg-1) in caviar samples were 0.95, 0.27, 71.3, 1.44, 0.01 and 17.0, respectively. Also, Health Risk Index values were within the safe limits (HRI<1), and there is no potential health risk for adults and children via consumption of caviar. Finally, considering the contents of Fe and Hg were higher than Maximum Permissible Limits in the caviar samples related to the discharge of pollutants into the aquatic environment, monitoring of chemicals accumulation in the foodstuff is recommended.

Selected heavy metals analysis of Persian sturgeon's (Acipenser persicus) caviar from Southern Caspian Sea.

The present research reports the heavy metal (Fe, Cr, Pb, As, and Co) contamination in caviar of Persian sturgeon (Acipenser persicus) caught from Southern Caspian Sea sampling site using ICP-OES. Heavy metal concentrations (microgram per gram, wet weight; means ± S.D.) in caviar samples were: Fe, 71.33 ± 0. 37; Cr, 0.27 ± 0.019; Pb, <0.01 ± 0.002; As, <0.01 ± 0.002; and Co, <0.01 ± 0.001, respectively. Comparative evaluation of these metals in different samples showed that except Fe, the average concentrations of Cr, Pb, As, and Co are significantly lower than adverse level for the species themselves and for human consumption when compared with FAO/WHO permissible limits. Therefore, their contribution to adverse health effects on human body can be considered as negligibly small.

Metal content in caviar of wild Persian sturgeon from the southern Caspian Sea.

Caviar (fish roe of sturgeon) may contain high levels of contaminants. An inductively coupled plasma-optical emission spectrometer and a direct mercury analyzer were used to assess the contents of four heavy metals (Hg, Se, Sn, and Ba) in caviar of wild Persian sturgeon sea foods. The levels of Hg ranged from 1.39 to 1.50 µg g(-1), Se from 0.90 to 1.10 µg g(-1), Sn from 0.23 to 0.33, and Ba from 0.71 to 1.17 µg g(-1). Evaluation of these levels showed that except for Hg, the average concentrations of other metals are significantly lower than adverse level for the human consumption when compared with Food and Agricultural Organization of the United Nations and World Health Organization permissible limits. Therefore, their contribution to the total body burden of these heavy metals can be considered as negligibly small given that caviar is a luxury product.

Heavy metals removal from wastewaters using organic solid waste-rice husk.

In this study, the removal of Cr(III) and Cu(II) from contaminated wastewaters by rice husk, as an organic solid waste, was investigated. Experiments were performed to investigate the influence of wastewater initial concentration, pH of solution, and contact time on the efficiency of Cr(III) and Cu(II) removal. The results indicated that the maximum removal of Cr(III) and Cu(II) occurred at pH 5-6 by rice husk and removal rate increased by increased pH from 1 to 6. It could be concluded that the removal efficiency was enhanced by increasing wastewater initial concentration in the first percentage of adsorption and then decreased due to saturation of rice husk particles. Also according to achieved results, calculated saturation capacity in per gram rice husk for Cr(III) and Cu(II) were 30 and 22.5 mg g(-1), respectively. The amounts of Cr(III) and Cu(II) adsorbed increased with increase in their contact time. The rate of reaction was fast. So that 15-20 min after the start of the reaction, between 50 and 60 % of metal ions were removed. Finally, contact time of 60 min as the optimum contact time was proposed.

A new catalytic-spectrophotometric method for quantification of trace amounts of nitrite in fruit juice samples.

A new kinetic method has been developed for the determination of nitrite in fruit juice samples. The method is based on the catalytic effect of nitrite with the oxidation of Nile Blue A (NBA) by KBrO(3) in the sulfuric acid medium. The optimum conditions obtained are 1.2 mM sulfuric acid, 0.034 mM of NBA, 2.8 × 10(-3) M KBrO(3), reaction temperature of 20 °C, and reaction time of 100 s at 595.5 nm. Under the optimized conditions, the method allowed the quantification of nitrite in a range of 0.2-800 µg/mL with a detection limit of 0.02 µg/mL. The method was applied to the determination of nitrite in 15 brands of fruit juice samples.

Analysis of mercury, selenium, and tin concentrations in canned fish marketed in Iran.

The presence of heavy metals in the environment could constitute a hazard to food security and public health. These can be accumulated in aquatic animals such as fish. In the present paper, three heavy metals (mercury, selenium, and tin) in canned products produced and sold in Iran were studied: longtail tuna, Kawakawa, Kilka, and yellowfin tuna were determined using inductively coupled plasma-optical emission spectrometer and a direct mercury analyzer. Analytical results were validated by spiking the samples with various concentrations of these metals to test recovery. The metal contents, expressed in micrograms per gram, wet weight, varied depending upon the species studied. The levels of Hg ranged from 0.0003 to 0.408 µg/g, the levels of Sn ranged from 0.036 to 0.480 µg/g, while the levels of Se ranged from 0.130 to 4.500 µg/g. Comparative evaluation of these metals in different brands of canned fish showed that the average concentrations of Hg, Sn, and Se of all species is significantly lower than adverse level for the species themselves and for human consumption when compared with FAO/WHO permissible limits. Therefore, their contribution to the total body burden of these heavy metals can be considered as negligibly small.

New kinetic-spectrophotometric method for monitoring the concentration of iodine in river and city water samples.

A new kinetic method has been developed for the determination of iodine in water samples. The method is based on the catalytic effect of I(-) with the oxidation of Indigo Carmine (IC) by KBrO(3) in the sulfuric acid medium. The optimum conditions obtained are 0.16 M sulfuric acid, 1 × 10(-3) M of IC, 1 × 10(-2) M KBrO(3), reaction temperature of 35°C, and reaction time of 80 s at 612 nm. Under the optimized conditions, the method allowed the quantification of I(-) in a range of 12-375 ng/mL with a detection limit of 0.46 ng/mL. The method was applied to the determination of iodine in river and city water samples with the satisfactorily results.

Analysis of trace elements (Cu, Cd, and Zn) in the muscle, gill, and liver tissues of some fish species using anodic stripping voltammetry.

Heavy metal (Cu, Cd, Zn) concentration of the muscle, gill, and liver of Otolithes rubber, Pampus argenteus, Parastromateus niger, Scomberomorus commerson, and Onchorynchus mykiss are determined by anodic stripping voltammetry method. The results show that the concentration of Cu, Cd, and Zn varied between 0.44 and not detected, 0.585 and 0.001, and 0.450 and 0.005 µg/g, respectively. It is interesting that in O. mykiss, the mean value of copper concentration was more than other marine organisms of this study, while in P. niger, the mean value of copper was minimum. The results of this study indicate that in the different tissues of fish species (O. rubber, P. argenteus, P. niger, S. commerson, and O. mykiss), the concentrations of Cu, Cd, and Zn were significantly lower than the permissible FAO/WHO levels.