Chemical risks in drinking water of inhabitants in the basin of the Tonle Sap Great Lake.

The present study aimed to assess chemical risks in the drinking water of inhabitants in the basin of the Tonle Sap Great Lake. Water samples from tube wells (n = 52), dug wells (n = 13), stored rain water (n = 39), ponds/lakes (n = 19), canals/rivers (n = 24), and household pipe water (n = 45) were collected and analyzed for physicochemical properties, as well as microbial and chemical qualities using standard methods. Analytical results revealed that 42.1% of tube wells had As > 10 µg L-1 while 8.3% had Cr > 0.05 mg L-1. Concurrently, 55.2 and 11.8% of tube wells had Cd > 3.00 µg L-1 and Pb > 10 µg L-1, respectively. Moreover, 35.0% of pipe water had Fe > 0.3 mg L-1, whereas 85.7% of tube wells and 69.2% of dug wells had Mn > 0.1 mg L-1. All water sources including pipe water could pose risks of non-carcinogenic effects of chemical mixtures to all exposure groups through their drinking water pathway. Children were at a higher risk of chemical mixtures in their drinking water than adults. This study suggests that advanced treatment technologies should be applied to the current water treatment plants to provide inhabitants with safe drinking water.

Optical phonons of SnSe(1-x)Sx layered semiconductor alloys.

The evolution of the optical phonons in layered semiconductor alloys SnSe(1-x)Sx is studied as a function of the composition by using polarized Raman spectroscopy with six different excitation wavelengths (784.8, 632.8, 532, 514.5, 488, and 441.6 nm). The polarization dependences of the phonon modes are compared with transmission electron diffraction measurements to determine the crystallographic orientation of the samples. Some of the Raman modes show significant variation in their polarization behavior depending on the excitation wavelengths. It is established that the maximum intensity direction of the Ag2 mode of SnSe(1-x)Sx (0 ≤ x ≤ 1) does not depend on the excitation wavelength and corresponds to the armchair direction. It is additionally found that the lower-frequency Raman modes of Ag1, Ag2 and B3g1 in the alloys show the typical one-mode behavior of optical phonons, whereas the higher-frequency modes of B3g2, Ag3 and Ag4 show two-mode behavior.

Low-Frequency Raman Spectroscopy of Few-Layer 2H-SnS2.

We investigated interlayer phonon modes of mechanically exfoliated few-layer 2H-SnS2 samples by using room temperature low-frequency micro-Raman spectroscopy. Raman measurements were performed using laser wavelengths of 441.6, 514.4, 532 and 632.8 nm with power below 100 µW and inside a vacuum chamber to avoid photo-oxidation. The intralayer Eg and A1g modes are observed at ~206 cm-1 and 314 cm-1, respectively, but the Eg mode is much weaker for all excitation energies. The A1g mode exhibits strong resonant enhancement for the 532 nm (2.33 eV) laser. In the low-frequency region, interlayer vibrational modes of shear and breathing modes are observed. These modes show characteristic dependence on the number of layers. The strengths of the interlayer interactions are estimated by fitting the interlayer mode frequencies using the linear chain model and are found to be 1.64 × 1019 N · m-3 and 5.03 × 1019 N · m-3 for the shear and breathing modes, respectively.