RESUMO
This study evaluated similarities/dissimilarities of raw and processed chicken breast and thigh lipids that were complexed by ß-cyclodextrin, using a combined FTIR-PCA technique. Lipid fractions were analyzed as non-complexed and ß-cyclodextrin-complexed samples via thermogravimetry, differential scanning calorimetry and ATR-FTIR. The lipid complexation reduced the water content to 7.67-8.33%, in comparison with the ß-cyclodextrin hydrate (~14%). The stabilities of the complexes and ß-cyclodextrin were almost the same. ATR-FTIR analysis revealed the presence of important bands that corresponded to the C=O groups (1743-1744 cm-1) in both the non-complexed and nano-encapsulated lipids. Furthermore, the bands that corresponded to the vibrations of double bonds corresponding to the natural/degraded (cis/trans) fatty acids in lipids appeared at 3008-3011 and 938-946 cm-1, respectively. The main FTIR bands that were involved in the discrimination of raw and processed chicken lipids, and of non-complexed and complexed lipids, were evaluated with PCA. The shifting of specific FTIR band wavenumbers had the highest influence, especially vibrations of the α(1â4) glucosidic bond in ß-cyclodextrin for PC1, and CH2/3 groups from lipids for PC2. This first approach on ß-cyclodextrin nano-encapsulation of chicken lipids revealed the possibility to stabilize poultry fatty components for further applications in various ingredients for the food industry.
