Primordial Radioactivity and Prebiotic Chemical Evolution: Effect of γ Radiation on Formamide-Based Synthesis.

Although the effect of ionizing radiation on prebiotic chemistry is often overlooked, primordial natural radioactivity might have been an important source of energy for various chemical transformations. Estimates of the abundances of short-lived radionuclides on early Earth suggest that the primordial intensity of endogenous terrestrial radioactivity was up to 4 × 103 times higher than it is today. Therefore, we assume that chemical substances in contact with radioactive rocks should therefore undergo radiolysis. The calculations are followed by research investigating the influence of ionizing γ radiation on basic prebiotic substances, including formamide mixed with various clays, which might have played the role of a catalyst and an agent that partially blocked radiation that was potentially destructive for the products. Our explorations of this effect have shown that the irradiation of formamide-clay mixtures at doses of ∼6 kGy produces significant amounts of urea (up to the maximal concentration of approximately 250 mg L-1), which plays a role in HCN-based prebiotic chemistry.

Revealing the Earth's mantle from the tallest mountains using the Jinping Neutrino Experiment.

The Earth's engine is driven by unknown proportions of primordial energy and heat produced in radioactive decay. Unfortunately, competing models of Earth's composition reveal an order of magnitude uncertainty in the amount of radiogenic power driving mantle dynamics. Recent measurements of the Earth's flux of geoneutrinos, electron antineutrinos from terrestrial natural radioactivity, reveal the amount of uranium and thorium in the Earth and set limits on the residual proportion of primordial energy. Comparison of the flux measured at large underground neutrino experiments with geologically informed predictions of geoneutrino emission from the crust provide the critical test needed to define the mantle's radiogenic power. Measurement at an oceanic location, distant from nuclear reactors and continental crust, would best reveal the mantle flux, however, no such experiment is anticipated. We predict the geoneutrino flux at the site of the Jinping Neutrino Experiment (Sichuan, China). Within 8 years, the combination of existing data and measurements from soon to come experiments, including Jinping, will exclude end-member models at the 1σ level, define the mantle's radiogenic contribution to the surface heat loss, set limits on the composition of the silicate Earth, and provide significant parameter bounds for models defining the mode of mantle convection.