A combined 3D-atomic/nanoscale comprehension and ab initio computation of iron carbide structures tailored in Q&P steels via Si alloying.

The essences of the quenching and partitioning (Q&P) process are to stabilize the finely divided retained austenite (RA) via carbon (C) partitioning from supersaturated martensite during partitioning. Competitive reactions, i.e., transition carbide precipitation, C segregation, and decomposition of austenite, might take place concurrently during partitioning. In order to maintain the high volume fraction of RA, it is crucial to suppress the carbide precipitation sufficiently. Since silicon (Si) in the cementite θ (Fe3C) is insoluble, alloying Si in adequate concentrations prolongs its precipitation during the partitioning step. Consequently, C partitioning facilitates the desired chemical stabilization of RA. To elucidate the mechanisms of formation of transition η (Fe2C) carbides as well as cementite, θ (Fe3C), besides the transformation of transition carbides to more stable θ during the quenching and partitioning (Q&P) process, samples of 0.4 wt% C steels tailored with different Si contents were extensively characterized for microstructural evolution at different partitioning temperatures (TP) using high resolution transmission electron microscopy (HR-TEM) and three-dimensional atom probe tomography (3D-APT). While 1.5 wt% Si in the steel allowed only the formation of η carbides even at a high TP of 300 °C, reduction in Si content to 0.75 wt% only partially stabilized η carbides, allowing limited η → θ transformation. With 0.25 wt% Si, only θ was present in the microstructure, suggesting a η → θ transition during the early partitioning stage, followed by coarsening due to enhanced growth kinetics at 300 °C. Although η carbides precipitated in martensite under paraequilibrium conditions at 200 °C, θ carbides precipitated under negligible partitioning local equilibrium conditions at 300 °C. Competition with the formation of orthorhombic η and θ precipitation further examined via ab initio (density functional theory, DFT) computation and a similar probability of formation/thermodynamic stability were obtained. With an increase in Si concentration, the cohesive energy decreased when Si atoms occupied C positions, indicating decreasing stability. Overall, the thermodynamic prediction was in accord with the HR-TEM and 3D-APT results.

Heterogeneous Multiphase Microstructure Formation through Partial Recrystallization of a Warm-Deformed Medium Mn Steel during High-Temperature Partitioning.

A novel processing route is proposed to create a heterogeneous, multiphase structure in a medium Mn steel by incorporating partial quenching above the ambient, warm deformation, and partial recrystallization at high partitioning temperatures. The processing schedule was implemented in a Gleeble thermomechanical simulator and microstructures were examined by electron microscopy and X-ray diffraction. The hardness of the structures was measured as the preliminary mechanical property. Quenching of the reaustenitized sample to 120 °C provided a microstructure consisting of 73% martensite and balance (27%) untransformed austenite. Subsequent warm deformation at 500 °C enabled partially recrystallized ferrite and retained austenite during subsequent partitioning at 650 °C. The final microstructure consisted of a heterogeneous mixture of several phases and morphologies including lath-tempered martensite, partially recrystallized ferrite, lath and equiaxed austenite, and carbides. The volume fraction of retained austenite was 29% with a grain size of 200-300 nm and an estimated average stacking fault energy of 45 mJ/m2. The study indicates that desired novel microstructures can be imparted in these steels through suitable process design, whereby various hardening mechanisms, such as transformation-induced plasticity, bimodal grain size, phase boundary, strain partitioning, and precipitation hardening can be activated, resulting presumably in enhanced mechanical properties.

Characteristics and Kinetics of Bainite Transformation Behaviour in a High-Silicon Medium-Carbon Steel above and below the Ms Temperature.

This work deals with the kinetic aspects of bainite formation during isothermal holding above and below the martensite start (Ms~275 °C) temperature using a low-alloy, high-silicon DIN 1.5025 steel in a range suitable for achieving ultrafine/nanostructured bainite. Dilatation measurements were conducted to study transformation behaviour and kinetics, while the microstructural features were examined using laser scanning confocal microscopy and electron backscatter diffraction (EBSD) techniques combined with hardness measurements. The results showed that for isothermal holding above the Ms temperature, the maximum bainitic transformation rate decreased with the decrease in isothermal holding temperature between 450 and 300 °C. On the other hand, for isothermal holding below the Ms temperature at 250 and 200 °C, the maximum rate of transformation was achieved corresponding to region I due to the partitioning of carbon and also possibly because of the ledged growth of isothermal martensite soon after the start of isothermal holding. In addition, a second peak was obvious at about 100 and 500 s, respectively, during holding at 250 and 200 °C due to the occurrence of bainitic transformation, marking the beginning of region II.

Characterization of Friction Stir and TIG Welded CK45 Carbon Steel.

The present paper aims to compare the microstructural and mechanical properties of CK45 carbon steel plates, joined by friction stir (FSW) and tungsten inert gas (TIG) welding methods. Besides visual inspection, the welded joints and the base material were subsequently evaluated in respect of optical microstructures, hardness and tensile properties. Sound joints could be accomplished using both the FSW and TIG welding methods through proper selection of process parameters and the filler metal. The influence of a water-cooling system on the FSW and various filler metals on the quality of TIG welding were further assessed. Both the FS welded sample as well as TIG welded samples with two different filler metals ER70S-6 and ER80S-B2 exhibited brittle behavior that could be mitigated through optimized water cooling and use of R60 filler metal. A drastic reduction of brittle martensite phase constituent in the microstructure corroborated significant improvements in mechanical properties of the welded zones for both the FSW sample as well as TIG welded samples with R60 filler metal.

Constitutive modelling of hot deformation behaviour of a CoCrFeMnNi high-entropy alloy.

Models describing the constitutive flow behaviour of a metallic material are desired for appropriate process design and realization of defect-free components. In this study, constitutive equations based on the hyperbolic-sinusoidal Arrhenius-type model have been developed to define the hot deformation characteristics of a CoCrFeMnNi high-entropy alloy. The experimental true stress-true strain data were generated over a wide temperature (1023-1423 K) and strain rates (10-3-10 s-1) ranges. The impact of strain rate and temperature on deformation behaviour was further characterized through a temperature compensated strain rate parameter, i.e. Zener-Hollomon parameter. Additionally, a mathematical relation was employed to express the influence of various material constants on true-strain ranging from 0.2 to 0.75. Typical third order polynomial relations were found to be appropriate to fit the true-strain dependency of these material constants. The accuracy of the developed constitutive equations was evaluated by using the average absolute relative error (AARE) and correlation coefficient (R); the obtained values were 7.63% and 0.9858, respectively, suggesting reasonable predictions. These results demonstrate that the developed constitutive equations can predict the flow stress behaviour of the alloy with a good accuracy over a wide range of temperature and strain rate conditions and for large strains.