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1.
Entropy (Basel) ; 26(1)2024 Jan 16.
Artigo em Inglês | MEDLINE | ID: mdl-38248200

RESUMO

Eisenbud-Wigner-Smith delay and the Larmor time give different estimates for the duration of a quantum scattering event. The difference is most pronounced in the case where the de Broglie wavelength is large compared to the size of the scatterer. We use the methods of quantum measurement theory to analyse both approaches and to decide which one of them, if any, describes the duration a particle spends in the region that contains the scattering potential. The cases of transmission, reflection, and three-dimensional elastic scattering are discussed in some detail.

2.
Phys Chem Chem Phys ; 26(4): 3647-3666, 2024 Jan 24.
Artigo em Inglês | MEDLINE | ID: mdl-38224460

RESUMO

The aim of the present paper is to bring clarity, through simplicity, to the important and long-standing problem: does a resonance contribute to the forward-angle scattering of the F + H2 reaction? We reduce the problem to its essentials and present a well-defined, yet rigorous and unambiguous, investigation of structure in the differential cross sections (DCSs) of the following three state-to-state reactions at a translational energy of 62.09 meV: F + H2(vi = 0, ji = 0, mi = 0) → FH(vf = 3, jf = 0, 1, 2, mf = 0) + H, where vi, ji, mi and vf, jf, mf are the initial and final vibrational, rotational and helicity quantum numbers respectively. Firstly, we carry out quantum-scattering calculations for the Fu-Xu-Zhang potential energy surface, obtaining accurate numerical scattering matrix elements for indistinguishable H2. The calculations use a time-independent method, with hyperspherical coordinates and an enhanced Numerov method. Secondly, the following theoretical techniques are employed to analyse structures in the DCSs: (a) full and Nearside-Farside (NF) partial wave series (PWS) and local angular momentum theory, including resummations of the full PWS up to second order. (b) The recently introduced "CoroGlo" test, which lets us distinguish between glory and corona scattering at forward angles for a Legendre PWS. (c) Six asymptotic (semiclassical) forward-angle glory theories and three asymptotic farside rainbow theories, valid for rainbows at sideward-scattering angles. (d) Complex angular momentum (CAM) theories of forward and backward scattering, with the Regge pole positions and residues computed by Thiele rational interpolation. Thirdly, our conclusions for the three PWS DCSs are: (a) the forward-angle peaks arise from glory scattering. (b) A broad (hidden) farside rainbow is present at sideward angles. (c) A single Regge pole contributes to the DCS across the whole angular range, being most prominent at forward angles. This proves that a resonance contributes to the DCSs for the three transitions. (d) The diffraction oscillations in the DCSs arise from NF interference, in particular, interference between the Regge pole and direct subamplitudes.

3.
Entropy (Basel) ; 24(7)2022 Jun 26.
Artigo em Inglês | MEDLINE | ID: mdl-35885100

RESUMO

Probabilities of the outcomes of consecutive quantum measurements can be obtained by construction probability amplitudes, thus implying the unitary evolution of the measured system, broken each time a measurement is made. In practice, the experimenter needs to know all past outcomes at the end of the experiment, and that requires the presence of probes carrying the corresponding records. With this in mind, we consider two different ways to extend the description of a quantum system beyond what is actually measured and recorded. One is to look for quantities whose values can be ascertained without altering the existing probabilities. Such "elements of reality" can be found, yet they suffer from the same drawback as their EPR counterparts. The probes designed to measure non-commuting operators frustrate each other if set up to work jointly, so no simultaneous values of such quantities can be established consistently. The other possibility is to investigate the system's response to weekly coupled probes. Such weak probes are shown either to reduce to a small fraction the number of cases where the corresponding values are still accurately measured, or lead only to the evaluation of the system's probability amplitudes, or their combinations. It is difficult, we conclude, to see in quantum mechanics anything other than a formalism for predicting the likelihoods of the recorded outcomes of actually performed observations.

4.
Entropy (Basel) ; 23(9)2021 Sep 09.
Artigo em Inglês | MEDLINE | ID: mdl-34573811

RESUMO

Wigner's friend scenarios involve an Observer, or Observers, measuring a Friend, or Friends, who themselves make quantum measurements. In recent discussions, it has been suggested that quantum mechanics may not always be able to provide a consistent account of a situation involving two Observers and two Friends. We investigate this problem by invoking the basic rules of quantum mechanics as outlined by Feynman in the well-known "Feynman Lectures on Physics". We show here that these "Feynman rules" constrain the a priori assumptions which can be made in generalised Wigner's friend scenarios, because the existence of the probabilities of interest ultimately depends on the availability of physical evidence (material records) of the system's past. With these constraints obeyed, a non-ambiguous and consistent account of all measurement outcomes is obtained for all agents, taking part in various Wigner's Friend scenarios.

5.
Entropy (Basel) ; 22(10)2020 Oct 21.
Artigo em Inglês | MEDLINE | ID: mdl-33286953

RESUMO

It is argued that Feynman's rules for evaluating probabilities, combined with von Neumann's principle of psycho-physical parallelism, help avoid inconsistencies, often associated with quantum theory. The former allows one to assign probabilities to entire sequences of hypothetical Observers' experiences, without mentioning the problem of wave function collapse. The latter limits the Observer's (e.g., Wigner's friend's) participation in a measurement to the changes produced in material objects, thus leaving his/her consciousness outside the picture.

6.
Entropy (Basel) ; 22(12)2020 Dec 08.
Artigo em Inglês | MEDLINE | ID: mdl-33302584

RESUMO

The task of reconstructing the system's state from the measurements results, known as the Pauli problem, usually requires repetition of two successive steps. Preparation in an initial state to be determined is followed by an accurate measurement of one of the several chosen operators in order to provide the necessary "Pauli data". We consider a similar yet more general problem of recovering Feynman's transition (path) amplitudes from the results of at least three consecutive measurements. The three-step histories of a pre- and post-selected quantum system are subjected to a type of interference not available to their two-step counterparts. We show that this interference can be exploited, and if the intermediate measurement is "fuzzy", the path amplitudes can be successfully recovered. The simplest case of a two-level system is analysed in detail. The "weak measurement" limit and the usefulness of the path amplitudes are also discussed.

7.
J Phys Chem A ; 112(10): 1999-2006, 2008 Mar 13.
Artigo em Inglês | MEDLINE | ID: mdl-18047301

RESUMO

We investigate the near-threshold formation of negative ions as Regge resonances in electron-atom scattering, with specific results obtained for e--K, e--Rb, and e--Cs. The complex angular momentum method, implemented within the Mulholland formulation of the total elastic cross sections, is employed. We demonstrate that for e--K, e--Rb, and e--Cs scattering, the near-threshold electron attachment cross sections are characterized by the Wigner threshold behavior, Ramsauer-Townsend minima, and Regge resonances, all discernible only through Regge partial cross section scrutiny. Regge partial, differential, and total elastic cross sections are presented and contrasted, as well as the differential cross section critical minima.

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