1.
Org Lett
; 4(24): 4297-300, 2002 Nov 28.
Artigo
em Inglês
| MEDLINE
| ID: mdl-12443082
RESUMO
[reaction: see text] [corrected] Regio- and chemoselective reduction of nitroarenes and carbonyl compounds and reductive cleavage of azo compounds, including bulkier molecules, was achieved by the catalytic transfer hydrogenation method (CTH) using a novel nickel-containing mesoporous silicate (NiMCM-41) molecular sieve catalyst. In addition, the catalyst was also found to behave as a truly heterogeneous catalyst as the yield was practically unaffected.