Comparative environmental and economic life cycle assessment of phytoremediation of dredged sediment using Arundo Donax, integrated with biomass to bioenergy valorization chain.

The economic and environmental life cycle assessment (LCA) was integrated into a laboratory-based experiment to evaluate the feasibility and sustainability of phytoremediation of chloride-rich marine dredged sediment, using perennial reed Arundo Donax along with biomass valorization. As a prerequisite for life cycle assessments, a baseline mathematical model was developed to estimate the yields of biomass to bioenergy valorization chain including the estimation of biomass yield per m3 sediment, bioenergy yields from valorization schemes, expected green electricity yield, and the phytoremediation time frame. This mathematical model was applied to develop a parametric life cycle inventory for two scenarios of sediment phytoremediation separately or integrated with biomass valorization, for LCA and further sensitivity and uncertainty analysis. Comparative LCA unveiled that the cost and environmental impacts of annual phytoremediation of 1m3 sediment alone or integrated with biomass valorization are much inferior to the corresponding sediment landfill as the inevitable alternative approach for sediment management. With the chloride bioaccumulation capacity of 9940 mg per kg dry biomass of A. donax, the phytoremediation of sediment with chloride concentration higher than 1650 mg/kg may not be achievable in a realistic time frame. Due to the importance of considering sediment depth and the effectiveness of the plant rooting system in estimating the performance of phytoremediation and the time frame, the volume of sediment (1m3) is a more appropriate functional unit than the surface area (ha) for LCA studies of phytoremediation. In addition, considering the volume of sediment as a functional unit retains comparability to other valorization scenarios such as sediment incorporation in cementitious matrices and management scenarios such as landfill, which are generally expressed on a volume or mass basis. Integrating biomass-derived bioenergy production into phytoremediation could offer local and global benefits in terms of economy and environment mainly due to carbon sequestration and avoiding fossil-based fuels.

Environmental, economic and experimental assessment of the valorization of dredged sediment through sand substitution in concrete.

The integrated life cycle assessment (LCA), life cycle cost assessment (LCC) and laboratory-based experimental assessment were applied to provide insight for early stage decision-making on the valorization of the dredged sediments. The objective was to find a viable and sustainable solution for the valorization of the dredged sediment in concrete, holding up a certain level of standard concrete performance without compromising in terms of economy and environment. For the sensitivity analysis, parametric life cycle inventories were developed to assess the sensitivity of environmental and economic costs to the rate of sand substitution by sediment, as well as the variations in the concrete components. The workability of fresh concrete and the compressive strength of hardened concrete at 28 days were assigned as the quality indicators to evaluate the influence of sand substitution by sediment on the concrete performance. The compressive strength evaluation in the laboratory demonstrated that a maximum rate of sand substitution in concrete up to 40 % by predominantly sandy sediment could sustain the concrete strength class. However, LCA and LCC negated the rate of sand substitution by sediment higher than 20 %. The integrated environmental, economic, and experimental assessments demonstrated that the substitution of sand by predominantly fine sediment downgrades the strength class of concrete, even in the low rate of incorporation (10 %) and increases the environmental and economic costs. Inferred from the results, the maximum rate of sustainable sand substitution by sediment in concrete could be optimized through a compromise between the expected mechanical strength and workability of the concrete, the economic and environmental impacts of the superplasticiser and the sediment transport. Overall, integrating environmental and economic cost assessments into the laboratory-based assessment of the valorization scenarios would determine the threshold for the sustainable rate of incorporation of sediment in valorization scenarios.

Contribution of settling measurements to the study of polycyclic aromatic hydrocarbons' (PAHs) mobilisation during resuspension of PAHs-associated sediment.

This paper aims to investigate the effect of the settling behaviour of sediment particles during resuspension on the mobilisation of pollutants such as polycyclic aromatic hydrocarbons (PAHs). Sediments were collected in different areas (basin, channel, beach) of a Mediterranean harbour, located in the south of France (the Grau du Roi harbour), and then separated into different size fractions: large (80-1000 µm), intermediate (40-80 µm), and fine (< 40 µm). Total PAHs concentrations in the initial sediment ranged from 320 to 1043 µg kg-1. Study of the settling behaviour of the PAH-contaminated sediment revealed two sedimentation regimes: sedimentation by mass, which exhibits a sharp interface between the supernatant and the deposit, and sedimentation by clarification with no interface. It appears that sediment particles settle either by the clarification regime or by a combination of the two sedimentation regimes, depending on the size fraction. Particle size distribution monitoring during the settling process allowed the identification of sediment particles less than 20 µm which remain in the water column up to 20 min after resuspension and appear to be the ones that can potentially mobilise PAHs.